Manganese-Catalyzed Ring-Opening Coupling Reactions of Cyclopropanols with Enones

Yong Hui Zhang; Wen Wei Zhang; Ze Yu Zhang; Kai Zhao; Teck Peng Loh

doi:10.1021/acs.orglett.9b01703

Manganese-Catalyzed Ring-Opening Coupling Reactions of Cyclopropanols with Enones

Yong Hui Zhang, Wen Wei Zhang, Ze Yu Zhang, Kai Zhao, Teck Peng Loh

School of Chemistry and Moleculai Engineering

Research output: Contribution to journal › Article › peer-review

44 Scopus citations

Abstract

A manganese-catalyzed ring-opening coupling reaction of cyclopropanols with enones for the facile and efficient preparation of 1,6-diketones is described. A wide array of synthetically important 1,6-diketones bearing manifold functional groups are obtained with up to 93% yield. These reactions feature broad substrate scopes, environmentally benign conditions, inexpensive catalyst, and operational simplicity.

Original language	English
Pages (from-to)	5101-5105
Number of pages	5
Journal	Organic Letters
Volume	21
Issue number	13
DOIs	https://doi.org/10.1021/acs.orglett.9b01703
State	Published - 17 Jun 2019

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abstract = "A manganese-catalyzed ring-opening coupling reaction of cyclopropanols with enones for the facile and efficient preparation of 1,6-diketones is described. A wide array of synthetically important 1,6-diketones bearing manifold functional groups are obtained with up to 93% yield. These reactions feature broad substrate scopes, environmentally benign conditions, inexpensive catalyst, and operational simplicity.",

author = "Zhang, {Yong Hui} and Zhang, {Wen Wei} and Zhang, {Ze Yu} and Kai Zhao and Loh, {Teck Peng}",

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AU - Zhang, Ze Yu

AU - Zhao, Kai

AU - Loh, Teck Peng

PY - 2019/6/17

Y1 - 2019/6/17

N2 - A manganese-catalyzed ring-opening coupling reaction of cyclopropanols with enones for the facile and efficient preparation of 1,6-diketones is described. A wide array of synthetically important 1,6-diketones bearing manifold functional groups are obtained with up to 93% yield. These reactions feature broad substrate scopes, environmentally benign conditions, inexpensive catalyst, and operational simplicity.

AB - A manganese-catalyzed ring-opening coupling reaction of cyclopropanols with enones for the facile and efficient preparation of 1,6-diketones is described. A wide array of synthetically important 1,6-diketones bearing manifold functional groups are obtained with up to 93% yield. These reactions feature broad substrate scopes, environmentally benign conditions, inexpensive catalyst, and operational simplicity.

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Manganese-Catalyzed Ring-Opening Coupling Reactions of Cyclopropanols with Enones

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