Oxidative activation of light alkanes on dense ionic oxygen conducting membranes

M. Rebeilleau, A. C. Van Veen, D. Farrusseng, J. L. Rousset, C. Mirodatos, Z. P. Shao, G. Xiong

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

12 Scopus citations

Abstract

The oxidative dehydrogenation of ethane to ethylene (ODHE) has been studied in a catalytic membrane reactor (CMR) using a dense mixed ionic oxygen and electronic conducting perovskite membrane Ba0.5Sr 0.5Co0.8Fe0.2O3.&. At 1080K, an ethylene yield of 66% was obtained with the bare membrane. After Pd cluster deposition, the ethylene yield reached 76% at 1050K. Ni cluster deposition led to a decrease of ethane conversion compared to the bare membrane without changing ethylene selectivity.

Original languageEnglish
Title of host publicationStudies in Surface Science and Catalysis
PublisherElsevier Inc.
Pages655-660
Number of pages6
ISBN (Print)9780444515995
DOIs
StatePublished - 2004
Externally publishedYes

Publication series

NameStudies in Surface Science and Catalysis
Volume147
ISSN (Print)0167-2991

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