New ion-pair nickel(III) complexes containing [Ni('S2')2] ('S2'2- = 1,2-benzenedithiolate) fragments: Synthesis, crystal structure and properties

Jing Li Xie; Xiao Ming Ren; Cheng He; You Song; Chun Yin Duan; Song Gao; Qing Jin Meng

doi:10.1016/S0277-5387(02)01334-7

New ion-pair nickel(III) complexes containing [Ni('S₂')₂] ('S₂'^2- = 1,2-benzenedithiolate) fragments: Synthesis, crystal structure and properties

Jing Li Xie, Xiao Ming Ren, Cheng He, You Song, Chun Yin Duan, Song Gao, Qing Jin Meng

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Two new ion-pair complexes [1-(4′-fluorobenzyl)pyridinium][Ni(bdt)₂] (1) and [1-(4′-bromobenzyl)pyridinium][Ni(bdt)2] (2), in which bdt^2- = 1,2-benzenedithiolate ('S₂'^2-), have been prepared and characterized. X-ray structural analyses showed that 1 and 2 are isostructural, and the anions are centrosymmetric. The 2 non-equiv. anions form different uniform-spaced stacking pattern in 1 and 2. The magnetic measurements of 1 and 2 indicate ferromagnetic behavior in the antiferromagnetic exchange system, which may arise from spin canting. Cyclovoltammetry revealed two quasi-reversible one-electron steps for 1 and 2, which are attributed to Ni(IV/III) and Ni(III/II) redox couples.

Original language	English
Pages (from-to)	299-305
Number of pages	7
Journal	Polyhedron
Volume	22
Issue number	2
DOIs	https://doi.org/10.1016/S0277-5387(02)01334-7
State	Published - 15 Jan 2003
Externally published	Yes

Keywords

Crystal structures
Magnetism
Ni(III) thiolate complexes
Spin canting

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10.1016/S0277-5387(02)01334-7

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title = "New ion-pair nickel(III) complexes containing [Ni('S2')2] ('S2'2- = 1,2-benzenedithiolate) fragments: Synthesis, crystal structure and properties",

abstract = "Two new ion-pair complexes [1-(4′-fluorobenzyl)pyridinium][Ni(bdt)2] (1) and [1-(4′-bromobenzyl)pyridinium][Ni(bdt)2] (2), in which bdt2- = 1,2-benzenedithiolate ('S2'2-), have been prepared and characterized. X-ray structural analyses showed that 1 and 2 are isostructural, and the anions are centrosymmetric. The 2 non-equiv. anions form different uniform-spaced stacking pattern in 1 and 2. The magnetic measurements of 1 and 2 indicate ferromagnetic behavior in the antiferromagnetic exchange system, which may arise from spin canting. Cyclovoltammetry revealed two quasi-reversible one-electron steps for 1 and 2, which are attributed to Ni(IV/III) and Ni(III/II) redox couples.",

keywords = "Crystal structures, Magnetism, Ni(III) thiolate complexes, Spin canting",

author = "Xie, {Jing Li} and Ren, {Xiao Ming} and Cheng He and You Song and Duan, {Chun Yin} and Song Gao and Meng, {Qing Jin}",

year = "2003",

month = jan,

day = "15",

doi = "10.1016/S0277-5387(02)01334-7",

language = "英语",

volume = "22",

pages = "299--305",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd",

number = "2",

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TY - JOUR

T1 - New ion-pair nickel(III) complexes containing [Ni('S2')2] ('S2'2- = 1,2-benzenedithiolate) fragments

T2 - Synthesis, crystal structure and properties

AU - Xie, Jing Li

AU - Ren, Xiao Ming

AU - He, Cheng

AU - Song, You

AU - Duan, Chun Yin

AU - Gao, Song

AU - Meng, Qing Jin

PY - 2003/1/15

Y1 - 2003/1/15

N2 - Two new ion-pair complexes [1-(4′-fluorobenzyl)pyridinium][Ni(bdt)2] (1) and [1-(4′-bromobenzyl)pyridinium][Ni(bdt)2] (2), in which bdt2- = 1,2-benzenedithiolate ('S2'2-), have been prepared and characterized. X-ray structural analyses showed that 1 and 2 are isostructural, and the anions are centrosymmetric. The 2 non-equiv. anions form different uniform-spaced stacking pattern in 1 and 2. The magnetic measurements of 1 and 2 indicate ferromagnetic behavior in the antiferromagnetic exchange system, which may arise from spin canting. Cyclovoltammetry revealed two quasi-reversible one-electron steps for 1 and 2, which are attributed to Ni(IV/III) and Ni(III/II) redox couples.

AB - Two new ion-pair complexes [1-(4′-fluorobenzyl)pyridinium][Ni(bdt)2] (1) and [1-(4′-bromobenzyl)pyridinium][Ni(bdt)2] (2), in which bdt2- = 1,2-benzenedithiolate ('S2'2-), have been prepared and characterized. X-ray structural analyses showed that 1 and 2 are isostructural, and the anions are centrosymmetric. The 2 non-equiv. anions form different uniform-spaced stacking pattern in 1 and 2. The magnetic measurements of 1 and 2 indicate ferromagnetic behavior in the antiferromagnetic exchange system, which may arise from spin canting. Cyclovoltammetry revealed two quasi-reversible one-electron steps for 1 and 2, which are attributed to Ni(IV/III) and Ni(III/II) redox couples.

KW - Crystal structures

KW - Magnetism

KW - Ni(III) thiolate complexes

KW - Spin canting

UR - http://www.scopus.com/inward/record.url?scp=0037439204&partnerID=8YFLogxK

U2 - 10.1016/S0277-5387(02)01334-7

DO - 10.1016/S0277-5387(02)01334-7

M3 - 文章

AN - SCOPUS:0037439204

SN - 0277-5387

VL - 22

SP - 299

EP - 305

JO - Polyhedron

JF - Polyhedron

IS - 2

ER -

New ion-pair nickel(III) complexes containing [Ni('S₂')₂] ('S₂'^2- = 1,2-benzenedithiolate) fragments: Synthesis, crystal structure and properties

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Keywords

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