Preparation and self-assembly of poly(diglycidyl maleate-co-stearyl methacrylate)

Haojie Yu; Li Wang; Junfeng Zhou; Xiaochen Dong; Guohua Jiang

doi:10.1002/app.26264

Preparation and self-assembly of poly(diglycidyl maleate-co-stearyl methacrylate)

Haojie Yu, Li Wang, Junfeng Zhou, Xiaochen Dong, Guohua Jiang

Zhejiang University

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Poly(diglycidyl maleate-co-stearyl methacrylate) (P(DGMA-co-SMA)) with reactive epoxy groups was synthesized by reaction of poly(maleic anhydride-co-stearyl methacrylate) (P(MA-co-SMA)) and epichlorohydrin. The effect of precipitant on self-assembly behaviors of the resultant copolymer was investigated. It was found that vesicles and nanotubule liked aggregates can be obtained through self-assembly of P(DGMA-co-SMA) in THF solution using CH ₃CH₂OH (EtOH) as precipitant while spheral aggregates can be obtained using H₂O as precipitant. The mechanism of the self-assembly behavior was discussed.

Original language	English
Pages (from-to)	1156-1161
Number of pages	6
Journal	Journal of Applied Polymer Science
Volume	105
Issue number	3
DOIs	https://doi.org/10.1002/app.26264
State	Published - 5 Aug 2007
Externally published	Yes

Keywords

Aggregate
Copolymer
Epoxy
Morphology
Self-assembly

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10.1002/app.26264

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title = "Preparation and self-assembly of poly(diglycidyl maleate-co-stearyl methacrylate)",

abstract = "Poly(diglycidyl maleate-co-stearyl methacrylate) (P(DGMA-co-SMA)) with reactive epoxy groups was synthesized by reaction of poly(maleic anhydride-co-stearyl methacrylate) (P(MA-co-SMA)) and epichlorohydrin. The effect of precipitant on self-assembly behaviors of the resultant copolymer was investigated. It was found that vesicles and nanotubule liked aggregates can be obtained through self-assembly of P(DGMA-co-SMA) in THF solution using CH 3CH2OH (EtOH) as precipitant while spheral aggregates can be obtained using H2O as precipitant. The mechanism of the self-assembly behavior was discussed.",

keywords = "Aggregate, Copolymer, Epoxy, Morphology, Self-assembly",

author = "Haojie Yu and Li Wang and Junfeng Zhou and Xiaochen Dong and Guohua Jiang",

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doi = "10.1002/app.26264",

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volume = "105",

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TY - JOUR

T1 - Preparation and self-assembly of poly(diglycidyl maleate-co-stearyl methacrylate)

AU - Yu, Haojie

AU - Wang, Li

AU - Zhou, Junfeng

AU - Dong, Xiaochen

AU - Jiang, Guohua

PY - 2007/8/5

Y1 - 2007/8/5

N2 - Poly(diglycidyl maleate-co-stearyl methacrylate) (P(DGMA-co-SMA)) with reactive epoxy groups was synthesized by reaction of poly(maleic anhydride-co-stearyl methacrylate) (P(MA-co-SMA)) and epichlorohydrin. The effect of precipitant on self-assembly behaviors of the resultant copolymer was investigated. It was found that vesicles and nanotubule liked aggregates can be obtained through self-assembly of P(DGMA-co-SMA) in THF solution using CH 3CH2OH (EtOH) as precipitant while spheral aggregates can be obtained using H2O as precipitant. The mechanism of the self-assembly behavior was discussed.

AB - Poly(diglycidyl maleate-co-stearyl methacrylate) (P(DGMA-co-SMA)) with reactive epoxy groups was synthesized by reaction of poly(maleic anhydride-co-stearyl methacrylate) (P(MA-co-SMA)) and epichlorohydrin. The effect of precipitant on self-assembly behaviors of the resultant copolymer was investigated. It was found that vesicles and nanotubule liked aggregates can be obtained through self-assembly of P(DGMA-co-SMA) in THF solution using CH 3CH2OH (EtOH) as precipitant while spheral aggregates can be obtained using H2O as precipitant. The mechanism of the self-assembly behavior was discussed.

KW - Aggregate

KW - Copolymer

KW - Epoxy

KW - Morphology

KW - Self-assembly

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U2 - 10.1002/app.26264

DO - 10.1002/app.26264

M3 - 文章

AN - SCOPUS:34547476484

SN - 0021-8995

VL - 105

SP - 1156

EP - 1161

JO - Journal of Applied Polymer Science

JF - Journal of Applied Polymer Science

IS - 3

ER -

Preparation and self-assembly of poly(diglycidyl maleate-co-stearyl methacrylate)

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Keywords

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