Organic reactions in ionic liquids: An efficient method for the synthesis of aryl sulfones by alkylation of sodium arenesulfinates with alkyl halides

Yi Hu; Zhen Chu Chen; Zhang Gao Le; Qin Guo Zheng

doi:10.3184/0308234041209031

Organic reactions in ionic liquids: An efficient method for the synthesis of aryl sulfones by alkylation of sodium arenesulfinates with alkyl halides

Yi Hu, Zhen Chu Chen, Zhang Gao Le, Qin Guo Zheng

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

An ionic liquid based on 1-butyl-3-methylimidazolium tetrafluoroborate (BmimBF₄) is used as a reusable reaction medium for the alkylation of sodium arenesulfinates with alkyl halides. This procedure is convenient, efficient and generally gives rise to the S-alkylated product with high selectivity when applied to active halides.

Original language	English
Pages (from-to)	267-269
Number of pages	3
Journal	Journal of Chemical Research
Issue number	4
DOIs	https://doi.org/10.3184/0308234041209031
State	Published - Apr 2004
Externally published	Yes

Keywords

Alkyl halides
Alkylation
Arenesulfinate
Ionic liquids
Sulfones

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10.3184/0308234041209031

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title = "Organic reactions in ionic liquids: An efficient method for the synthesis of aryl sulfones by alkylation of sodium arenesulfinates with alkyl halides",

abstract = "An ionic liquid based on 1-butyl-3-methylimidazolium tetrafluoroborate (BmimBF4) is used as a reusable reaction medium for the alkylation of sodium arenesulfinates with alkyl halides. This procedure is convenient, efficient and generally gives rise to the S-alkylated product with high selectivity when applied to active halides.",

keywords = "Alkyl halides, Alkylation, Arenesulfinate, Ionic liquids, Sulfones",

author = "Yi Hu and Chen, {Zhen Chu} and Le, {Zhang Gao} and Zheng, {Qin Guo}",

year = "2004",

month = apr,

doi = "10.3184/0308234041209031",

language = "英语",

pages = "267--269",

journal = "Journal of Chemical Research",

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T2 - An efficient method for the synthesis of aryl sulfones by alkylation of sodium arenesulfinates with alkyl halides

AU - Hu, Yi

AU - Chen, Zhen Chu

AU - Le, Zhang Gao

AU - Zheng, Qin Guo

PY - 2004/4

Y1 - 2004/4

N2 - An ionic liquid based on 1-butyl-3-methylimidazolium tetrafluoroborate (BmimBF4) is used as a reusable reaction medium for the alkylation of sodium arenesulfinates with alkyl halides. This procedure is convenient, efficient and generally gives rise to the S-alkylated product with high selectivity when applied to active halides.

AB - An ionic liquid based on 1-butyl-3-methylimidazolium tetrafluoroborate (BmimBF4) is used as a reusable reaction medium for the alkylation of sodium arenesulfinates with alkyl halides. This procedure is convenient, efficient and generally gives rise to the S-alkylated product with high selectivity when applied to active halides.

KW - Alkyl halides

KW - Alkylation

KW - Arenesulfinate

KW - Ionic liquids

KW - Sulfones

UR - http://www.scopus.com/inward/record.url?scp=2942724585&partnerID=8YFLogxK

U2 - 10.3184/0308234041209031

DO - 10.3184/0308234041209031

M3 - 文章

AN - SCOPUS:2942724585

SN - 0308-2342

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EP - 269

JO - Journal of Chemical Research

JF - Journal of Chemical Research

IS - 4

ER -

Organic reactions in ionic liquids: An efficient method for the synthesis of aryl sulfones by alkylation of sodium arenesulfinates with alkyl halides

Abstract

Keywords

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