Precisely tunable magnetic phase transition temperature, TC, through the formation of a molecular alloy in [NixPt 1-x(mnt)2]--based spin systems (mnt 2- = maleonitriledithiolate, x = 0.09-0.91)

Guo Jun Yuan; Hao Yang; Shao Xian Liu; Jian Lan Liu; Xiao Ming Ren

doi:10.1039/c4dt00868e

Precisely tunable magnetic phase transition temperature, T_C, through the formation of a molecular alloy in [Ni_xPt _1-x(mnt)₂]^--based spin systems (mnt ^2- = maleonitriledithiolate, x = 0.09-0.91)

Guo Jun Yuan, Hao Yang, Shao Xian Liu, Jian Lan Liu, Xiao Ming Ren

School of Chemistry and Moleculai Engineering

Nanjing Tech University

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4 Scopus citations

Abstract

Nine molecular substitutional alloys with formula [Cl-BzPy][Ni _xPt_1-x(mnt)₂] (x = 0.09-0.91) were prepared by mixing the isostructural [Cl-BzPy][Ni(mnt)₂] and [Cl-BzPy][Pt(mnt) ₂] in acetonitrile according to the molar ratio of x/(1 - x), where mnt^2- = maleonitriledithiolate, Cl-BzPy⁺ = 1-(4′-chloro-benzyl)pyridinium. Each alloy compound is isostructural with the parent compounds and shows a magnetic transition; the T_C decreases linearly with the molar fraction x, indicating that T_C is precisely tunable in this alloy system. This journal is

Original language	English
Pages (from-to)	11908-11914
Number of pages	7
Journal	Dalton Transactions
Volume	43
Issue number	31
DOIs	https://doi.org/10.1039/c4dt00868e
State	Published - 21 Aug 2014

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title = "Precisely tunable magnetic phase transition temperature, TC, through the formation of a molecular alloy in [NixPt 1-x(mnt)2]--based spin systems (mnt 2- = maleonitriledithiolate, x = 0.09-0.91)",

abstract = "Nine molecular substitutional alloys with formula [Cl-BzPy][Ni xPt1-x(mnt)2] (x = 0.09-0.91) were prepared by mixing the isostructural [Cl-BzPy][Ni(mnt)2] and [Cl-BzPy][Pt(mnt) 2] in acetonitrile according to the molar ratio of x/(1 - x), where mnt2- = maleonitriledithiolate, Cl-BzPy+ = 1-(4′-chloro-benzyl)pyridinium. Each alloy compound is isostructural with the parent compounds and shows a magnetic transition; the TC decreases linearly with the molar fraction x, indicating that TC is precisely tunable in this alloy system. This journal is",

author = "Yuan, {Guo Jun} and Hao Yang and Liu, {Shao Xian} and Liu, {Jian Lan} and Ren, {Xiao Ming}",

year = "2014",

month = aug,

day = "21",

doi = "10.1039/c4dt00868e",

language = "英语",

volume = "43",

pages = "11908--11914",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "31",

}

Precisely tunable magnetic phase transition temperature, T_C, through the formation of a molecular alloy in [Ni_xPt _1-x(mnt)₂]^--based spin systems (mnt ^2- = maleonitriledithiolate, x = 0.09-0.91). / Yuan, Guo Jun; Yang, Hao; Liu, Shao Xian et al.
In: Dalton Transactions, Vol. 43, No. 31, 21.08.2014, p. 11908-11914.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Precisely tunable magnetic phase transition temperature, TC, through the formation of a molecular alloy in [NixPt 1-x(mnt)2]--based spin systems (mnt 2- = maleonitriledithiolate, x = 0.09-0.91)

AU - Yuan, Guo Jun

AU - Yang, Hao

AU - Liu, Shao Xian

AU - Liu, Jian Lan

AU - Ren, Xiao Ming

PY - 2014/8/21

Y1 - 2014/8/21

N2 - Nine molecular substitutional alloys with formula [Cl-BzPy][Ni xPt1-x(mnt)2] (x = 0.09-0.91) were prepared by mixing the isostructural [Cl-BzPy][Ni(mnt)2] and [Cl-BzPy][Pt(mnt) 2] in acetonitrile according to the molar ratio of x/(1 - x), where mnt2- = maleonitriledithiolate, Cl-BzPy+ = 1-(4′-chloro-benzyl)pyridinium. Each alloy compound is isostructural with the parent compounds and shows a magnetic transition; the TC decreases linearly with the molar fraction x, indicating that TC is precisely tunable in this alloy system. This journal is

AB - Nine molecular substitutional alloys with formula [Cl-BzPy][Ni xPt1-x(mnt)2] (x = 0.09-0.91) were prepared by mixing the isostructural [Cl-BzPy][Ni(mnt)2] and [Cl-BzPy][Pt(mnt) 2] in acetonitrile according to the molar ratio of x/(1 - x), where mnt2- = maleonitriledithiolate, Cl-BzPy+ = 1-(4′-chloro-benzyl)pyridinium. Each alloy compound is isostructural with the parent compounds and shows a magnetic transition; the TC decreases linearly with the molar fraction x, indicating that TC is precisely tunable in this alloy system. This journal is

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U2 - 10.1039/c4dt00868e

DO - 10.1039/c4dt00868e

M3 - 文章

AN - SCOPUS:84904438419

SN - 1477-9226

VL - 43

SP - 11908

EP - 11914

JO - Dalton Transactions

JF - Dalton Transactions

IS - 31

ER -

Precisely tunable magnetic phase transition temperature, T_C, through the formation of a molecular alloy in [Ni_xPt _1-x(mnt)₂]^--based spin systems (mnt ^2- = maleonitriledithiolate, x = 0.09-0.91)

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