Lanthanum-phosphorous modified HZSM-5 catalysts in dehydration of ethanol to ethylene: A comparative analysis

Nina Zhan; Yi Hu; Heng Li; Dinghua Yu; Yuwang Han; He Huang

doi:10.1016/j.catcom.2010.01.011

Lanthanum-phosphorous modified HZSM-5 catalysts in dehydration of ethanol to ethylene: A comparative analysis

Nina Zhan, Yi Hu, Heng Li, Dinghua Yu, Yuwang Han, He Huang

School of Pharmaceutical Sciences

Nanjing Tech University

Research output: Contribution to journal › Article › peer-review

102 Scopus citations

Abstract

The catalytic dehydration of ethanol into ethylene was studied over HZSM-5, phosphorous modified HZSM-5 and lanthanum-phosphorous modified HZSM-5 in the low temperature range from 473 K to 573 K. The experimental results demonstrated the lanthanum-phosphorous modified HZSM-5 offered the outstanding catalytic performance and the enhanced anti-coking ability markedly, especially for 0.5%La-2%PHZSM-5. Characterizations revealed that the improved catalytic performance and the excellent anti-coking ability of lanthanum-phosphorous modified HZSM-5 could be attributed to the harmonious acid sites and pore structure by the modification with lanthanum and phosphorous.

Original language	English
Pages (from-to)	633-637
Number of pages	5
Journal	Catalysis Communications
Volume	11
Issue number	7
DOIs	https://doi.org/10.1016/j.catcom.2010.01.011
State	Published - 10 Mar 2010

Keywords

Dehydration
Ethanol
Ethylene
HZSM-5
Lanthanum
Modification

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10.1016/j.catcom.2010.01.011

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title = "Lanthanum-phosphorous modified HZSM-5 catalysts in dehydration of ethanol to ethylene: A comparative analysis",

abstract = "The catalytic dehydration of ethanol into ethylene was studied over HZSM-5, phosphorous modified HZSM-5 and lanthanum-phosphorous modified HZSM-5 in the low temperature range from 473 K to 573 K. The experimental results demonstrated the lanthanum-phosphorous modified HZSM-5 offered the outstanding catalytic performance and the enhanced anti-coking ability markedly, especially for 0.5%La-2%PHZSM-5. Characterizations revealed that the improved catalytic performance and the excellent anti-coking ability of lanthanum-phosphorous modified HZSM-5 could be attributed to the harmonious acid sites and pore structure by the modification with lanthanum and phosphorous.",

keywords = "Dehydration, Ethanol, Ethylene, HZSM-5, Lanthanum, Modification",

author = "Nina Zhan and Yi Hu and Heng Li and Dinghua Yu and Yuwang Han and He Huang",

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TY - JOUR

T1 - Lanthanum-phosphorous modified HZSM-5 catalysts in dehydration of ethanol to ethylene

T2 - A comparative analysis

AU - Zhan, Nina

AU - Hu, Yi

AU - Li, Heng

AU - Yu, Dinghua

AU - Han, Yuwang

AU - Huang, He

PY - 2010/3/10

Y1 - 2010/3/10

N2 - The catalytic dehydration of ethanol into ethylene was studied over HZSM-5, phosphorous modified HZSM-5 and lanthanum-phosphorous modified HZSM-5 in the low temperature range from 473 K to 573 K. The experimental results demonstrated the lanthanum-phosphorous modified HZSM-5 offered the outstanding catalytic performance and the enhanced anti-coking ability markedly, especially for 0.5%La-2%PHZSM-5. Characterizations revealed that the improved catalytic performance and the excellent anti-coking ability of lanthanum-phosphorous modified HZSM-5 could be attributed to the harmonious acid sites and pore structure by the modification with lanthanum and phosphorous.

AB - The catalytic dehydration of ethanol into ethylene was studied over HZSM-5, phosphorous modified HZSM-5 and lanthanum-phosphorous modified HZSM-5 in the low temperature range from 473 K to 573 K. The experimental results demonstrated the lanthanum-phosphorous modified HZSM-5 offered the outstanding catalytic performance and the enhanced anti-coking ability markedly, especially for 0.5%La-2%PHZSM-5. Characterizations revealed that the improved catalytic performance and the excellent anti-coking ability of lanthanum-phosphorous modified HZSM-5 could be attributed to the harmonious acid sites and pore structure by the modification with lanthanum and phosphorous.

KW - Dehydration

KW - Ethanol

KW - Ethylene

KW - HZSM-5

KW - Lanthanum

KW - Modification

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DO - 10.1016/j.catcom.2010.01.011

M3 - 文章

AN - SCOPUS:76749099642

SN - 1566-7367

VL - 11

SP - 633

EP - 637

JO - Catalysis Communications

JF - Catalysis Communications

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ER -

Lanthanum-phosphorous modified HZSM-5 catalysts in dehydration of ethanol to ethylene: A comparative analysis

Abstract

Keywords

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