Preparation and spectroscopic study of two new charge transfer salts

You Cun Chen; Guang Xiang Liu; Ming Wang; Ming Tian Zhang; Xiao Ming Ren

Preparation and spectroscopic study of two new charge transfer salts

You Cun Chen, Guang Xiang Liu, Ming Wang, Ming Tian Zhang, Xiao Ming Ren

Anqing Normal University

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

TCNQ (TCNQ=tetracyanoquinodimethane) salts have good conductivity. The magnetic properties of substituted benzylpridiniums, such as ferromagnetisrn, antiferromagnetisni and spin Peierls transition, have widely been investigated. In order to obtain some new materials with both conductivity and magnetism, two new organic salts, [NO₂BzPy]Cl (1) and [NO₂BzPyNH₂]Cl (2), were synthesized and characterized. Further more, two new charge transfer salts, [NO₂BzPy] [TCNQ]₂ (3) and [NO₂BzPyNH₂] [TCNQ]₂ (4) were synthesized and characterized. The tested results of elementary analysis of charge transfer salts (3) and (4) were consistent with theoretical values, and the results of IR indicated that there exist TCNQ and TCNQ anions. One-dimensional molecular column of TCNQ has been formed. Partial charge transfer takes place from [TCNQ]₂^- to cation.

Original language	English
Pages (from-to)	395-397
Number of pages	3
Journal	Guang Pu Xue Yu Guang Pu Fen Xi/Spectroscopy and Spectral Analysis
Volume	25
Issue number	3
State	Published - Mar 2005
Externally published	Yes

Keywords

Characterization
Charge transfer salts
Synthesis
TCNQ

Cite this

@article{5ad919564d774cb09b2379f745cbbe8b,

title = "Preparation and spectroscopic study of two new charge transfer salts",

abstract = "TCNQ (TCNQ=tetracyanoquinodimethane) salts have good conductivity. The magnetic properties of substituted benzylpridiniums, such as ferromagnetisrn, antiferromagnetisni and spin Peierls transition, have widely been investigated. In order to obtain some new materials with both conductivity and magnetism, two new organic salts, [NO2BzPy]Cl (1) and [NO2BzPyNH2]Cl (2), were synthesized and characterized. Further more, two new charge transfer salts, [NO2BzPy] [TCNQ]2 (3) and [NO2BzPyNH2] [TCNQ]2 (4) were synthesized and characterized. The tested results of elementary analysis of charge transfer salts (3) and (4) were consistent with theoretical values, and the results of IR indicated that there exist TCNQ and TCNQ anions. One-dimensional molecular column of TCNQ has been formed. Partial charge transfer takes place from [TCNQ]2- to cation.",

keywords = "Characterization, Charge transfer salts, Synthesis, TCNQ",

author = "Chen, {You Cun} and Liu, {Guang Xiang} and Ming Wang and Zhang, {Ming Tian} and Ren, {Xiao Ming}",

year = "2005",

month = mar,

language = "英语",

volume = "25",

pages = "395--397",

journal = "Guang Pu Xue Yu Guang Pu Fen Xi/Spectroscopy and Spectral Analysis",

issn = "1000-0593",

publisher = "Science China Press",

number = "3",

}

TY - JOUR

T1 - Preparation and spectroscopic study of two new charge transfer salts

AU - Chen, You Cun

AU - Liu, Guang Xiang

AU - Wang, Ming

AU - Zhang, Ming Tian

AU - Ren, Xiao Ming

PY - 2005/3

Y1 - 2005/3

N2 - TCNQ (TCNQ=tetracyanoquinodimethane) salts have good conductivity. The magnetic properties of substituted benzylpridiniums, such as ferromagnetisrn, antiferromagnetisni and spin Peierls transition, have widely been investigated. In order to obtain some new materials with both conductivity and magnetism, two new organic salts, [NO2BzPy]Cl (1) and [NO2BzPyNH2]Cl (2), were synthesized and characterized. Further more, two new charge transfer salts, [NO2BzPy] [TCNQ]2 (3) and [NO2BzPyNH2] [TCNQ]2 (4) were synthesized and characterized. The tested results of elementary analysis of charge transfer salts (3) and (4) were consistent with theoretical values, and the results of IR indicated that there exist TCNQ and TCNQ anions. One-dimensional molecular column of TCNQ has been formed. Partial charge transfer takes place from [TCNQ]2- to cation.

AB - TCNQ (TCNQ=tetracyanoquinodimethane) salts have good conductivity. The magnetic properties of substituted benzylpridiniums, such as ferromagnetisrn, antiferromagnetisni and spin Peierls transition, have widely been investigated. In order to obtain some new materials with both conductivity and magnetism, two new organic salts, [NO2BzPy]Cl (1) and [NO2BzPyNH2]Cl (2), were synthesized and characterized. Further more, two new charge transfer salts, [NO2BzPy] [TCNQ]2 (3) and [NO2BzPyNH2] [TCNQ]2 (4) were synthesized and characterized. The tested results of elementary analysis of charge transfer salts (3) and (4) were consistent with theoretical values, and the results of IR indicated that there exist TCNQ and TCNQ anions. One-dimensional molecular column of TCNQ has been formed. Partial charge transfer takes place from [TCNQ]2- to cation.

KW - Characterization

KW - Charge transfer salts

KW - Synthesis

KW - TCNQ

UR - http://www.scopus.com/inward/record.url?scp=16644398163&partnerID=8YFLogxK

M3 - 文章

C2 - 16013315

AN - SCOPUS:16644398163

SN - 1000-0593

VL - 25

SP - 395

EP - 397

JO - Guang Pu Xue Yu Guang Pu Fen Xi/Spectroscopy and Spectral Analysis

JF - Guang Pu Xue Yu Guang Pu Fen Xi/Spectroscopy and Spectral Analysis

IS - 3

ER -

Preparation and spectroscopic study of two new charge transfer salts

Abstract

Keywords

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