N-sulfinylcarboximidates as a new class of chiral bidentate ligands: Application to asymmetric coordination chemistry

Zhijie Lin; Mehmet Ali Celik; Chen Fu; Klaus Harms; Gernot Frenking; Eric Meggers

doi:10.1002/chem.201101886

N-sulfinylcarboximidates as a new class of chiral bidentate ligands: Application to asymmetric coordination chemistry

Zhijie Lin, Mehmet Ali Celik, Chen Fu, Klaus Harms, Gernot Frenking, Eric Meggers

University of Marburg

Research output: Contribution to journal › Article › peer-review

26 Scopus citations

Abstract

A class of its own: A new chiral bidentate ligand, N-acetyl-tert- butanesulfinamide, was applied to the asymmetric synthesis of octahedral ruthenium polypyridyl complexes. This new class of ligands coordinates in a bidentate fashion through its deprotonated N-sulfinylcarboximidate form (see scheme). This sulfinamide auxiliary should be highly valuable for the efficient asymmetric synthesis of a large variety of ruthenium complexes.

Original language	English
Pages (from-to)	12602-12605
Number of pages	4
Journal	Chemistry - A European Journal
Volume	17
Issue number	45
DOIs	https://doi.org/10.1002/chem.201101886
State	Published - 4 Nov 2011
Externally published	Yes

Keywords

asymmetric synthesis
chiral auxiliaries
coordination modes
ligand effects
ruthenium

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abstract = "A class of its own: A new chiral bidentate ligand, N-acetyl-tert- butanesulfinamide, was applied to the asymmetric synthesis of octahedral ruthenium polypyridyl complexes. This new class of ligands coordinates in a bidentate fashion through its deprotonated N-sulfinylcarboximidate form (see scheme). This sulfinamide auxiliary should be highly valuable for the efficient asymmetric synthesis of a large variety of ruthenium complexes.",

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T1 - N-sulfinylcarboximidates as a new class of chiral bidentate ligands

T2 - Application to asymmetric coordination chemistry

AU - Lin, Zhijie

AU - Celik, Mehmet Ali

AU - Fu, Chen

AU - Harms, Klaus

AU - Frenking, Gernot

AU - Meggers, Eric

PY - 2011/11/4

Y1 - 2011/11/4

N2 - A class of its own: A new chiral bidentate ligand, N-acetyl-tert- butanesulfinamide, was applied to the asymmetric synthesis of octahedral ruthenium polypyridyl complexes. This new class of ligands coordinates in a bidentate fashion through its deprotonated N-sulfinylcarboximidate form (see scheme). This sulfinamide auxiliary should be highly valuable for the efficient asymmetric synthesis of a large variety of ruthenium complexes.

AB - A class of its own: A new chiral bidentate ligand, N-acetyl-tert- butanesulfinamide, was applied to the asymmetric synthesis of octahedral ruthenium polypyridyl complexes. This new class of ligands coordinates in a bidentate fashion through its deprotonated N-sulfinylcarboximidate form (see scheme). This sulfinamide auxiliary should be highly valuable for the efficient asymmetric synthesis of a large variety of ruthenium complexes.

KW - asymmetric synthesis

KW - chiral auxiliaries

KW - coordination modes

KW - ligand effects

KW - ruthenium

UR - http://www.scopus.com/inward/record.url?scp=80054901265&partnerID=8YFLogxK

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DO - 10.1002/chem.201101886

M3 - 文章

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JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 45

ER -

N-sulfinylcarboximidates as a new class of chiral bidentate ligands: Application to asymmetric coordination chemistry

Abstract

Keywords

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