Measurement and correlation solubility and mixing properties of l-malic acid in pure and mixed organic solvents

Yumei Kai; Yonghong Hu; Zheng Cao; Xiang Liu; Yan Liu; Wenge Yang

doi:10.1016/j.fluid.2013.10.011

Measurement and correlation solubility and mixing properties of l-malic acid in pure and mixed organic solvents

Yumei Kai, Yonghong Hu, Zheng Cao, Xiang Liu, Yan Liu, Wenge Yang

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

The solubilities of l-malic acid in pure and mixture organic solvents were measured from 278.15 to 323.15K using the laser monitoring observation system. The modified Apelblat equation, the semi-empirical Buchowski-Ksiazczak λh equation and the Combined Nearly Ideal Binary Solvent/Redlich (CNIBS/R-K) equation were proposed to correlate the experimental data. In pure and mixed solvents, the 100RD (relative deviation) <3.61 and 7.58, respectively, the 10⁴RMSD (root-mean-square deviations) <3.07 and 2.28, respectively, so the equations selected in this work fit the data very well. Van't Hoff equation was used to predict the dissolution enthalpy and entropy of l-malic acid in the corresponding solvents.

Original language	English
Pages (from-to)	466-471
Number of pages	6
Journal	Fluid Phase Equilibria
Volume	360
DOIs	https://doi.org/10.1016/j.fluid.2013.10.011
State	Published - 25 Dec 2013

Keywords

Apelblat equation
Buchowski-Ksiazczak equation
Combined Nearly Ideal Binary Solvent/Redlich equation
L-Malic acid
Van't Hoff equation

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10.1016/j.fluid.2013.10.011

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title = "Measurement and correlation solubility and mixing properties of l-malic acid in pure and mixed organic solvents",

abstract = "The solubilities of l-malic acid in pure and mixture organic solvents were measured from 278.15 to 323.15K using the laser monitoring observation system. The modified Apelblat equation, the semi-empirical Buchowski-Ksiazczak λh equation and the Combined Nearly Ideal Binary Solvent/Redlich (CNIBS/R-K) equation were proposed to correlate the experimental data. In pure and mixed solvents, the 100RD (relative deviation) <3.61 and 7.58, respectively, the 104RMSD (root-mean-square deviations) <3.07 and 2.28, respectively, so the equations selected in this work fit the data very well. Van't Hoff equation was used to predict the dissolution enthalpy and entropy of l-malic acid in the corresponding solvents.",

keywords = "Apelblat equation, Buchowski-Ksiazczak equation, Combined Nearly Ideal Binary Solvent/Redlich equation, L-Malic acid, Van't Hoff equation",

author = "Yumei Kai and Yonghong Hu and Zheng Cao and Xiang Liu and Yan Liu and Wenge Yang",

year = "2013",

month = dec,

day = "25",

doi = "10.1016/j.fluid.2013.10.011",

language = "英语",

volume = "360",

pages = "466--471",

journal = "Fluid Phase Equilibria",

issn = "0378-3812",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Measurement and correlation solubility and mixing properties of l-malic acid in pure and mixed organic solvents

AU - Kai, Yumei

AU - Hu, Yonghong

AU - Cao, Zheng

AU - Liu, Xiang

AU - Liu, Yan

AU - Yang, Wenge

PY - 2013/12/25

Y1 - 2013/12/25

N2 - The solubilities of l-malic acid in pure and mixture organic solvents were measured from 278.15 to 323.15K using the laser monitoring observation system. The modified Apelblat equation, the semi-empirical Buchowski-Ksiazczak λh equation and the Combined Nearly Ideal Binary Solvent/Redlich (CNIBS/R-K) equation were proposed to correlate the experimental data. In pure and mixed solvents, the 100RD (relative deviation) <3.61 and 7.58, respectively, the 104RMSD (root-mean-square deviations) <3.07 and 2.28, respectively, so the equations selected in this work fit the data very well. Van't Hoff equation was used to predict the dissolution enthalpy and entropy of l-malic acid in the corresponding solvents.

AB - The solubilities of l-malic acid in pure and mixture organic solvents were measured from 278.15 to 323.15K using the laser monitoring observation system. The modified Apelblat equation, the semi-empirical Buchowski-Ksiazczak λh equation and the Combined Nearly Ideal Binary Solvent/Redlich (CNIBS/R-K) equation were proposed to correlate the experimental data. In pure and mixed solvents, the 100RD (relative deviation) <3.61 and 7.58, respectively, the 104RMSD (root-mean-square deviations) <3.07 and 2.28, respectively, so the equations selected in this work fit the data very well. Van't Hoff equation was used to predict the dissolution enthalpy and entropy of l-malic acid in the corresponding solvents.

KW - Apelblat equation

KW - Buchowski-Ksiazczak equation

KW - Combined Nearly Ideal Binary Solvent/Redlich equation

KW - L-Malic acid

KW - Van't Hoff equation

UR - http://www.scopus.com/inward/record.url?scp=84886739933&partnerID=8YFLogxK

U2 - 10.1016/j.fluid.2013.10.011

DO - 10.1016/j.fluid.2013.10.011

M3 - 文章

AN - SCOPUS:84886739933

SN - 0378-3812

VL - 360

SP - 466

EP - 471

JO - Fluid Phase Equilibria

JF - Fluid Phase Equilibria

ER -

Measurement and correlation solubility and mixing properties of l-malic acid in pure and mixed organic solvents

Abstract

Keywords

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