Microwave heating synthesis and luminescence property of Eu 3+ doped SrMoO 4 micro-octahedrons

Yun Fei Liu; Shen Hua Dai; Yi Nong Lu; Hui Hua Min

doi:10.1016/j.powtec.2012.01.039

Microwave heating synthesis and luminescence property of Eu ³⁺ doped SrMoO ₄ micro-octahedrons

Yun Fei Liu, Shen Hua Dai, Yi Nong Lu, Hui Hua Min

College of Materials Science and Engineering

Nanjing Tech University

Research output: Contribution to journal › Article › peer-review

44 Scopus citations

Abstract

Uniform SrMoO ₄ micro-octahedrons were synthesized by microwave heating method. The as-prepared products were characterized by several techniques. Results showed that the reactant concentration and reaction time had crucial influence on the morphology of the products. The possible growth process of SrMoO ₄ octahedron was proposed based on the time-dependent shape evolution, which followed Ostwald ripening, crystallization/dissolution, and re-crystallization. Eu ³⁺-doped (1-20mol%) SrMoO ₄ with octahedrons-like polyhedron was prepared under the same condition. The excitation spectrum of SrMoO ₄:Eu ³⁺ was mainly composed of three intense peaks of 305, 393 and 463nm. The characteristic red emission peaks at 612/615nm were ascribed to ⁵D ₀→ ⁷F ₂ transition of Eu ³⁺ ions. The quenching concentration was found at ~15mol% doping of Eu ³⁺.

Original language	English
Pages (from-to)	412-418
Number of pages	7
Journal	Powder Technology
Volume	221
DOIs	https://doi.org/10.1016/j.powtec.2012.01.039
State	Published - May 2012

Keywords

Electron microscopy
Eu doping
Microwave synthesis
Optical materials

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10.1016/j.powtec.2012.01.039

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title = "Microwave heating synthesis and luminescence property of Eu 3+ doped SrMoO 4 micro-octahedrons",

abstract = "Uniform SrMoO 4 micro-octahedrons were synthesized by microwave heating method. The as-prepared products were characterized by several techniques. Results showed that the reactant concentration and reaction time had crucial influence on the morphology of the products. The possible growth process of SrMoO 4 octahedron was proposed based on the time-dependent shape evolution, which followed Ostwald ripening, crystallization/dissolution, and re-crystallization. Eu 3+-doped (1-20mol%) SrMoO 4 with octahedrons-like polyhedron was prepared under the same condition. The excitation spectrum of SrMoO 4:Eu 3+ was mainly composed of three intense peaks of 305, 393 and 463nm. The characteristic red emission peaks at 612/615nm were ascribed to 5D 0→ 7F 2 transition of Eu 3+ ions. The quenching concentration was found at ~15mol% doping of Eu 3+.",

keywords = "Electron microscopy, Eu doping, Microwave synthesis, Optical materials",

author = "Liu, {Yun Fei} and Dai, {Shen Hua} and Lu, {Yi Nong} and Min, {Hui Hua}",

year = "2012",

month = may,

doi = "10.1016/j.powtec.2012.01.039",

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journal = "Powder Technology",

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T1 - Microwave heating synthesis and luminescence property of Eu 3+ doped SrMoO 4 micro-octahedrons

AU - Liu, Yun Fei

AU - Dai, Shen Hua

AU - Lu, Yi Nong

AU - Min, Hui Hua

PY - 2012/5

Y1 - 2012/5

N2 - Uniform SrMoO 4 micro-octahedrons were synthesized by microwave heating method. The as-prepared products were characterized by several techniques. Results showed that the reactant concentration and reaction time had crucial influence on the morphology of the products. The possible growth process of SrMoO 4 octahedron was proposed based on the time-dependent shape evolution, which followed Ostwald ripening, crystallization/dissolution, and re-crystallization. Eu 3+-doped (1-20mol%) SrMoO 4 with octahedrons-like polyhedron was prepared under the same condition. The excitation spectrum of SrMoO 4:Eu 3+ was mainly composed of three intense peaks of 305, 393 and 463nm. The characteristic red emission peaks at 612/615nm were ascribed to 5D 0→ 7F 2 transition of Eu 3+ ions. The quenching concentration was found at ~15mol% doping of Eu 3+.

AB - Uniform SrMoO 4 micro-octahedrons were synthesized by microwave heating method. The as-prepared products were characterized by several techniques. Results showed that the reactant concentration and reaction time had crucial influence on the morphology of the products. The possible growth process of SrMoO 4 octahedron was proposed based on the time-dependent shape evolution, which followed Ostwald ripening, crystallization/dissolution, and re-crystallization. Eu 3+-doped (1-20mol%) SrMoO 4 with octahedrons-like polyhedron was prepared under the same condition. The excitation spectrum of SrMoO 4:Eu 3+ was mainly composed of three intense peaks of 305, 393 and 463nm. The characteristic red emission peaks at 612/615nm were ascribed to 5D 0→ 7F 2 transition of Eu 3+ ions. The quenching concentration was found at ~15mol% doping of Eu 3+.

KW - Electron microscopy

KW - Eu doping

KW - Microwave synthesis

KW - Optical materials

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DO - 10.1016/j.powtec.2012.01.039

M3 - 文章

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SN - 0032-5910

VL - 221

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EP - 418

JO - Powder Technology

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Microwave heating synthesis and luminescence property of Eu ³⁺ doped SrMoO ₄ micro-octahedrons

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Keywords

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