Isolation, structure and magnetic properties of two novel core-shell 3d-4f heterometallic nanoscale clusters

Qingfang Lin; Yu Zhang; Weiwei Cheng; Ying Liu; Yan Xu

doi:10.1039/c6dt04118c

Isolation, structure and magnetic properties of two novel core-shell 3d-4f heterometallic nanoscale clusters

Qingfang Lin, Yu Zhang, Weiwei Cheng, Ying Liu, Yan Xu

College of Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

Two novel core-shell Ni-Ln nanosized clusters, Na₄(H₃O)₄[Nd₃₈Ni_42.5(IDA)₄₂(OAc)₄(CH₃CH₂OH)₂(CO₃)₁₈(μ₃-OH)₆₂(μ₃-O)₆(H₂O)₁₂]Cl₆·26H₂O (1) and Na[Pr₄₂Ni₃₈(μ₃-OH)₇₁(μ₃-O)₄(IDA)₃₈(NH₂CH₂COO)₂(OAc)₂(CH₃CH₂OH)₂(CO₃)₁₆(H₂O)₆Cl₇]Cl₃·37H₂O (2) (IDA = iminodiacetate), were successfully prepared using the Cl⁻ anion and the flexible ligand iminodiacetic acid. Structural analysis indicates that the discrete dumbbell-shaped 3d-4f heterometallic cluster in 1 is constructed from two {Nd₁₉Ni₂₁} clusters connected by one {NiO₆} unit, whereas the bowknot-shaped nanosized cluster is composed of two {Pr₁₉Ni₁₉} clusters ligated by two {Pr₂} units and CO₃²⁻ anions. The formation of both compounds indicates that Cl⁻ ions play important roles and act not only as balance anions but also as template and bridging ligands. The magnetic properties of compounds 1 and 2 were investigated, and it was revealed that they display dominant antiferromagnetic exchange.

Original language	English
Pages (from-to)	643-646
Number of pages	4
Journal	Dalton Transactions
Volume	46
Issue number	3
DOIs	https://doi.org/10.1039/c6dt04118c
State	Published - 2017

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@article{01fa5e6ef12647a1b4615bb62fd85f19,

title = "Isolation, structure and magnetic properties of two novel core-shell 3d-4f heterometallic nanoscale clusters",

abstract = "Two novel core-shell Ni-Ln nanosized clusters, Na4(H3O)4[Nd38Ni42.5(IDA)42(OAc)4(CH3CH2OH)2(CO3)18(μ3-OH)62(μ3-O)6(H2O)12]Cl6·26H2O (1) and Na[Pr42Ni38(μ3-OH)71(μ3-O)4(IDA)38(NH2CH2COO)2(OAc)2(CH3CH2OH)2(CO3)16(H2O)6Cl7]Cl3·37H2O (2) (IDA = iminodiacetate), were successfully prepared using the Cl− anion and the flexible ligand iminodiacetic acid. Structural analysis indicates that the discrete dumbbell-shaped 3d-4f heterometallic cluster in 1 is constructed from two {Nd19Ni21} clusters connected by one {NiO6} unit, whereas the bowknot-shaped nanosized cluster is composed of two {Pr19Ni19} clusters ligated by two {Pr2} units and CO32− anions. The formation of both compounds indicates that Cl− ions play important roles and act not only as balance anions but also as template and bridging ligands. The magnetic properties of compounds 1 and 2 were investigated, and it was revealed that they display dominant antiferromagnetic exchange.",

author = "Qingfang Lin and Yu Zhang and Weiwei Cheng and Ying Liu and Yan Xu",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2017",

doi = "10.1039/c6dt04118c",

language = "英语",

volume = "46",

pages = "643--646",

journal = "Dalton Transactions",

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T1 - Isolation, structure and magnetic properties of two novel core-shell 3d-4f heterometallic nanoscale clusters

AU - Lin, Qingfang

AU - Zhang, Yu

AU - Cheng, Weiwei

AU - Liu, Ying

AU - Xu, Yan

N1 - Publisher Copyright: © The Royal Society of Chemistry.

PY - 2017

Y1 - 2017

N2 - Two novel core-shell Ni-Ln nanosized clusters, Na4(H3O)4[Nd38Ni42.5(IDA)42(OAc)4(CH3CH2OH)2(CO3)18(μ3-OH)62(μ3-O)6(H2O)12]Cl6·26H2O (1) and Na[Pr42Ni38(μ3-OH)71(μ3-O)4(IDA)38(NH2CH2COO)2(OAc)2(CH3CH2OH)2(CO3)16(H2O)6Cl7]Cl3·37H2O (2) (IDA = iminodiacetate), were successfully prepared using the Cl− anion and the flexible ligand iminodiacetic acid. Structural analysis indicates that the discrete dumbbell-shaped 3d-4f heterometallic cluster in 1 is constructed from two {Nd19Ni21} clusters connected by one {NiO6} unit, whereas the bowknot-shaped nanosized cluster is composed of two {Pr19Ni19} clusters ligated by two {Pr2} units and CO32− anions. The formation of both compounds indicates that Cl− ions play important roles and act not only as balance anions but also as template and bridging ligands. The magnetic properties of compounds 1 and 2 were investigated, and it was revealed that they display dominant antiferromagnetic exchange.

AB - Two novel core-shell Ni-Ln nanosized clusters, Na4(H3O)4[Nd38Ni42.5(IDA)42(OAc)4(CH3CH2OH)2(CO3)18(μ3-OH)62(μ3-O)6(H2O)12]Cl6·26H2O (1) and Na[Pr42Ni38(μ3-OH)71(μ3-O)4(IDA)38(NH2CH2COO)2(OAc)2(CH3CH2OH)2(CO3)16(H2O)6Cl7]Cl3·37H2O (2) (IDA = iminodiacetate), were successfully prepared using the Cl− anion and the flexible ligand iminodiacetic acid. Structural analysis indicates that the discrete dumbbell-shaped 3d-4f heterometallic cluster in 1 is constructed from two {Nd19Ni21} clusters connected by one {NiO6} unit, whereas the bowknot-shaped nanosized cluster is composed of two {Pr19Ni19} clusters ligated by two {Pr2} units and CO32− anions. The formation of both compounds indicates that Cl− ions play important roles and act not only as balance anions but also as template and bridging ligands. The magnetic properties of compounds 1 and 2 were investigated, and it was revealed that they display dominant antiferromagnetic exchange.

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U2 - 10.1039/c6dt04118c

DO - 10.1039/c6dt04118c

M3 - 文章

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AN - SCOPUS:85010390690

SN - 1477-9226

VL - 46

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EP - 646

JO - Dalton Transactions

JF - Dalton Transactions

IS - 3

ER -

Isolation, structure and magnetic properties of two novel core-shell 3d-4f heterometallic nanoscale clusters

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