Predesign and systematic synthesis of 11 highly porous coordination polymers with unprecedented topology

Jingui Duan; Masakazu Higuchi; Susumu Kitagawa

doi:10.1021/ic502643m

Predesign and systematic synthesis of 11 highly porous coordination polymers with unprecedented topology

Jingui Duan, Masakazu Higuchi, Susumu Kitagawa

College of Chemical Engineering

Kyoto University

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

We propose and validate a simple strategy of vertex connection that can be used for framework design and pore size/type modulation to prepare a mother structure and another 10 highly porous isoreticular frameworks with unprecedented topology. Importantly, the potential accessible pore volumes (57-71%), pore sizes (6.8-11. 2 Å; 17.0-29.0 Å; 12.5-22.8 Å; 11.9-24.5 Å), and the pore shapes of this series of highly porous frameworks were simultaneously and systematically tuned. Interestingly, the pore size of IIa [Zn₄O(L²)₂(BDC)_0.5]{(CH₃)₂NH₂} decreased a little less than that of IIc [Zn₄O(L²)₂(2,6-NDC)_0.5]{(CH₃)₂NH₂}; however, its selectivity of CO₂ toward CH₄ increased by almost two times.

Original language	English
Pages (from-to)	1645-1649
Number of pages	5
Journal	Inorganic Chemistry
Volume	54
Issue number	4
DOIs	https://doi.org/10.1021/ic502643m
State	Published - 16 Feb 2015

Access to Document

10.1021/ic502643m

Cite this

@article{4ff4058b7d3a4d7cabfd082743c11602,

title = "Predesign and systematic synthesis of 11 highly porous coordination polymers with unprecedented topology",

abstract = "We propose and validate a simple strategy of vertex connection that can be used for framework design and pore size/type modulation to prepare a mother structure and another 10 highly porous isoreticular frameworks with unprecedented topology. Importantly, the potential accessible pore volumes (57-71%), pore sizes (6.8-11. 2 {\AA}; 17.0-29.0 {\AA}; 12.5-22.8 {\AA}; 11.9-24.5 {\AA}), and the pore shapes of this series of highly porous frameworks were simultaneously and systematically tuned. Interestingly, the pore size of IIa [Zn4O(L2)2(BDC)0.5]{(CH3)2NH2} decreased a little less than that of IIc [Zn4O(L2)2(2,6-NDC)0.5]{(CH3)2NH2}; however, its selectivity of CO2 toward CH4 increased by almost two times.",

author = "Jingui Duan and Masakazu Higuchi and Susumu Kitagawa",

note = "Publisher Copyright: {\textcopyright} 2015 American Chemical Society.",

year = "2015",

month = feb,

day = "16",

doi = "10.1021/ic502643m",

language = "英语",

volume = "54",

pages = "1645--1649",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "4",

}

TY - JOUR

T1 - Predesign and systematic synthesis of 11 highly porous coordination polymers with unprecedented topology

AU - Duan, Jingui

AU - Higuchi, Masakazu

AU - Kitagawa, Susumu

PY - 2015/2/16

Y1 - 2015/2/16

N2 - We propose and validate a simple strategy of vertex connection that can be used for framework design and pore size/type modulation to prepare a mother structure and another 10 highly porous isoreticular frameworks with unprecedented topology. Importantly, the potential accessible pore volumes (57-71%), pore sizes (6.8-11. 2 Å; 17.0-29.0 Å; 12.5-22.8 Å; 11.9-24.5 Å), and the pore shapes of this series of highly porous frameworks were simultaneously and systematically tuned. Interestingly, the pore size of IIa [Zn4O(L2)2(BDC)0.5]{(CH3)2NH2} decreased a little less than that of IIc [Zn4O(L2)2(2,6-NDC)0.5]{(CH3)2NH2}; however, its selectivity of CO2 toward CH4 increased by almost two times.

AB - We propose and validate a simple strategy of vertex connection that can be used for framework design and pore size/type modulation to prepare a mother structure and another 10 highly porous isoreticular frameworks with unprecedented topology. Importantly, the potential accessible pore volumes (57-71%), pore sizes (6.8-11. 2 Å; 17.0-29.0 Å; 12.5-22.8 Å; 11.9-24.5 Å), and the pore shapes of this series of highly porous frameworks were simultaneously and systematically tuned. Interestingly, the pore size of IIa [Zn4O(L2)2(BDC)0.5]{(CH3)2NH2} decreased a little less than that of IIc [Zn4O(L2)2(2,6-NDC)0.5]{(CH3)2NH2}; however, its selectivity of CO2 toward CH4 increased by almost two times.

UR - http://www.scopus.com/inward/record.url?scp=84923198025&partnerID=8YFLogxK

U2 - 10.1021/ic502643m

DO - 10.1021/ic502643m

M3 - 文章

C2 - 25594909

AN - SCOPUS:84923198025

SN - 0020-1669

VL - 54

SP - 1645

EP - 1649

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 4

ER -

Predesign and systematic synthesis of 11 highly porous coordination polymers with unprecedented topology

Abstract

Access to Document

Other files and links

Fingerprint

Cite this