New 3d-4f heterometallic coordination polymers based on pyrazole-bridged CuIILnIII dinuclear units and sulfate anions: Syntheses, structures, and magnetic properties

Xin Hui Zhou; Yan Hong Peng; Xiao Di Du; Cai Feng Wang; Jing Lin Zuo; Xiao Zeng You

doi:10.1021/cg800848n

New 3d-4f heterometallic coordination polymers based on pyrazole-bridged Cu^IILn^III dinuclear units and sulfate anions: Syntheses, structures, and magnetic properties

Xin Hui Zhou, Yan Hong Peng, Xiao Di Du, Cai Feng Wang, Jing Lin Zuo, Xiao Zeng You

Nanjing University

Research output: Contribution to journal › Article › peer-review

97 Scopus citations

Abstract

A series of 3d-4f heterometallic coordination polymers ([CuLn ₂(PdC)₂(SO₄)(H₂O) ₆]·H₂O)_n (Ln = Tb (1), Dy (2); H ₃pdc = 3,5-pyrazoledicarboxylic acid), ([CuLn₂(PdC) ₂(SO₄)(H₂O)₄]·H ₂O)_n (Ln = Sm (3), Eu (4), Gd (5), Tb (6), Dy (7)) have been hydrothermally synthesized and structurally characterized. The sulfate anions were in situ obtained from oxidation of CuSCN during the reaction. Complexes 1-7 are all constructed from pyrazole-bridged Cu^IILn _III dinuclear units and sulfate anions. Complexes 1 and 2 are isostructural and possess an infinite double-stranded tapelike ID coordination framework. However, complexes 3-7 are interesting 3d-4f heterometallic coordination polymers with similar 3D framework structures. The magnetic properties of compounds 2, 4-6 have been investigated through the magnetic measurements over the temperature range of 1.8-300 K.

Original language	English
Pages (from-to)	1028-1035
Number of pages	8
Journal	Crystal Growth and Design
Volume	9
Issue number	2
DOIs	https://doi.org/10.1021/cg800848n
State	Published - Feb 2009
Externally published	Yes

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title = "New 3d-4f heterometallic coordination polymers based on pyrazole-bridged CuIILnIII dinuclear units and sulfate anions: Syntheses, structures, and magnetic properties",

abstract = "A series of 3d-4f heterometallic coordination polymers ([CuLn 2(PdC)2(SO4)(H2O) 6]·H2O)n (Ln = Tb (1), Dy (2); H 3pdc = 3,5-pyrazoledicarboxylic acid), ([CuLn2(PdC) 2(SO4)(H2O)4]·H 2O)n (Ln = Sm (3), Eu (4), Gd (5), Tb (6), Dy (7)) have been hydrothermally synthesized and structurally characterized. The sulfate anions were in situ obtained from oxidation of CuSCN during the reaction. Complexes 1-7 are all constructed from pyrazole-bridged CuIILn III dinuclear units and sulfate anions. Complexes 1 and 2 are isostructural and possess an infinite double-stranded tapelike ID coordination framework. However, complexes 3-7 are interesting 3d-4f heterometallic coordination polymers with similar 3D framework structures. The magnetic properties of compounds 2, 4-6 have been investigated through the magnetic measurements over the temperature range of 1.8-300 K.",

author = "Zhou, {Xin Hui} and Peng, {Yan Hong} and Du, {Xiao Di} and Wang, {Cai Feng} and Zuo, {Jing Lin} and You, {Xiao Zeng}",

year = "2009",

month = feb,

doi = "10.1021/cg800848n",

language = "英语",

volume = "9",

pages = "1028--1035",

journal = "Crystal Growth and Design",

issn = "1528-7483",

publisher = "American Chemical Society",

number = "2",

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T1 - New 3d-4f heterometallic coordination polymers based on pyrazole-bridged CuIILnIII dinuclear units and sulfate anions

T2 - Syntheses, structures, and magnetic properties

AU - Zhou, Xin Hui

AU - Peng, Yan Hong

AU - Du, Xiao Di

AU - Wang, Cai Feng

AU - Zuo, Jing Lin

AU - You, Xiao Zeng

PY - 2009/2

Y1 - 2009/2

N2 - A series of 3d-4f heterometallic coordination polymers ([CuLn 2(PdC)2(SO4)(H2O) 6]·H2O)n (Ln = Tb (1), Dy (2); H 3pdc = 3,5-pyrazoledicarboxylic acid), ([CuLn2(PdC) 2(SO4)(H2O)4]·H 2O)n (Ln = Sm (3), Eu (4), Gd (5), Tb (6), Dy (7)) have been hydrothermally synthesized and structurally characterized. The sulfate anions were in situ obtained from oxidation of CuSCN during the reaction. Complexes 1-7 are all constructed from pyrazole-bridged CuIILn III dinuclear units and sulfate anions. Complexes 1 and 2 are isostructural and possess an infinite double-stranded tapelike ID coordination framework. However, complexes 3-7 are interesting 3d-4f heterometallic coordination polymers with similar 3D framework structures. The magnetic properties of compounds 2, 4-6 have been investigated through the magnetic measurements over the temperature range of 1.8-300 K.

AB - A series of 3d-4f heterometallic coordination polymers ([CuLn 2(PdC)2(SO4)(H2O) 6]·H2O)n (Ln = Tb (1), Dy (2); H 3pdc = 3,5-pyrazoledicarboxylic acid), ([CuLn2(PdC) 2(SO4)(H2O)4]·H 2O)n (Ln = Sm (3), Eu (4), Gd (5), Tb (6), Dy (7)) have been hydrothermally synthesized and structurally characterized. The sulfate anions were in situ obtained from oxidation of CuSCN during the reaction. Complexes 1-7 are all constructed from pyrazole-bridged CuIILn III dinuclear units and sulfate anions. Complexes 1 and 2 are isostructural and possess an infinite double-stranded tapelike ID coordination framework. However, complexes 3-7 are interesting 3d-4f heterometallic coordination polymers with similar 3D framework structures. The magnetic properties of compounds 2, 4-6 have been investigated through the magnetic measurements over the temperature range of 1.8-300 K.

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DO - 10.1021/cg800848n

M3 - 文章

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SN - 1528-7483

VL - 9

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JO - Crystal Growth and Design

JF - Crystal Growth and Design

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New 3d-4f heterometallic coordination polymers based on pyrazole-bridged Cu^IILn^III dinuclear units and sulfate anions: Syntheses, structures, and magnetic properties

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