Preparation of 1,3-propanediol by glycerol hydrogenolysis with Pt/Al 2O3-WO3/ZrO2 catalysts

Peng Xiaopeng; Chen Changlin; Chen Rizhi

Preparation of 1,3-propanediol by glycerol hydrogenolysis with Pt/Al ₂O₃-WO₃/ZrO₂ catalysts

Peng Xiaopeng, Chen Changlin, Chen Rizhi

College of Chemical Engineering

Nanjing Tech University

Research output: Contribution to journal › Article › peer-review

Abstract

A series of Pt/WO₃/ZrO₂ and Pt/Al₂O ₃-WO₃/ZrO₂ catalysts were prepared by impregnation and their catalytic performance for glycerol hydrogenolysis was studied in a fixed bed reactor. The physic-chemical properties were characterized by FT-IR spectra of pyridine adsorption, temperatureprogrammed desorption of NH₃(NH₃-TPD) and temperature-programmed desorption of H₂(H₂-TPD) methods. The results indicated that the activity of Pt/Al₂O₃-WO₃/ZrO ₂ was closely related with the Al content, capacity of H₂ adsorption and surface acid property. The addition of appropriate amount of Al can increase the Lewis acid site. The amount of H₂ adsorption over the catalyst with n(Al)/n (W) = 0. 1 is 106. 7 μmol/g, the conversion of glycerol and the yield of 1,3-propanediol are 36.8% and 16. 3% respectively, each of which is much higher than that over Pt/WO₃/ZrO₂ catalyst.

Original language	English
Pages (from-to)	1-4
Number of pages	4
Journal	Speciality Petrochemicals
Volume	31
Issue number	3
State	Published - 18 May 2014

Keywords

1,3-propanediol
Alumina
Catalytic hydrogenolysis
Glycerol
Tungsten oxide
Zirconia

Cite this

@article{2bb147f83de540cb841516390b6032c8,

title = "Preparation of 1,3-propanediol by glycerol hydrogenolysis with Pt/Al 2O3-WO3/ZrO2 catalysts",

abstract = "A series of Pt/WO3/ZrO2 and Pt/Al2O 3-WO3/ZrO2 catalysts were prepared by impregnation and their catalytic performance for glycerol hydrogenolysis was studied in a fixed bed reactor. The physic-chemical properties were characterized by FT-IR spectra of pyridine adsorption, temperatureprogrammed desorption of NH3(NH3-TPD) and temperature-programmed desorption of H2(H2-TPD) methods. The results indicated that the activity of Pt/Al2O3-WO3/ZrO 2 was closely related with the Al content, capacity of H2 adsorption and surface acid property. The addition of appropriate amount of Al can increase the Lewis acid site. The amount of H2 adsorption over the catalyst with n(Al)/n (W) = 0. 1 is 106. 7 μmol/g, the conversion of glycerol and the yield of 1,3-propanediol are 36.8% and 16. 3% respectively, each of which is much higher than that over Pt/WO3/ZrO2 catalyst.",

keywords = "1,3-propanediol, Alumina, Catalytic hydrogenolysis, Glycerol, Tungsten oxide, Zirconia",

author = "Peng Xiaopeng and Chen Changlin and Chen Rizhi",

year = "2014",

month = may,

day = "18",

language = "英语",

volume = "31",

pages = "1--4",

journal = "Speciality Petrochemicals",

issn = "1003-9384",

publisher = "SINOPEC",

number = "3",

}

TY - JOUR

T1 - Preparation of 1,3-propanediol by glycerol hydrogenolysis with Pt/Al 2O3-WO3/ZrO2 catalysts

AU - Xiaopeng, Peng

AU - Changlin, Chen

AU - Rizhi, Chen

PY - 2014/5/18

Y1 - 2014/5/18

N2 - A series of Pt/WO3/ZrO2 and Pt/Al2O 3-WO3/ZrO2 catalysts were prepared by impregnation and their catalytic performance for glycerol hydrogenolysis was studied in a fixed bed reactor. The physic-chemical properties were characterized by FT-IR spectra of pyridine adsorption, temperatureprogrammed desorption of NH3(NH3-TPD) and temperature-programmed desorption of H2(H2-TPD) methods. The results indicated that the activity of Pt/Al2O3-WO3/ZrO 2 was closely related with the Al content, capacity of H2 adsorption and surface acid property. The addition of appropriate amount of Al can increase the Lewis acid site. The amount of H2 adsorption over the catalyst with n(Al)/n (W) = 0. 1 is 106. 7 μmol/g, the conversion of glycerol and the yield of 1,3-propanediol are 36.8% and 16. 3% respectively, each of which is much higher than that over Pt/WO3/ZrO2 catalyst.

AB - A series of Pt/WO3/ZrO2 and Pt/Al2O 3-WO3/ZrO2 catalysts were prepared by impregnation and their catalytic performance for glycerol hydrogenolysis was studied in a fixed bed reactor. The physic-chemical properties were characterized by FT-IR spectra of pyridine adsorption, temperatureprogrammed desorption of NH3(NH3-TPD) and temperature-programmed desorption of H2(H2-TPD) methods. The results indicated that the activity of Pt/Al2O3-WO3/ZrO 2 was closely related with the Al content, capacity of H2 adsorption and surface acid property. The addition of appropriate amount of Al can increase the Lewis acid site. The amount of H2 adsorption over the catalyst with n(Al)/n (W) = 0. 1 is 106. 7 μmol/g, the conversion of glycerol and the yield of 1,3-propanediol are 36.8% and 16. 3% respectively, each of which is much higher than that over Pt/WO3/ZrO2 catalyst.

KW - 1,3-propanediol

KW - Alumina

KW - Catalytic hydrogenolysis

KW - Glycerol

KW - Tungsten oxide

KW - Zirconia

UR - http://www.scopus.com/inward/record.url?scp=84902656396&partnerID=8YFLogxK

M3 - 文章

AN - SCOPUS:84902656396

SN - 1003-9384

VL - 31

SP - 1

EP - 4

JO - Speciality Petrochemicals

JF - Speciality Petrochemicals

IS - 3

ER -

Preparation of 1,3-propanediol by glycerol hydrogenolysis with Pt/Al ₂O₃-WO₃/ZrO₂ catalysts

Abstract

Keywords

Other files and links

Fingerprint

Cite this