N-heterocyclic carbene stabilized digermanium(0)

Anastas Sidiropoulos; Cameron Jones; Andreas Stasch; Susanne Klein; Gernot Frenking

doi:10.1002/anie.200905495

N-heterocyclic carbene stabilized digermanium(0)

Anastas Sidiropoulos, Cameron Jones, Andreas Stasch, Susanne Klein, Gernot Frenking

Research output: Contribution to journal › Article › peer-review

289 Scopus citations

Abstract

Zero Ge! Reductions of an N-heterocyclic carbene (NHC) adduct of GeCl2 with magnesium(1) dimers afford a dimeric compound (see picture), which structural and theoretical studies show to contain a singlet digermanium(0) fragment DGe=GeD datively coordinated by two NHC ligands.

Original language	English
Pages (from-to)	9701-9704
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	48
Issue number	51
DOIs	https://doi.org/10.1002/anie.200905495
State	Published - 14 Dec 2009
Externally published	Yes

Keywords

Carbene ligands
Density functional calculations
Germanium
Magnesium
Metal-metal interactions

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10.1002/anie.200905495

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abstract = "Zero Ge! Reductions of an N-heterocyclic carbene (NHC) adduct of GeCl2 with magnesium(1) dimers afford a dimeric compound (see picture), which structural and theoretical studies show to contain a singlet digermanium(0) fragment DGe=GeD datively coordinated by two NHC ligands.",

keywords = "Carbene ligands, Density functional calculations, Germanium, Magnesium, Metal-metal interactions",

author = "Anastas Sidiropoulos and Cameron Jones and Andreas Stasch and Susanne Klein and Gernot Frenking",

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T1 - N-heterocyclic carbene stabilized digermanium(0)

AU - Sidiropoulos, Anastas

AU - Jones, Cameron

AU - Stasch, Andreas

AU - Klein, Susanne

AU - Frenking, Gernot

PY - 2009/12/14

Y1 - 2009/12/14

N2 - Zero Ge! Reductions of an N-heterocyclic carbene (NHC) adduct of GeCl2 with magnesium(1) dimers afford a dimeric compound (see picture), which structural and theoretical studies show to contain a singlet digermanium(0) fragment DGe=GeD datively coordinated by two NHC ligands.

AB - Zero Ge! Reductions of an N-heterocyclic carbene (NHC) adduct of GeCl2 with magnesium(1) dimers afford a dimeric compound (see picture), which structural and theoretical studies show to contain a singlet digermanium(0) fragment DGe=GeD datively coordinated by two NHC ligands.

KW - Carbene ligands

KW - Density functional calculations

KW - Germanium

KW - Magnesium

KW - Metal-metal interactions

UR - http://www.scopus.com/inward/record.url?scp=71949091870&partnerID=8YFLogxK

U2 - 10.1002/anie.200905495

DO - 10.1002/anie.200905495

M3 - 文章

AN - SCOPUS:71949091870

SN - 1433-7851

VL - 48

SP - 9701

EP - 9704

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 51

ER -

N-heterocyclic carbene stabilized digermanium(0)

Abstract

Keywords

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