N-Phenylmaleimide as a new polymerizable additive for overcharge protection of lithium-ion batteries

B. Wang; Q. Xia; P. Zhang; G. C. Li; Y. P. Wu; H. J. Luo; S. Y. Zhao; T. van Ree

doi:10.1016/j.elecom.2008.02.011

N-Phenylmaleimide as a new polymerizable additive for overcharge protection of lithium-ion batteries

B. Wang, Q. Xia, P. Zhang, G. C. Li, Y. P. Wu, H. J. Luo, S. Y. Zhao, T. van Ree

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

Electrochemical properties and overcharge behavior of N-phenylmaleimide (NPM) as a new polymerizable electrolyte additive for overcharge protection of lithium-ion batteries are studied by cyclic voltammetry, charge-discharge performance, electrochemical impedance spectroscopy and scanning electron microscopy (SEM). The results show that NPM can electrochemically polymerize at the overcharge potential of 3.8-4.2 V (vs. Li/Li⁺) and form a thin polymer film on the surface of the cathode, thus preventing voltage runaway. On the other hand, the use of NPM as an overcharge protection electrolyte additive does not influence the normal performance of lithium-ion batteries.

Original language	English
Pages (from-to)	727-730
Number of pages	4
Journal	Electrochemistry Communications
Volume	10
Issue number	5
DOIs	https://doi.org/10.1016/j.elecom.2008.02.011
State	Published - May 2008
Externally published	Yes

Keywords

Additive
Electropolymerization
Lithium-ion battery
N-Phenylmaleimide
Overcharge protection

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.elecom.2008.02.011

Cite this

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title = "N-Phenylmaleimide as a new polymerizable additive for overcharge protection of lithium-ion batteries",

abstract = "Electrochemical properties and overcharge behavior of N-phenylmaleimide (NPM) as a new polymerizable electrolyte additive for overcharge protection of lithium-ion batteries are studied by cyclic voltammetry, charge-discharge performance, electrochemical impedance spectroscopy and scanning electron microscopy (SEM). The results show that NPM can electrochemically polymerize at the overcharge potential of 3.8-4.2 V (vs. Li/Li+) and form a thin polymer film on the surface of the cathode, thus preventing voltage runaway. On the other hand, the use of NPM as an overcharge protection electrolyte additive does not influence the normal performance of lithium-ion batteries.",

keywords = "Additive, Electropolymerization, Lithium-ion battery, N-Phenylmaleimide, Overcharge protection",

author = "B. Wang and Q. Xia and P. Zhang and Li, {G. C.} and Wu, {Y. P.} and Luo, {H. J.} and Zhao, {S. Y.} and {van Ree}, T.",

year = "2008",

month = may,

doi = "10.1016/j.elecom.2008.02.011",

language = "英语",

volume = "10",

pages = "727--730",

journal = "Electrochemistry Communications",

issn = "1388-2481",

publisher = "Elsevier Inc.",

number = "5",

}

TY - JOUR

T1 - N-Phenylmaleimide as a new polymerizable additive for overcharge protection of lithium-ion batteries

AU - Wang, B.

AU - Xia, Q.

AU - Zhang, P.

AU - Li, G. C.

AU - Wu, Y. P.

AU - Luo, H. J.

AU - Zhao, S. Y.

AU - van Ree, T.

PY - 2008/5

Y1 - 2008/5

N2 - Electrochemical properties and overcharge behavior of N-phenylmaleimide (NPM) as a new polymerizable electrolyte additive for overcharge protection of lithium-ion batteries are studied by cyclic voltammetry, charge-discharge performance, electrochemical impedance spectroscopy and scanning electron microscopy (SEM). The results show that NPM can electrochemically polymerize at the overcharge potential of 3.8-4.2 V (vs. Li/Li+) and form a thin polymer film on the surface of the cathode, thus preventing voltage runaway. On the other hand, the use of NPM as an overcharge protection electrolyte additive does not influence the normal performance of lithium-ion batteries.

AB - Electrochemical properties and overcharge behavior of N-phenylmaleimide (NPM) as a new polymerizable electrolyte additive for overcharge protection of lithium-ion batteries are studied by cyclic voltammetry, charge-discharge performance, electrochemical impedance spectroscopy and scanning electron microscopy (SEM). The results show that NPM can electrochemically polymerize at the overcharge potential of 3.8-4.2 V (vs. Li/Li+) and form a thin polymer film on the surface of the cathode, thus preventing voltage runaway. On the other hand, the use of NPM as an overcharge protection electrolyte additive does not influence the normal performance of lithium-ion batteries.

KW - Additive

KW - Electropolymerization

KW - Lithium-ion battery

KW - N-Phenylmaleimide

KW - Overcharge protection

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U2 - 10.1016/j.elecom.2008.02.011

DO - 10.1016/j.elecom.2008.02.011

M3 - 文章

AN - SCOPUS:42649142578

SN - 1388-2481

VL - 10

SP - 727

EP - 730

JO - Electrochemistry Communications

JF - Electrochemistry Communications

IS - 5

ER -

N-Phenylmaleimide as a new polymerizable additive for overcharge protection of lithium-ion batteries

Abstract

Keywords

UN SDGs

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