Mild Rh(III)-catalyzed direct C-H bond arylation of (hetero)arenes with arylsilanes in aqueous media

Ming Zhu Lu; Ping Lu; Yun He Xu; Teck Peng Loh

doi:10.1021/ol500754h

Mild Rh(III)-catalyzed direct C-H bond arylation of (hetero)arenes with arylsilanes in aqueous media

Ming Zhu Lu, Ping Lu, Yun He Xu, Teck Peng Loh

Research output: Contribution to journal › Article › peer-review

128 Scopus citations

Abstract

An efficient rhodium(III)-catalyzed C-H bond activation and further direct arylation of (hetero)arenes with organosilanes in aqueous media was developed. This reaction shows good substrate scope and excellent functional group compatibility and gives the products in good yields with excellent regioselectivity.

Original language	English
Pages (from-to)	2614-2617
Number of pages	4
Journal	Organic Letters
Volume	16
Issue number	10
DOIs	https://doi.org/10.1021/ol500754h
State	Published - 16 May 2014
Externally published	Yes

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title = "Mild Rh(III)-catalyzed direct C-H bond arylation of (hetero)arenes with arylsilanes in aqueous media",

abstract = "An efficient rhodium(III)-catalyzed C-H bond activation and further direct arylation of (hetero)arenes with organosilanes in aqueous media was developed. This reaction shows good substrate scope and excellent functional group compatibility and gives the products in good yields with excellent regioselectivity.",

author = "Lu, {Ming Zhu} and Ping Lu and Xu, {Yun He} and Loh, {Teck Peng}",

year = "2014",

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T1 - Mild Rh(III)-catalyzed direct C-H bond arylation of (hetero)arenes with arylsilanes in aqueous media

AU - Lu, Ming Zhu

AU - Lu, Ping

AU - Xu, Yun He

AU - Loh, Teck Peng

PY - 2014/5/16

Y1 - 2014/5/16

N2 - An efficient rhodium(III)-catalyzed C-H bond activation and further direct arylation of (hetero)arenes with organosilanes in aqueous media was developed. This reaction shows good substrate scope and excellent functional group compatibility and gives the products in good yields with excellent regioselectivity.

AB - An efficient rhodium(III)-catalyzed C-H bond activation and further direct arylation of (hetero)arenes with organosilanes in aqueous media was developed. This reaction shows good substrate scope and excellent functional group compatibility and gives the products in good yields with excellent regioselectivity.

UR - http://www.scopus.com/inward/record.url?scp=84900848600&partnerID=8YFLogxK

U2 - 10.1021/ol500754h

DO - 10.1021/ol500754h

M3 - 文章

C2 - 24785121

AN - SCOPUS:84900848600

SN - 1523-7060

VL - 16

SP - 2614

EP - 2617

JO - Organic Letters

JF - Organic Letters

IS - 10

ER -

Mild Rh(III)-catalyzed direct C-H bond arylation of (hetero)arenes with arylsilanes in aqueous media

Abstract

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