Nickel-catalyzed direct cross-coupling of heterocyclic phosphonium salts with aryl bromides

Yan Ying Cui; Wen Xin Li; Na Na Ma; Chuanji Shen; Xiaocong Zhou; Xue Qiang Chu; Weidong Rao; Zhi Liang Shen

doi:10.1039/d1qo01474a

Nickel-catalyzed direct cross-coupling of heterocyclic phosphonium salts with aryl bromides

Yan Ying Cui, Wen Xin Li, Na Na Ma, Chuanji Shen, Xiaocong Zhou, Xue Qiang Chu, Weidong Rao, Zhi Liang Shen

School of Chemistry and Moleculai Engineering

Research output: Contribution to journal › Article › peer-review

33 Scopus citations

Abstract

The direct cross-coupling of heterocyclic phosphonium salts with aryl bromides was successfully realized by performing the reactions in THF at ambient temperature with the aid of a nickel(ii) catalyst, the 1,10-phenanthroline-5,6-dione ligand, magnesium turnings, and lithium chloride, providing an easy access to 4-arylated pyridine, quinoline, quinoxaline, and pyrazine.

Original language	English
Pages (from-to)	6931-6936
Number of pages	6
Journal	Organic Chemistry Frontiers
Volume	8
Issue number	24
DOIs	https://doi.org/10.1039/d1qo01474a
State	Published - 21 Dec 2021

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title = "Nickel-catalyzed direct cross-coupling of heterocyclic phosphonium salts with aryl bromides",

abstract = "The direct cross-coupling of heterocyclic phosphonium salts with aryl bromides was successfully realized by performing the reactions in THF at ambient temperature with the aid of a nickel(ii) catalyst, the 1,10-phenanthroline-5,6-dione ligand, magnesium turnings, and lithium chloride, providing an easy access to 4-arylated pyridine, quinoline, quinoxaline, and pyrazine.",

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T1 - Nickel-catalyzed direct cross-coupling of heterocyclic phosphonium salts with aryl bromides

AU - Cui, Yan Ying

AU - Li, Wen Xin

AU - Ma, Na Na

AU - Shen, Chuanji

AU - Zhou, Xiaocong

AU - Chu, Xue Qiang

AU - Rao, Weidong

AU - Shen, Zhi Liang

PY - 2021/12/21

Y1 - 2021/12/21

N2 - The direct cross-coupling of heterocyclic phosphonium salts with aryl bromides was successfully realized by performing the reactions in THF at ambient temperature with the aid of a nickel(ii) catalyst, the 1,10-phenanthroline-5,6-dione ligand, magnesium turnings, and lithium chloride, providing an easy access to 4-arylated pyridine, quinoline, quinoxaline, and pyrazine.

AB - The direct cross-coupling of heterocyclic phosphonium salts with aryl bromides was successfully realized by performing the reactions in THF at ambient temperature with the aid of a nickel(ii) catalyst, the 1,10-phenanthroline-5,6-dione ligand, magnesium turnings, and lithium chloride, providing an easy access to 4-arylated pyridine, quinoline, quinoxaline, and pyrazine.

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U2 - 10.1039/d1qo01474a

DO - 10.1039/d1qo01474a

M3 - 文章

AN - SCOPUS:85121041948

SN - 2052-4110

VL - 8

SP - 6931

EP - 6936

JO - Organic Chemistry Frontiers

JF - Organic Chemistry Frontiers

IS - 24

ER -

Nickel-catalyzed direct cross-coupling of heterocyclic phosphonium salts with aryl bromides

Abstract

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