TY - JOUR
T1 - Modeling of specific structure crystallization coupling with dissolution
AU - Ji, Yuanhui
AU - Qian, Hongliang
AU - Liu, Chang
AU - Ji, Xiaoyan
AU - Lu, Xiaohua
AU - Feng, Xin
PY - 2010/3
Y1 - 2010/3
N2 - In this paper, the research framework for specific structure crystallization modeling has been proposed in which four steps are required in order to investigate the rigorous crystallization modeling by thermodynamics. The first is the activity coefficient model of the solution, the second is Solid-Liquid equilibrium, the third and fourth are the dissolution and crystallization kinetics modeling, respectively. Our investigations show that the mechanisms of complex structure formation and microphase transition can be analyzed by combining the dissolution and crystallization kinetics modeling. Moreover, the formation mechanism of the porous KCl has been analyzed, which may provide a reference for the porous structure formation in the advanced material synthesis.
AB - In this paper, the research framework for specific structure crystallization modeling has been proposed in which four steps are required in order to investigate the rigorous crystallization modeling by thermodynamics. The first is the activity coefficient model of the solution, the second is Solid-Liquid equilibrium, the third and fourth are the dissolution and crystallization kinetics modeling, respectively. Our investigations show that the mechanisms of complex structure formation and microphase transition can be analyzed by combining the dissolution and crystallization kinetics modeling. Moreover, the formation mechanism of the porous KCl has been analyzed, which may provide a reference for the porous structure formation in the advanced material synthesis.
KW - Activity coefficient model
KW - Crystallization modeling
KW - Dissolution kinetics
KW - Microphase separation
KW - Porous structures
KW - Solid-liquid equilibrium
UR - http://www.scopus.com/inward/record.url?scp=77952887030&partnerID=8YFLogxK
U2 - 10.1007/s11705-009-0301-7
DO - 10.1007/s11705-009-0301-7
M3 - 文章
AN - SCOPUS:77952887030
SN - 1673-7369
VL - 4
SP - 52
EP - 56
JO - Frontiers of Chemical Engineering in China
JF - Frontiers of Chemical Engineering in China
IS - 1
ER -