Polyoxometalate-based metal-organic framework-derived hybrid electrocatalysts for highly efficient hydrogen evolution reaction

Ji Sen Li; Yu Jia Tang; Chun Hui Liu; Shun Li Li; Run Han Li; Long Zhang Dong; Zhi Hui Dai; Jian Chun Bao; Ya Qian Lan

doi:10.1039/c5ta09743f

Polyoxometalate-based metal-organic framework-derived hybrid electrocatalysts for highly efficient hydrogen evolution reaction

Ji Sen Li, Yu Jia Tang, Chun Hui Liu, Shun Li Li, Run Han Li, Long Zhang Dong, Zhi Hui Dai, Jian Chun Bao, Ya Qian Lan

Research output: Contribution to journal › Article › peer-review

172 Scopus citations

Abstract

The design and fabrication of electrocatalysts for HER, with superior activity and stability, still remain a significant challenge for clean and renewable energy technologies. Here we have synthesized Fe₃C/Mo₂C-containing N, P co-doped graphitic carbon derived from POM@MOF-100 (Fe) (denoted as Fe₃C/Mo₂C@NPGC) via a "killing three birds with one stone" strategy. The Fe₃C/Mo₂C@NPGC catalyst demonstrates excellent electrocatalytic activity and stability towards HER with a low onset overpotential of 18 mV (vs. RHE), small Tafel slope of 45.2 mV dec^-1, as well as long-term durability for 10 h, which is one of the best non-noble metal HER catalysts in acidic media reported so far. Most importantly, this work opens up exciting opportunities for fabricating novel and highly efficient electrocatalysts to replace Pt or Pt-based catalysts utilizing POM-based metal-organic frameworks (MOFs) as precursors.

Original language	English
Pages (from-to)	1202-1207
Number of pages	6
Journal	Journal of Materials Chemistry A
Volume	4
Issue number	4
DOIs	https://doi.org/10.1039/c5ta09743f
State	Published - 28 Jan 2016
Externally published	Yes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1039/c5ta09743f

Cite this

@article{9077a1bb46f84538866b823b7d12a69d,

title = "Polyoxometalate-based metal-organic framework-derived hybrid electrocatalysts for highly efficient hydrogen evolution reaction",

abstract = "The design and fabrication of electrocatalysts for HER, with superior activity and stability, still remain a significant challenge for clean and renewable energy technologies. Here we have synthesized Fe3C/Mo2C-containing N, P co-doped graphitic carbon derived from POM@MOF-100 (Fe) (denoted as Fe3C/Mo2C@NPGC) via a {"}killing three birds with one stone{"} strategy. The Fe3C/Mo2C@NPGC catalyst demonstrates excellent electrocatalytic activity and stability towards HER with a low onset overpotential of 18 mV (vs. RHE), small Tafel slope of 45.2 mV dec-1, as well as long-term durability for 10 h, which is one of the best non-noble metal HER catalysts in acidic media reported so far. Most importantly, this work opens up exciting opportunities for fabricating novel and highly efficient electrocatalysts to replace Pt or Pt-based catalysts utilizing POM-based metal-organic frameworks (MOFs) as precursors.",

author = "Li, {Ji Sen} and Tang, {Yu Jia} and Liu, {Chun Hui} and Li, {Shun Li} and Li, {Run Han} and Dong, {Long Zhang} and Dai, {Zhi Hui} and Bao, {Jian Chun} and Lan, {Ya Qian}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2016.",

year = "2016",

month = jan,

day = "28",

doi = "10.1039/c5ta09743f",

language = "英语",

volume = "4",

pages = "1202--1207",

journal = "Journal of Materials Chemistry A",

issn = "2050-7488",

publisher = "Royal Society of Chemistry",

number = "4",

}

TY - JOUR

T1 - Polyoxometalate-based metal-organic framework-derived hybrid electrocatalysts for highly efficient hydrogen evolution reaction

AU - Li, Ji Sen

AU - Tang, Yu Jia

AU - Liu, Chun Hui

AU - Li, Shun Li

AU - Li, Run Han

AU - Dong, Long Zhang

AU - Dai, Zhi Hui

AU - Bao, Jian Chun

AU - Lan, Ya Qian

PY - 2016/1/28

Y1 - 2016/1/28

N2 - The design and fabrication of electrocatalysts for HER, with superior activity and stability, still remain a significant challenge for clean and renewable energy technologies. Here we have synthesized Fe3C/Mo2C-containing N, P co-doped graphitic carbon derived from POM@MOF-100 (Fe) (denoted as Fe3C/Mo2C@NPGC) via a "killing three birds with one stone" strategy. The Fe3C/Mo2C@NPGC catalyst demonstrates excellent electrocatalytic activity and stability towards HER with a low onset overpotential of 18 mV (vs. RHE), small Tafel slope of 45.2 mV dec-1, as well as long-term durability for 10 h, which is one of the best non-noble metal HER catalysts in acidic media reported so far. Most importantly, this work opens up exciting opportunities for fabricating novel and highly efficient electrocatalysts to replace Pt or Pt-based catalysts utilizing POM-based metal-organic frameworks (MOFs) as precursors.

AB - The design and fabrication of electrocatalysts for HER, with superior activity and stability, still remain a significant challenge for clean and renewable energy technologies. Here we have synthesized Fe3C/Mo2C-containing N, P co-doped graphitic carbon derived from POM@MOF-100 (Fe) (denoted as Fe3C/Mo2C@NPGC) via a "killing three birds with one stone" strategy. The Fe3C/Mo2C@NPGC catalyst demonstrates excellent electrocatalytic activity and stability towards HER with a low onset overpotential of 18 mV (vs. RHE), small Tafel slope of 45.2 mV dec-1, as well as long-term durability for 10 h, which is one of the best non-noble metal HER catalysts in acidic media reported so far. Most importantly, this work opens up exciting opportunities for fabricating novel and highly efficient electrocatalysts to replace Pt or Pt-based catalysts utilizing POM-based metal-organic frameworks (MOFs) as precursors.

UR - http://www.scopus.com/inward/record.url?scp=84955255831&partnerID=8YFLogxK

U2 - 10.1039/c5ta09743f

DO - 10.1039/c5ta09743f

M3 - 文章

AN - SCOPUS:84955255831

SN - 2050-7488

VL - 4

SP - 1202

EP - 1207

JO - Journal of Materials Chemistry A

JF - Journal of Materials Chemistry A

IS - 4

ER -

Polyoxometalate-based metal-organic framework-derived hybrid electrocatalysts for highly efficient hydrogen evolution reaction

Abstract

UN SDGs

Access to Document

Other files and links

Fingerprint

Cite this