Novel heterometallic Fe-Ru2-Fe arrays via "complex of complexes" approach

Cai Feng Wang; Lin Zuo Jing; Jie Wen Ying; Tong Ren; Xiao Zeng You

doi:10.1021/ic8011684

Novel heterometallic Fe-Ru₂-Fe arrays via "complex of complexes" approach

Cai Feng Wang, Lin Zuo Jing, Jie Wen Ying, Tong Ren, Xiao Zeng You

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

Four tetranuclear heterometallic compounds, [(Tp)Fe(CN)₃] ₂(Ru₂(DMBA)₄] (1), [(MeTp)Fe(CN) ₃]₂[Ru₂(DMBA)₄] (2), [( ⁱBuTp)Fe(CN)₃]₂[Ru₂(DMBA) ₄] (3), and [(PhTp)Fe(CN)₃]₂[Ru ₂(DMBA)₄] (4) [DMBA = N,N′-dimethylbenzamidinate, Tp = (hydrotris(pyrazolyl)borate, MeTp = (methyltris(pyrazolyl)borate, ⁱBuTp = (2-methylpropyltris(pyrazolyl)borate, and PhTp = (tris(pyrazolyl)phenylborate)] were prepared from the combination of Ru ₂(DMBA)₄(NO₃)₂ and an appropriate [(RTp)Fe(CN)₃]^-. Molecular structures of compounds 1-4 were established using single-crystal X-ray diffraction, and all feature a linear Fe-C≡N-Ru-Ru-N≡C-Fe array. The magnetic study revealed that the temperature dependence of _χMT is mostly attributed to the zero-field splitting of the Ru₂ center, indicating the absence of strong spin coupling among three metallic centers. The electronic independence was further confirmed by the vis-NIR spectroscopic studies. Also described are the voltammetric properties of these compounds.

Original language	English
Pages (from-to)	9716-9722
Number of pages	7
Journal	Inorganic Chemistry
Volume	47
Issue number	20
DOIs	https://doi.org/10.1021/ic8011684
State	Published - 20 Oct 2008
Externally published	Yes

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@article{3d53d225a8fc4b67932f0f1989691602,

title = "Novel heterometallic Fe-Ru2-Fe arrays via {"}complex of complexes{"} approach",

abstract = "Four tetranuclear heterometallic compounds, [(Tp)Fe(CN)3] 2(Ru2(DMBA)4] (1), [(MeTp)Fe(CN) 3]2[Ru2(DMBA)4] (2), [( iBuTp)Fe(CN)3]2[Ru2(DMBA) 4] (3), and [(PhTp)Fe(CN)3]2[Ru 2(DMBA)4] (4) [DMBA = N,N′-dimethylbenzamidinate, Tp = (hydrotris(pyrazolyl)borate, MeTp = (methyltris(pyrazolyl)borate, iBuTp = (2-methylpropyltris(pyrazolyl)borate, and PhTp = (tris(pyrazolyl)phenylborate)] were prepared from the combination of Ru 2(DMBA)4(NO3)2 and an appropriate [(RTp)Fe(CN)3]-. Molecular structures of compounds 1-4 were established using single-crystal X-ray diffraction, and all feature a linear Fe-C≡N-Ru-Ru-N≡C-Fe array. The magnetic study revealed that the temperature dependence of χMT is mostly attributed to the zero-field splitting of the Ru2 center, indicating the absence of strong spin coupling among three metallic centers. The electronic independence was further confirmed by the vis-NIR spectroscopic studies. Also described are the voltammetric properties of these compounds.",

author = "Wang, {Cai Feng} and Jing, {Lin Zuo} and Ying, {Jie Wen} and Tong Ren and You, {Xiao Zeng}",

year = "2008",

month = oct,

day = "20",

doi = "10.1021/ic8011684",

language = "英语",

volume = "47",

pages = "9716--9722",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "20",

}

TY - JOUR

T1 - Novel heterometallic Fe-Ru2-Fe arrays via "complex of complexes" approach

AU - Wang, Cai Feng

AU - Jing, Lin Zuo

AU - Ying, Jie Wen

AU - Ren, Tong

AU - You, Xiao Zeng

PY - 2008/10/20

Y1 - 2008/10/20

N2 - Four tetranuclear heterometallic compounds, [(Tp)Fe(CN)3] 2(Ru2(DMBA)4] (1), [(MeTp)Fe(CN) 3]2[Ru2(DMBA)4] (2), [( iBuTp)Fe(CN)3]2[Ru2(DMBA) 4] (3), and [(PhTp)Fe(CN)3]2[Ru 2(DMBA)4] (4) [DMBA = N,N′-dimethylbenzamidinate, Tp = (hydrotris(pyrazolyl)borate, MeTp = (methyltris(pyrazolyl)borate, iBuTp = (2-methylpropyltris(pyrazolyl)borate, and PhTp = (tris(pyrazolyl)phenylborate)] were prepared from the combination of Ru 2(DMBA)4(NO3)2 and an appropriate [(RTp)Fe(CN)3]-. Molecular structures of compounds 1-4 were established using single-crystal X-ray diffraction, and all feature a linear Fe-C≡N-Ru-Ru-N≡C-Fe array. The magnetic study revealed that the temperature dependence of χMT is mostly attributed to the zero-field splitting of the Ru2 center, indicating the absence of strong spin coupling among three metallic centers. The electronic independence was further confirmed by the vis-NIR spectroscopic studies. Also described are the voltammetric properties of these compounds.

AB - Four tetranuclear heterometallic compounds, [(Tp)Fe(CN)3] 2(Ru2(DMBA)4] (1), [(MeTp)Fe(CN) 3]2[Ru2(DMBA)4] (2), [( iBuTp)Fe(CN)3]2[Ru2(DMBA) 4] (3), and [(PhTp)Fe(CN)3]2[Ru 2(DMBA)4] (4) [DMBA = N,N′-dimethylbenzamidinate, Tp = (hydrotris(pyrazolyl)borate, MeTp = (methyltris(pyrazolyl)borate, iBuTp = (2-methylpropyltris(pyrazolyl)borate, and PhTp = (tris(pyrazolyl)phenylborate)] were prepared from the combination of Ru 2(DMBA)4(NO3)2 and an appropriate [(RTp)Fe(CN)3]-. Molecular structures of compounds 1-4 were established using single-crystal X-ray diffraction, and all feature a linear Fe-C≡N-Ru-Ru-N≡C-Fe array. The magnetic study revealed that the temperature dependence of χMT is mostly attributed to the zero-field splitting of the Ru2 center, indicating the absence of strong spin coupling among three metallic centers. The electronic independence was further confirmed by the vis-NIR spectroscopic studies. Also described are the voltammetric properties of these compounds.

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U2 - 10.1021/ic8011684

DO - 10.1021/ic8011684

M3 - 文章

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SN - 0020-1669

VL - 47

SP - 9716

EP - 9722

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 20

ER -

Novel heterometallic Fe-Ru₂-Fe arrays via "complex of complexes" approach

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