Kinetics research of phenol hydroxylation on Fe-Cu catalyst

Xiao Li Gu; Xu Qiao; Mi Fen Cui

Kinetics research of phenol hydroxylation on Fe-Cu catalyst

Xiao Li Gu, Xu Qiao, Mi Fen Cui

COLLEGE OF CHEMICAL ENGINEERING

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

Phenol hydroxylation with aqueous H₂O₂ was known as one of the most effective manufactures in the world. With Fe-Cu or Fe-Cu/Al₂O₃ metallic acid salts as catalyst and in gradientless reactor, phenol hydroxylation reaction kinetics process was investigated by changing the factors of reaction temperature, phenol/H₂O₂ molar ratio and phenol initial mass fraction. It was shown that under the same value of M/F_A0(M-the mass of catalyst; F_A0-the mass flow rate of critical component A of reactant at the inlet of reactor), phenol conversion was increased but dihydroxybenzene total selectivity went down with the temperature rise, H₂O₂/phenol molar ratio and phenol initial mass fraction increasing. Therefore, the reaction mechanism of phenol/H₂O₂ hydroxylation over Fe-Cu or Fe-Cu/Al₂O₃ was purposed, its reaction kinetics equation and the relative kinetics parameters were also calculated.

Original language	English
Pages (from-to)	87-92
Number of pages	6
Journal	Shiyou Xuebao, Shiyou Jiagong/Acta Petrolei Sinica (Petroleum Processing Section)
Volume	22
Issue number	2
State	Published - Apr 2006

Keywords

Fe-Cu catalyst
Hydroxylation
Phenol
Reaction kinetics
Reaction mechanism

Cite this

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title = "Kinetics research of phenol hydroxylation on Fe-Cu catalyst",

abstract = "Phenol hydroxylation with aqueous H2O2 was known as one of the most effective manufactures in the world. With Fe-Cu or Fe-Cu/Al2O3 metallic acid salts as catalyst and in gradientless reactor, phenol hydroxylation reaction kinetics process was investigated by changing the factors of reaction temperature, phenol/H2O2 molar ratio and phenol initial mass fraction. It was shown that under the same value of M/FA0(M-the mass of catalyst; FA0-the mass flow rate of critical component A of reactant at the inlet of reactor), phenol conversion was increased but dihydroxybenzene total selectivity went down with the temperature rise, H2O2/phenol molar ratio and phenol initial mass fraction increasing. Therefore, the reaction mechanism of phenol/H2O2 hydroxylation over Fe-Cu or Fe-Cu/Al2O3 was purposed, its reaction kinetics equation and the relative kinetics parameters were also calculated.",

keywords = "Fe-Cu catalyst, Hydroxylation, Phenol, Reaction kinetics, Reaction mechanism",

author = "Gu, {Xiao Li} and Xu Qiao and Cui, {Mi Fen}",

year = "2006",

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volume = "22",

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journal = "Shiyou Xuebao, Shiyou Jiagong/Acta Petrolei Sinica (Petroleum Processing Section)",

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TY - JOUR

T1 - Kinetics research of phenol hydroxylation on Fe-Cu catalyst

AU - Gu, Xiao Li

AU - Qiao, Xu

AU - Cui, Mi Fen

PY - 2006/4

Y1 - 2006/4

N2 - Phenol hydroxylation with aqueous H2O2 was known as one of the most effective manufactures in the world. With Fe-Cu or Fe-Cu/Al2O3 metallic acid salts as catalyst and in gradientless reactor, phenol hydroxylation reaction kinetics process was investigated by changing the factors of reaction temperature, phenol/H2O2 molar ratio and phenol initial mass fraction. It was shown that under the same value of M/FA0(M-the mass of catalyst; FA0-the mass flow rate of critical component A of reactant at the inlet of reactor), phenol conversion was increased but dihydroxybenzene total selectivity went down with the temperature rise, H2O2/phenol molar ratio and phenol initial mass fraction increasing. Therefore, the reaction mechanism of phenol/H2O2 hydroxylation over Fe-Cu or Fe-Cu/Al2O3 was purposed, its reaction kinetics equation and the relative kinetics parameters were also calculated.

AB - Phenol hydroxylation with aqueous H2O2 was known as one of the most effective manufactures in the world. With Fe-Cu or Fe-Cu/Al2O3 metallic acid salts as catalyst and in gradientless reactor, phenol hydroxylation reaction kinetics process was investigated by changing the factors of reaction temperature, phenol/H2O2 molar ratio and phenol initial mass fraction. It was shown that under the same value of M/FA0(M-the mass of catalyst; FA0-the mass flow rate of critical component A of reactant at the inlet of reactor), phenol conversion was increased but dihydroxybenzene total selectivity went down with the temperature rise, H2O2/phenol molar ratio and phenol initial mass fraction increasing. Therefore, the reaction mechanism of phenol/H2O2 hydroxylation over Fe-Cu or Fe-Cu/Al2O3 was purposed, its reaction kinetics equation and the relative kinetics parameters were also calculated.

KW - Fe-Cu catalyst

KW - Hydroxylation

KW - Phenol

KW - Reaction kinetics

KW - Reaction mechanism

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M3 - 文章

AN - SCOPUS:33646688217

SN - 1001-8719

VL - 22

SP - 87

EP - 92

JO - Shiyou Xuebao, Shiyou Jiagong/Acta Petrolei Sinica (Petroleum Processing Section)

JF - Shiyou Xuebao, Shiyou Jiagong/Acta Petrolei Sinica (Petroleum Processing Section)

IS - 2

ER -

Kinetics research of phenol hydroxylation on Fe-Cu catalyst

Abstract

Keywords

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