Palladium nanoparticles in cross-linked polyaniline as highly efficient catalysts for Suzuki-Miyaura reactions

Haipeng Fan; Zhengliang Qi; Dejun Sui; Fei Mao; Rizhi Chen; Jun Huang

doi:10.1016/S1872-2067(17)62772-4

Palladium nanoparticles in cross-linked polyaniline as highly efficient catalysts for Suzuki-Miyaura reactions

Haipeng Fan, Zhengliang Qi, Dejun Sui, Fei Mao, Rizhi Chen, Jun Huang

College of Chemical Engineering

Nanjing Tech University

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

Palladium nanoparticles supported on cross-linked polyaniline with bulky phosphorus ligands were developed. These catalysts showed high efficiency in the Suzuki-Miyaura reaction of aryl chlorides and bromides with phenylboronic acids. Aryl chlorides and bromides with functional groups, such as CN, MeO, CHO, MeCO and NO₂, were converted to the corresponding biphenyls in high yields with catalyst loading. Additionally, the catalysts combined high activity with good reusability; they could be used at least five times for the Suzuki-Miyaura coupling reaction.

Original language	English
Pages (from-to)	589-596
Number of pages	8
Journal	Chinese Journal of Catalysis
Volume	38
Issue number	3
DOIs	https://doi.org/10.1016/S1872-2067(17)62772-4
State	Published - 1 Mar 2017

Keywords

Biphenyls
Heterogeneous catalyst
Palladium
Polyaniline
Suzuki-Miyaura coupling reactions

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10.1016/S1872-2067(17)62772-4

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title = "Palladium nanoparticles in cross-linked polyaniline as highly efficient catalysts for Suzuki-Miyaura reactions",

abstract = "Palladium nanoparticles supported on cross-linked polyaniline with bulky phosphorus ligands were developed. These catalysts showed high efficiency in the Suzuki-Miyaura reaction of aryl chlorides and bromides with phenylboronic acids. Aryl chlorides and bromides with functional groups, such as CN, MeO, CHO, MeCO and NO2, were converted to the corresponding biphenyls in high yields with catalyst loading. Additionally, the catalysts combined high activity with good reusability; they could be used at least five times for the Suzuki-Miyaura coupling reaction.",

keywords = "Biphenyls, Heterogeneous catalyst, Palladium, Polyaniline, Suzuki-Miyaura coupling reactions",

author = "Haipeng Fan and Zhengliang Qi and Dejun Sui and Fei Mao and Rizhi Chen and Jun Huang",

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T1 - Palladium nanoparticles in cross-linked polyaniline as highly efficient catalysts for Suzuki-Miyaura reactions

AU - Fan, Haipeng

AU - Qi, Zhengliang

AU - Sui, Dejun

AU - Mao, Fei

AU - Chen, Rizhi

AU - Huang, Jun

PY - 2017/3/1

Y1 - 2017/3/1

N2 - Palladium nanoparticles supported on cross-linked polyaniline with bulky phosphorus ligands were developed. These catalysts showed high efficiency in the Suzuki-Miyaura reaction of aryl chlorides and bromides with phenylboronic acids. Aryl chlorides and bromides with functional groups, such as CN, MeO, CHO, MeCO and NO2, were converted to the corresponding biphenyls in high yields with catalyst loading. Additionally, the catalysts combined high activity with good reusability; they could be used at least five times for the Suzuki-Miyaura coupling reaction.

AB - Palladium nanoparticles supported on cross-linked polyaniline with bulky phosphorus ligands were developed. These catalysts showed high efficiency in the Suzuki-Miyaura reaction of aryl chlorides and bromides with phenylboronic acids. Aryl chlorides and bromides with functional groups, such as CN, MeO, CHO, MeCO and NO2, were converted to the corresponding biphenyls in high yields with catalyst loading. Additionally, the catalysts combined high activity with good reusability; they could be used at least five times for the Suzuki-Miyaura coupling reaction.

KW - Biphenyls

KW - Heterogeneous catalyst

KW - Palladium

KW - Polyaniline

KW - Suzuki-Miyaura coupling reactions

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U2 - 10.1016/S1872-2067(17)62772-4

DO - 10.1016/S1872-2067(17)62772-4

M3 - 文章

AN - SCOPUS:85016423733

SN - 1872-2067

VL - 38

SP - 589

EP - 596

JO - Chinese Journal of Catalysis

JF - Chinese Journal of Catalysis

IS - 3

ER -

Palladium nanoparticles in cross-linked polyaniline as highly efficient catalysts for Suzuki-Miyaura reactions

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Keywords

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