Mn-doped ZnFe2O4 nanoparticles with enhanced performances as anode materials for lithium ion batteries

Xiaoqin Tang; Xianhua Hou; Lingmin Yao; Shejun Hu; Xiang Liu; Liangzhong Xiang

doi:10.1016/j.materresbull.2014.05.038

Mn-doped ZnFe₂O₄ nanoparticles with enhanced performances as anode materials for lithium ion batteries

Xiaoqin Tang, Xianhua Hou, Lingmin Yao, Shejun Hu, Xiang Liu, Liangzhong Xiang

School of energy science and engineering

Research output: Contribution to journal › Article › peer-review

68 Scopus citations

Abstract

Nanocrystalline Zn_1-xMn_xFe₂O₄ (x = 0, 0.02, 0.04, 0.06, 0.08, 0.1) have been successfully synthesized by one-step hydrothermal method. The morphologies and electrochemical performance of Mn-doped ZnFe₂O₄ in various proportions were investigated at room temperature, respectively. The Zn_1-xMn _xFe₂O₄ (x = 0.04) electrode in the as-synthesized samples showed the highest specific capacity of 1547 mA h g ^-1 and 1157 mA h g^-1 in the initial discharge/charge process, with a coulombic efficiency of 74.8%. Additionally, excellent cycling stability was performed with a 1214 mA h g^-1 capacity retention at a current density of 100 mA g^-1 after 50 cycles. The corresponding mechanism was proposed which indicated that the Mn-doped ZnFe₂O ₄ nanoparticles experienced an aggregation thermochemical reaction among ZnO, MnO and Fe₂O₃ subparticles.

Original language	English
Pages (from-to)	127-134
Number of pages	8
Journal	Materials Research Bulletin
Volume	57
DOIs	https://doi.org/10.1016/j.materresbull.2014.05.038
State	Published - Sep 2014

Keywords

A. Nanostructures
B. Chemical synthesis
D. Electrochemical properties
D. Energy storage

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This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1016/j.materresbull.2014.05.038

Cite this

@article{66dc097239074e378b63b9a227ef994c,

title = "Mn-doped ZnFe2O4 nanoparticles with enhanced performances as anode materials for lithium ion batteries",

abstract = "Nanocrystalline Zn1-xMnxFe2O4 (x = 0, 0.02, 0.04, 0.06, 0.08, 0.1) have been successfully synthesized by one-step hydrothermal method. The morphologies and electrochemical performance of Mn-doped ZnFe2O4 in various proportions were investigated at room temperature, respectively. The Zn1-xMn xFe2O4 (x = 0.04) electrode in the as-synthesized samples showed the highest specific capacity of 1547 mA h g -1 and 1157 mA h g-1 in the initial discharge/charge process, with a coulombic efficiency of 74.8%. Additionally, excellent cycling stability was performed with a 1214 mA h g-1 capacity retention at a current density of 100 mA g-1 after 50 cycles. The corresponding mechanism was proposed which indicated that the Mn-doped ZnFe2O 4 nanoparticles experienced an aggregation thermochemical reaction among ZnO, MnO and Fe2O3 subparticles.",

keywords = "A. Nanostructures, B. Chemical synthesis, D. Electrochemical properties, D. Energy storage",

author = "Xiaoqin Tang and Xianhua Hou and Lingmin Yao and Shejun Hu and Xiang Liu and Liangzhong Xiang",

year = "2014",

month = sep,

doi = "10.1016/j.materresbull.2014.05.038",

language = "英语",

volume = "57",

pages = "127--134",

journal = "Materials Research Bulletin",

issn = "0025-5408",

publisher = "Elsevier Ltd",

}

TY - JOUR

T1 - Mn-doped ZnFe2O4 nanoparticles with enhanced performances as anode materials for lithium ion batteries

AU - Tang, Xiaoqin

AU - Hou, Xianhua

AU - Yao, Lingmin

AU - Hu, Shejun

AU - Liu, Xiang

AU - Xiang, Liangzhong

PY - 2014/9

Y1 - 2014/9

N2 - Nanocrystalline Zn1-xMnxFe2O4 (x = 0, 0.02, 0.04, 0.06, 0.08, 0.1) have been successfully synthesized by one-step hydrothermal method. The morphologies and electrochemical performance of Mn-doped ZnFe2O4 in various proportions were investigated at room temperature, respectively. The Zn1-xMn xFe2O4 (x = 0.04) electrode in the as-synthesized samples showed the highest specific capacity of 1547 mA h g -1 and 1157 mA h g-1 in the initial discharge/charge process, with a coulombic efficiency of 74.8%. Additionally, excellent cycling stability was performed with a 1214 mA h g-1 capacity retention at a current density of 100 mA g-1 after 50 cycles. The corresponding mechanism was proposed which indicated that the Mn-doped ZnFe2O 4 nanoparticles experienced an aggregation thermochemical reaction among ZnO, MnO and Fe2O3 subparticles.

AB - Nanocrystalline Zn1-xMnxFe2O4 (x = 0, 0.02, 0.04, 0.06, 0.08, 0.1) have been successfully synthesized by one-step hydrothermal method. The morphologies and electrochemical performance of Mn-doped ZnFe2O4 in various proportions were investigated at room temperature, respectively. The Zn1-xMn xFe2O4 (x = 0.04) electrode in the as-synthesized samples showed the highest specific capacity of 1547 mA h g -1 and 1157 mA h g-1 in the initial discharge/charge process, with a coulombic efficiency of 74.8%. Additionally, excellent cycling stability was performed with a 1214 mA h g-1 capacity retention at a current density of 100 mA g-1 after 50 cycles. The corresponding mechanism was proposed which indicated that the Mn-doped ZnFe2O 4 nanoparticles experienced an aggregation thermochemical reaction among ZnO, MnO and Fe2O3 subparticles.

KW - A. Nanostructures

KW - B. Chemical synthesis

KW - D. Electrochemical properties

KW - D. Energy storage

UR - http://www.scopus.com/inward/record.url?scp=84901916782&partnerID=8YFLogxK

U2 - 10.1016/j.materresbull.2014.05.038

DO - 10.1016/j.materresbull.2014.05.038

M3 - 文章

AN - SCOPUS:84901916782

SN - 0025-5408

VL - 57

SP - 127

EP - 134

JO - Materials Research Bulletin

JF - Materials Research Bulletin

ER -