Intramolecular photo-substitution in the inclusion compound of mono[6-deoxy-6-(2-butenedinitrile-2,3-dimercapto sodium salt)]-β-cyclodextrin with cyclopentadienyl manganese tricarbonyl in DMF solution

C. S. Lu; W. W. Zhang; X. M. Ren; C. J. Hu; H. Z. Zhu; Q. J. Meng

Intramolecular photo-substitution in the inclusion compound of mono[6-deoxy-6-(2-butenedinitrile-2,3-dimercapto sodium salt)]-β-cyclodextrin with cyclopentadienyl manganese tricarbonyl in DMF solution

C. S. Lu, W. W. Zhang, X. M. Ren, C. J. Hu, H. Z. Zhu, Q. J. Meng

Nanjing University

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

A novel β-CD derivative, mono[6-deoxy-6-(2-butenedinitrile-2,3-dimercapto sodium salt)]-β-CD1, and its inclusion compound 2 with CpMn^I(CO)₃ have been prepared and characterized by spectroscopic methods. The inclusion complexation significantly stabilized both the host and guest. Upon irradiation of inclusion compound 2 in DMF solution, an interesting intramolecular photo-substitution resulting in the formation of a self-stabilized compound mono[6-deoxy-6-(2-butenedinitrile-2,3-dimercapto sodium salt)]-β-CD-Mn^II(DMF)₂Cp 5 was observed. Based upon a double-recognition between the host and the organometallic guest, compound 5 became very stable in DMF solution.

Original language	English
Pages (from-to)	3052-3055
Number of pages	4
Journal	Journal of the Chemical Society. Dalton Transactions
Issue number	20
State	Published - 2001
Externally published	Yes

Cite this

@article{d75ffb8e62374e95b12ca500426cf9c2,

title = "Intramolecular photo-substitution in the inclusion compound of mono[6-deoxy-6-(2-butenedinitrile-2,3-dimercapto sodium salt)]-β-cyclodextrin with cyclopentadienyl manganese tricarbonyl in DMF solution",

abstract = "A novel β-CD derivative, mono[6-deoxy-6-(2-butenedinitrile-2,3-dimercapto sodium salt)]-β-CD1, and its inclusion compound 2 with CpMnI(CO)3 have been prepared and characterized by spectroscopic methods. The inclusion complexation significantly stabilized both the host and guest. Upon irradiation of inclusion compound 2 in DMF solution, an interesting intramolecular photo-substitution resulting in the formation of a self-stabilized compound mono[6-deoxy-6-(2-butenedinitrile-2,3-dimercapto sodium salt)]-β-CD-MnII(DMF)2Cp 5 was observed. Based upon a double-recognition between the host and the organometallic guest, compound 5 became very stable in DMF solution.",

author = "Lu, {C. S.} and Zhang, {W. W.} and Ren, {X. M.} and Hu, {C. J.} and Zhu, {H. Z.} and Meng, {Q. J.}",

year = "2001",

language = "英语",

pages = "3052--3055",

journal = "Journal of the Chemical Society. Dalton Transactions",

issn = "1470-479X",

publisher = "Royal Society of Chemistry",

number = "20",

}

Intramolecular photo-substitution in the inclusion compound of mono[6-deoxy-6-(2-butenedinitrile-2,3-dimercapto sodium salt)]-β-cyclodextrin with cyclopentadienyl manganese tricarbonyl in DMF solution. / Lu, C. S.; Zhang, W. W.; Ren, X. M. et al.
In: Journal of the Chemical Society. Dalton Transactions, No. 20, 2001, p. 3052-3055.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Intramolecular photo-substitution in the inclusion compound of mono[6-deoxy-6-(2-butenedinitrile-2,3-dimercapto sodium salt)]-β-cyclodextrin with cyclopentadienyl manganese tricarbonyl in DMF solution

AU - Lu, C. S.

AU - Zhang, W. W.

AU - Ren, X. M.

AU - Hu, C. J.

AU - Zhu, H. Z.

AU - Meng, Q. J.

PY - 2001

Y1 - 2001

N2 - A novel β-CD derivative, mono[6-deoxy-6-(2-butenedinitrile-2,3-dimercapto sodium salt)]-β-CD1, and its inclusion compound 2 with CpMnI(CO)3 have been prepared and characterized by spectroscopic methods. The inclusion complexation significantly stabilized both the host and guest. Upon irradiation of inclusion compound 2 in DMF solution, an interesting intramolecular photo-substitution resulting in the formation of a self-stabilized compound mono[6-deoxy-6-(2-butenedinitrile-2,3-dimercapto sodium salt)]-β-CD-MnII(DMF)2Cp 5 was observed. Based upon a double-recognition between the host and the organometallic guest, compound 5 became very stable in DMF solution.

AB - A novel β-CD derivative, mono[6-deoxy-6-(2-butenedinitrile-2,3-dimercapto sodium salt)]-β-CD1, and its inclusion compound 2 with CpMnI(CO)3 have been prepared and characterized by spectroscopic methods. The inclusion complexation significantly stabilized both the host and guest. Upon irradiation of inclusion compound 2 in DMF solution, an interesting intramolecular photo-substitution resulting in the formation of a self-stabilized compound mono[6-deoxy-6-(2-butenedinitrile-2,3-dimercapto sodium salt)]-β-CD-MnII(DMF)2Cp 5 was observed. Based upon a double-recognition between the host and the organometallic guest, compound 5 became very stable in DMF solution.

UR - http://www.scopus.com/inward/record.url?scp=0034740323&partnerID=8YFLogxK

M3 - 文章

AN - SCOPUS:0036374140

SN - 1470-479X

SP - 3052

EP - 3055

JO - Journal of the Chemical Society. Dalton Transactions

JF - Journal of the Chemical Society. Dalton Transactions

IS - 20

ER -

Intramolecular photo-substitution in the inclusion compound of mono[6-deoxy-6-(2-butenedinitrile-2,3-dimercapto sodium salt)]-β-cyclodextrin with cyclopentadienyl manganese tricarbonyl in DMF solution

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