Pre-design and synthesis of a five-fold interpenetrated pcu -type porous coordination polymer and its CO2/CO separation

Haifei Cao; Suna Wang; Yang Wang; Hongliang Lyu; Rajamani Krishna; Zhiyong Lu; Jingui Duan; Wanqin Jin

doi:10.1039/c7ce01649b

Pre-design and synthesis of a five-fold interpenetrated pcu -type porous coordination polymer and its CO₂/CO separation

Haifei Cao, Suna Wang, Yang Wang, Hongliang Lyu, Rajamani Krishna, Zhiyong Lu, Jingui Duan, Wanqin Jin

College of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

From the viewpoint of mathematics and topology, we proposed a rational design and stabilized the first five-fold interpenetrated porous coordination polymer (PCP) with a pcu topology and extra-framework volume (60.0%) by employing a linear ligand with the length of ∼2 nm. The resulting compound exhibits good CO₂ uptake, enabling highly selective separation of CO₂ from CO₂/CO mixtures.

Original language	English
Pages (from-to)	6927-6931
Number of pages	5
Journal	CrystEngComm
Volume	19
Issue number	46
DOIs	https://doi.org/10.1039/c7ce01649b
State	Published - 2017

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abstract = "From the viewpoint of mathematics and topology, we proposed a rational design and stabilized the first five-fold interpenetrated porous coordination polymer (PCP) with a pcu topology and extra-framework volume (60.0%) by employing a linear ligand with the length of ∼2 nm. The resulting compound exhibits good CO2 uptake, enabling highly selective separation of CO2 from CO2/CO mixtures.",

author = "Haifei Cao and Suna Wang and Yang Wang and Hongliang Lyu and Rajamani Krishna and Zhiyong Lu and Jingui Duan and Wanqin Jin",

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T1 - Pre-design and synthesis of a five-fold interpenetrated pcu -type porous coordination polymer and its CO2/CO separation

AU - Cao, Haifei

AU - Wang, Suna

AU - Wang, Yang

AU - Lyu, Hongliang

AU - Krishna, Rajamani

AU - Lu, Zhiyong

AU - Duan, Jingui

AU - Jin, Wanqin

PY - 2017

Y1 - 2017

N2 - From the viewpoint of mathematics and topology, we proposed a rational design and stabilized the first five-fold interpenetrated porous coordination polymer (PCP) with a pcu topology and extra-framework volume (60.0%) by employing a linear ligand with the length of ∼2 nm. The resulting compound exhibits good CO2 uptake, enabling highly selective separation of CO2 from CO2/CO mixtures.

AB - From the viewpoint of mathematics and topology, we proposed a rational design and stabilized the first five-fold interpenetrated porous coordination polymer (PCP) with a pcu topology and extra-framework volume (60.0%) by employing a linear ligand with the length of ∼2 nm. The resulting compound exhibits good CO2 uptake, enabling highly selective separation of CO2 from CO2/CO mixtures.

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U2 - 10.1039/c7ce01649b

DO - 10.1039/c7ce01649b

M3 - 文章

AN - SCOPUS:85035327922

SN - 1466-8033

VL - 19

SP - 6927

EP - 6931

JO - CrystEngComm

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ER -

Pre-design and synthesis of a five-fold interpenetrated pcu -type porous coordination polymer and its CO₂/CO separation

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