Linear group 13 EΞE triple bonds

Zhong Hua Cui; Yu Qian Liu; Runfeng Huang; Meng Hui Wang; Bing Yan; Lili Zhao

doi:10.1039/d1cp01035b

Linear group 13 EΞE triple bonds

Zhong Hua Cui, Yu Qian Liu, Runfeng Huang, Meng Hui Wang, Bing Yan, Lili Zhao

School of Chemistry and Moleculai Engineering

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The unexpected linear group 13 EΞE triple bonds were herein uncovered with theD_3h-symmetry E₂M₅⁺(M = Li, Na, and K) clusters, where the linear M-EΞE-M form is perfectly surrounded by M₃motifs. The increasing nonbonded electron density of the heavier main-group elements is the key issue for thetrans-bent geometry, and yet it is strongly suppressed in E₂M₅⁺, creating two degenerate π bonds and one multi-center σ bond.

Original language	English
Pages (from-to)	11611-11615
Number of pages	5
Journal	Physical Chemistry Chemical Physics
Volume	23
Issue number	20
DOIs	https://doi.org/10.1039/d1cp01035b
State	Published - 28 May 2021

Access to Document

10.1039/d1cp01035b

Cite this

@article{1a7ac2b2d1784541897da590ea86e7e4,

title = "Linear group 13 EΞE triple bonds",

abstract = "The unexpected linear group 13 EΞE triple bonds were herein uncovered with theD3h-symmetry E2M5+(M = Li, Na, and K) clusters, where the linear M-EΞE-M form is perfectly surrounded by M3motifs. The increasing nonbonded electron density of the heavier main-group elements is the key issue for thetrans-bent geometry, and yet it is strongly suppressed in E2M5+, creating two degenerate π bonds and one multi-center σ bond.",

author = "Cui, {Zhong Hua} and Liu, {Yu Qian} and Runfeng Huang and Wang, {Meng Hui} and Bing Yan and Lili Zhao",

note = "Publisher Copyright: {\textcopyright} the Owner Societies 2021.",

year = "2021",

month = may,

day = "28",

doi = "10.1039/d1cp01035b",

language = "英语",

volume = "23",

pages = "11611--11615",

journal = "Physical Chemistry Chemical Physics",

issn = "1463-9076",

publisher = "Royal Society of Chemistry",

number = "20",

}

TY - JOUR

T1 - Linear group 13 EΞE triple bonds

AU - Cui, Zhong Hua

AU - Liu, Yu Qian

AU - Huang, Runfeng

AU - Wang, Meng Hui

AU - Yan, Bing

AU - Zhao, Lili

N1 - Publisher Copyright: © the Owner Societies 2021.

PY - 2021/5/28

Y1 - 2021/5/28

N2 - The unexpected linear group 13 EΞE triple bonds were herein uncovered with theD3h-symmetry E2M5+(M = Li, Na, and K) clusters, where the linear M-EΞE-M form is perfectly surrounded by M3motifs. The increasing nonbonded electron density of the heavier main-group elements is the key issue for thetrans-bent geometry, and yet it is strongly suppressed in E2M5+, creating two degenerate π bonds and one multi-center σ bond.

AB - The unexpected linear group 13 EΞE triple bonds were herein uncovered with theD3h-symmetry E2M5+(M = Li, Na, and K) clusters, where the linear M-EΞE-M form is perfectly surrounded by M3motifs. The increasing nonbonded electron density of the heavier main-group elements is the key issue for thetrans-bent geometry, and yet it is strongly suppressed in E2M5+, creating two degenerate π bonds and one multi-center σ bond.

UR - http://www.scopus.com/inward/record.url?scp=85107005949&partnerID=8YFLogxK

U2 - 10.1039/d1cp01035b

DO - 10.1039/d1cp01035b

M3 - 文章

C2 - 33988636

AN - SCOPUS:85107005949

SN - 1463-9076

VL - 23

SP - 11611

EP - 11615

JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

IS - 20

ER -

Linear group 13 EΞE triple bonds

Abstract

Access to Document

Other files and links

Fingerprint

Cite this