One stone kills four birds: A novel diazaperinone 12H-pyrazino[2′, 3′:3,4]pyrrolo[1,2-a]perimidin-12-one recognizes four different metal ions

Jian Feng Zhao; Yi Liu; Jiayun Bethia Soh; Yong Xin Li; Rakesh Ganguly; Kai Qi Ye; Fengwei Huo; Ling Huang; Alfred Iing Yoong Tok; Joachim Say Chye Loo; Qichun Zhang

doi:10.1016/j.tetlet.2012.08.106

One stone kills four birds: A novel diazaperinone 12H-pyrazino[2′, 3′:3,4]pyrrolo[1,2-a]perimidin-12-one recognizes four different metal ions

Jian Feng Zhao, Yi Liu, Jiayun Bethia Soh, Yong Xin Li, Rakesh Ganguly, Kai Qi Ye, Fengwei Huo, Ling Huang, Alfred Iing Yoong Tok, Joachim Say Chye Loo, Qichun Zhang

Nanyang Technological University

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

A novel diazaperinone 12H-pyrazino[2′,3′:3,4]pyrrolo[1,2-a] perimidin-12-one has been successfully synthesized through a one-step condensation. Single crystal X-ray analysis shows that the product is of planar structure with strong π⋯π interactions and H-bonding. Interestingly, the 12H-pyrazino[2′,3′:3,4]pyrrolo[1,2-a]perimidin- 12-one can recognize three different metal cations Cu ²⁺, Ag ⁺ and Hg ²⁺ via naked eye visualization, and shows turn-on fluorescence for Fe ³⁺ and Ag ⁺ among the 22 metal cations.

Original language	English
Pages (from-to)	6044-6047
Number of pages	4
Journal	Tetrahedron Letters
Volume	53
Issue number	45
DOIs	https://doi.org/10.1016/j.tetlet.2012.08.106
State	Published - 7 Nov 2012
Externally published	Yes

Keywords

Diazaperinone
Multiple metal cations
Recognition
Sensor
Turn-on fluorescence

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10.1016/j.tetlet.2012.08.106

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Zhao, J. F., Liu, Y., Soh, J. B., Li, Y. X., Ganguly, R., Ye, K. Q., Huo, F., Huang, L., Tok, A. I. Y., Loo, J. S. C., & Zhang, Q. (2012). One stone kills four birds: A novel diazaperinone 12H-pyrazino[2′, 3′:3,4]pyrrolo[1,2-a]perimidin-12-one recognizes four different metal ions. Tetrahedron Letters, 53(45), 6044-6047. https://doi.org/10.1016/j.tetlet.2012.08.106

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title = "One stone kills four birds: A novel diazaperinone 12H-pyrazino[2′, 3′:3,4]pyrrolo[1,2-a]perimidin-12-one recognizes four different metal ions",

abstract = "A novel diazaperinone 12H-pyrazino[2′,3′:3,4]pyrrolo[1,2-a] perimidin-12-one has been successfully synthesized through a one-step condensation. Single crystal X-ray analysis shows that the product is of planar structure with strong π⋯π interactions and H-bonding. Interestingly, the 12H-pyrazino[2′,3′:3,4]pyrrolo[1,2-a]perimidin- 12-one can recognize three different metal cations Cu 2+, Ag + and Hg 2+ via naked eye visualization, and shows turn-on fluorescence for Fe 3+ and Ag + among the 22 metal cations.",

keywords = "Diazaperinone, Multiple metal cations, Recognition, Sensor, Turn-on fluorescence",

author = "Zhao, {Jian Feng} and Yi Liu and Soh, {Jiayun Bethia} and Li, {Yong Xin} and Rakesh Ganguly and Ye, {Kai Qi} and Fengwei Huo and Ling Huang and Tok, {Alfred Iing Yoong} and Loo, {Joachim Say Chye} and Qichun Zhang",

year = "2012",

month = nov,

day = "7",

doi = "10.1016/j.tetlet.2012.08.106",

language = "英语",

volume = "53",

pages = "6044--6047",

journal = "Tetrahedron Letters",

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T2 - A novel diazaperinone 12H-pyrazino[2′, 3′:3,4]pyrrolo[1,2-a]perimidin-12-one recognizes four different metal ions

AU - Zhao, Jian Feng

AU - Liu, Yi

AU - Soh, Jiayun Bethia

AU - Li, Yong Xin

AU - Ganguly, Rakesh

AU - Ye, Kai Qi

AU - Huo, Fengwei

AU - Huang, Ling

AU - Tok, Alfred Iing Yoong

AU - Loo, Joachim Say Chye

AU - Zhang, Qichun

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AB - A novel diazaperinone 12H-pyrazino[2′,3′:3,4]pyrrolo[1,2-a] perimidin-12-one has been successfully synthesized through a one-step condensation. Single crystal X-ray analysis shows that the product is of planar structure with strong π⋯π interactions and H-bonding. Interestingly, the 12H-pyrazino[2′,3′:3,4]pyrrolo[1,2-a]perimidin- 12-one can recognize three different metal cations Cu 2+, Ag + and Hg 2+ via naked eye visualization, and shows turn-on fluorescence for Fe 3+ and Ag + among the 22 metal cations.

KW - Diazaperinone

KW - Multiple metal cations

KW - Recognition

KW - Sensor

KW - Turn-on fluorescence

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DO - 10.1016/j.tetlet.2012.08.106

M3 - 文章

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SN - 0040-4039

VL - 53

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

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ER -

One stone kills four birds: A novel diazaperinone 12H-pyrazino[2′, 3′:3,4]pyrrolo[1,2-a]perimidin-12-one recognizes four different metal ions

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Keywords

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