Abstract
Ionic liquid lubricants or lubricant additives have been studied intensively over past decades. However, ionic grease serving as lubricant has rarely been investigated so far. In this work, novel protic [triethanolamine][oleic acid] and aprotic [choline][oleic acid] ionic greases are successfully synthesized. These ionic greases can be directly used as lubricants without adding thickeners or other additives. Their distinct thermal and rheological properties are investigated and are well-correlated to their tribological properties. It is revealed that aprotic ionic grease shows superior temperature- and pressure-tolerant lubrication properties over those of protic ionic grease. The lubrication mechanism is studied, and it reveals that strong physical adsorption of ionic grease onto friction surface plays a dominating role for promoted lubrication instead of tribo-chemical film formation.
| Original language | English |
|---|---|
| Pages (from-to) | 4977-4984 |
| Number of pages | 8 |
| Journal | ACS Applied Materials and Interfaces |
| Volume | 8 |
| Issue number | 7 |
| DOIs | |
| State | Published - 24 Feb 2016 |
| Externally published | Yes |
Keywords
- friction
- interface
- ionic grease
- lubrication
- rheology