Preparation of Monolithic LaFeO₃ and Catalytic Oxidation of Toluene

Porous LaFeO₃ powders were produced by high-temperature calcination of LaFeO₃ precursors obtained by hydrothermal treatment of corresponding nitrates in the presence of citric acid. Four LaFeO₃ powders calcinated at different temperatures were mixed with appropriate amounts of kaolinite, carboxymethyl cellulose, glycerol and active carbon for the preparation of monolithic LaFeO₃ by extrusion. Porous LaFeO₃ powders were characterized using powder X-ray diffraction, scanning electron microscopy, nitrogen absorption/desorption and X-ray photoelectron spectroscopy. Among the four monolithic LaFeO₃ catalysts, the catalyst calcinated at 700 °C showed the best catalytic activity for the catalytic oxidation of toluene at 36,000 mL/(g∙h), and the corresponding T_10%, T_50% and T_90% was 76 °C, 253 °C and 420 °C, respectively. The catalytic performance is attributed to the larger specific surface area (23.41 m²/g), higher surface adsorption of oxygen concentration and larger Fe²⁺/Fe³⁺ ratio associated with LaFeO₃ calcined at 700 °C.