TY - JOUR
T1 - Layered zinc 4-phosphonoisophthalates pillared by flexible bis(imidazole) Co-ligands
AU - Jin, Hao Jun
AU - Wang, Peng Fei
AU - Yao, Cheng
AU - Zheng, Li Min
PY - 2011/10
Y1 - 2011/10
N2 - This paper reports two zinc phosphonates based on 4-phosphonoisophthalic acid (4-piH4) and bis(imidazole) co-ligands, namely, [Zn 2(4-pi)(1,2-bix)] (1) and [Zn2(4-pi)(1,3-bix)] (2) (1,2-bix = 1,2-bis(imidazol-1-ylmethyl)benzene, 1,3-bix = 1,3-bis(imidazol-1- ylmethyl)benzene). Both show layer structures in which the inorganic tetranuclear cores of Zn4P2O6 are connected by 4-pi4-ligands. The 1,2-bix or 1,3-bix ligand binds to the Zn atoms within the tetranuclear unit or between the neighboring tetranuclear units in a cis-coordination mode, and fill in the interlayer spaces in both cases. The luminescent properties are investigated.
AB - This paper reports two zinc phosphonates based on 4-phosphonoisophthalic acid (4-piH4) and bis(imidazole) co-ligands, namely, [Zn 2(4-pi)(1,2-bix)] (1) and [Zn2(4-pi)(1,3-bix)] (2) (1,2-bix = 1,2-bis(imidazol-1-ylmethyl)benzene, 1,3-bix = 1,3-bis(imidazol-1- ylmethyl)benzene). Both show layer structures in which the inorganic tetranuclear cores of Zn4P2O6 are connected by 4-pi4-ligands. The 1,2-bix or 1,3-bix ligand binds to the Zn atoms within the tetranuclear unit or between the neighboring tetranuclear units in a cis-coordination mode, and fill in the interlayer spaces in both cases. The luminescent properties are investigated.
KW - 4-Phosphonoisophthalic acid
KW - Bis(imidazol-1-ylmethyl)benzene
KW - Crystal structure
KW - Zinc
UR - http://www.scopus.com/inward/record.url?scp=81155159709&partnerID=8YFLogxK
U2 - 10.1016/j.inoche.2011.07.005
DO - 10.1016/j.inoche.2011.07.005
M3 - 文章
AN - SCOPUS:81155159709
SN - 1387-7003
VL - 14
SP - 1677
EP - 1680
JO - Inorganic Chemistry Communications
JF - Inorganic Chemistry Communications
IS - 10
ER -