Lithium methyl carbonate as a reaction product of metallic lithium and dimethyl carbonate

Guorong V. Zhuang; Hui Yang; Philip N. Ross; Kang Xu; T. Richard Jow

doi:10.1149/1.2142157

Lithium methyl carbonate as a reaction product of metallic lithium and dimethyl carbonate

Guorong V. Zhuang, Hui Yang, Philip N. Ross, Kang Xu, T. Richard Jow

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84 Scopus citations

Abstract

To improve the understanding of passive film formation on metallic lithium in organic electrolyte, we synthesized and characterized lithium methyl carbonate (LiOCO ₂CH ₃), a prototypical component of the film. The chemical structure of this compound was characterized with nuclear magnetic resonance and Fourier transform infrared spectroscopy (FTIR), and its thermal stability and decomposition pathway was studied by thermogravimetric analysis. The FTIR spectrum of chemically synthesized compound enabled us to resolve multiple products in the passive film on lithium in dimethyl carbonate. Lithium methyl carbonate is only one of the components, the others being lithium oxalate and lithium methoxide.

Original language	English
Pages (from-to)	A64-A68
Journal	Electrochemical and Solid-State Letters
Volume	9
Issue number	2
DOIs	https://doi.org/10.1149/1.2142157
State	Published - 2006
Externally published	Yes

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abstract = "To improve the understanding of passive film formation on metallic lithium in organic electrolyte, we synthesized and characterized lithium methyl carbonate (LiOCO 2CH 3), a prototypical component of the film. The chemical structure of this compound was characterized with nuclear magnetic resonance and Fourier transform infrared spectroscopy (FTIR), and its thermal stability and decomposition pathway was studied by thermogravimetric analysis. The FTIR spectrum of chemically synthesized compound enabled us to resolve multiple products in the passive film on lithium in dimethyl carbonate. Lithium methyl carbonate is only one of the components, the others being lithium oxalate and lithium methoxide.",

author = "Zhuang, {Guorong V.} and Hui Yang and Ross, {Philip N.} and Kang Xu and Jow, {T. Richard}",

year = "2006",

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AU - Zhuang, Guorong V.

AU - Yang, Hui

AU - Ross, Philip N.

AU - Xu, Kang

AU - Jow, T. Richard

PY - 2006

Y1 - 2006

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AB - To improve the understanding of passive film formation on metallic lithium in organic electrolyte, we synthesized and characterized lithium methyl carbonate (LiOCO 2CH 3), a prototypical component of the film. The chemical structure of this compound was characterized with nuclear magnetic resonance and Fourier transform infrared spectroscopy (FTIR), and its thermal stability and decomposition pathway was studied by thermogravimetric analysis. The FTIR spectrum of chemically synthesized compound enabled us to resolve multiple products in the passive film on lithium in dimethyl carbonate. Lithium methyl carbonate is only one of the components, the others being lithium oxalate and lithium methoxide.

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M3 - 文章

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JO - Electrochemical and Solid-State Letters

JF - Electrochemical and Solid-State Letters

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ER -

Lithium methyl carbonate as a reaction product of metallic lithium and dimethyl carbonate

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