Kinetic study of MSW incineration fly ash melting by DSC-DTA

Run Dong Li, Yong Chi, Lei Wang, Zeng Yi Ma, Shui Qing Li, Jian Hua Yan, Ke Fa Cen

Research output: Contribution to journalArticlepeer-review

8 Scopus citations

Abstract

In this work, the melting process of MSWI (municipal solid waste incineration) fly ash was studied by high-temperature DSC-DTA experiments performed under the temperature range of 20-145^DDGC and some other parameter variables including atmosphere (O2 and N2), heating rates (5°C/min, lO°C/min, 20°C/min) and CaO addition. Two samples of MSWI fly ash used in the experiment were collected from a power station in southern China and the Rouen power station in France respectively. Three main transitions were observed during the melting process of fly ash: dehydration, polymorphic transition and fusion, which occur in the temperature range of 100-200°C, 480-670°C and 1101-1244°C, respectively. Finally, a zero-order kinetic model of fly ash melting reaction was established and the apparent activation energy of MSWI ash melting was obtained.

Original languageEnglish
Pages (from-to)498-503
Number of pages6
JournalZhejiang Daxue Xuebao (Gongxue Ban)/Journal of Zhejiang University (Engineering Science)
Volume36
Issue number5
StatePublished - Sep 2002
Externally publishedYes

Keywords

  • DSC-DTA
  • Fly ash
  • Kinetics
  • Melting
  • Municipal solid waste

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