One-pot synthesis of potassium-functionalized mesoporous γ-alumina: A solid superbase

Lin Bing Sun; Jing Yang; Jia Hui Kou; Fang Na Gu; Yuan Chun; Ying Wang; Jian Hua Zhu; Zhi Gang Zou

doi:10.1002/anie.200800034

One-pot synthesis of potassium-functionalized mesoporous γ-alumina: A solid superbase

Lin Bing Sun, Jing Yang, Jia Hui Kou, Fang Na Gu, Yuan Chun, Ying Wang, Jian Hua Zhu, Zhi Gang Zou

Nanjing University

Research output: Contribution to journal › Article › peer-review

100 Scopus citations

Abstract

(Graph Presented) Basically super: Potassium-functionalized mesoporous γ-alumina solid superbases that have a high base strength (H_) of 27.0, a well-expressed mesoporous structure, and which are efficient in the isomerization of 1-hexene are synthesized by a one-pot method. The success of this method can be ascribed to the flexible application of K₂CO ₃ as a pH adjustor and close control of the calcination process (see picture).

Original language	English
Pages (from-to)	3418-3421
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	18
DOIs	https://doi.org/10.1002/anie.200800034
State	Published - 21 Apr 2008
Externally published	Yes

Keywords

Aluminosilicates
Basicity
Heterogeneous catalysis
Mesoporous materials
Template synthesis

Access to Document

10.1002/anie.200800034

Cite this

@article{cc7aadd948ec4dc9b33a39807654feff,

title = "One-pot synthesis of potassium-functionalized mesoporous γ-alumina: A solid superbase",

abstract = "(Graph Presented) Basically super: Potassium-functionalized mesoporous γ-alumina solid superbases that have a high base strength (H_) of 27.0, a well-expressed mesoporous structure, and which are efficient in the isomerization of 1-hexene are synthesized by a one-pot method. The success of this method can be ascribed to the flexible application of K2CO 3 as a pH adjustor and close control of the calcination process (see picture).",

keywords = "Aluminosilicates, Basicity, Heterogeneous catalysis, Mesoporous materials, Template synthesis",

author = "Sun, {Lin Bing} and Jing Yang and Kou, {Jia Hui} and Gu, {Fang Na} and Yuan Chun and Ying Wang and Zhu, {Jian Hua} and Zou, {Zhi Gang}",

year = "2008",

month = apr,

day = "21",

doi = "10.1002/anie.200800034",

language = "英语",

volume = "47",

pages = "3418--3421",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "18",

}

TY - JOUR

T1 - One-pot synthesis of potassium-functionalized mesoporous γ-alumina

T2 - A solid superbase

AU - Sun, Lin Bing

AU - Yang, Jing

AU - Kou, Jia Hui

AU - Gu, Fang Na

AU - Chun, Yuan

AU - Wang, Ying

AU - Zhu, Jian Hua

AU - Zou, Zhi Gang

PY - 2008/4/21

Y1 - 2008/4/21

N2 - (Graph Presented) Basically super: Potassium-functionalized mesoporous γ-alumina solid superbases that have a high base strength (H_) of 27.0, a well-expressed mesoporous structure, and which are efficient in the isomerization of 1-hexene are synthesized by a one-pot method. The success of this method can be ascribed to the flexible application of K2CO 3 as a pH adjustor and close control of the calcination process (see picture).

AB - (Graph Presented) Basically super: Potassium-functionalized mesoporous γ-alumina solid superbases that have a high base strength (H_) of 27.0, a well-expressed mesoporous structure, and which are efficient in the isomerization of 1-hexene are synthesized by a one-pot method. The success of this method can be ascribed to the flexible application of K2CO 3 as a pH adjustor and close control of the calcination process (see picture).

KW - Aluminosilicates

KW - Basicity

KW - Heterogeneous catalysis

KW - Mesoporous materials

KW - Template synthesis

UR - http://www.scopus.com/inward/record.url?scp=53549102502&partnerID=8YFLogxK

U2 - 10.1002/anie.200800034

DO - 10.1002/anie.200800034

M3 - 文章

AN - SCOPUS:53549102502

SN - 1433-7851

VL - 47

SP - 3418

EP - 3421

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 18

ER -

One-pot synthesis of potassium-functionalized mesoporous γ-alumina: A solid superbase

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this