Preparation of organic/inorganic hybrid nanoballs using aggregates of PTMSPMA-b-PSMA-Fc-PSMA-b-PTMSPMA block copolymers as precursors

Junfeng Zhou; Li Wang; Xiaochen Dong; Tao Chen; Qiang Yang; Chang Chen; Xu Chen

doi:10.1088/0957-4484/17/11/006

Preparation of organic/inorganic hybrid nanoballs using aggregates of PTMSPMA-b-PSMA-Fc-PSMA-b-PTMSPMA block copolymers as precursors

Junfeng Zhou, Li Wang, Xiaochen Dong, Tao Chen, Qiang Yang, Chang Chen, Xu Chen

Zhejiang University

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

Brush-type amphiphilic block copolymers of 3-(trimethoxysilyl)propyl methacrylate (TMSPMA) and stearyl methacrylate (SMA) were prepared through the initiation of chloroacetylferrocene using atom transfer radical polymerization (ATRP) in anisole solution. The resultant copolymers were characterized by ¹H NMR and GPC. We investigated the morphologies and sizes of organic/inorganic hybrid nanoballs using aggregates of these multi-block copolymers as precursors after a sol-gel process. The effect of the copolymer-solvent interaction on these aggregations was discussed.

Original language	English
Pages (from-to)	2745-2751
Number of pages	7
Journal	Nanotechnology
Volume	17
Issue number	11
DOIs	https://doi.org/10.1088/0957-4484/17/11/006
State	Published - 19 May 2006
Externally published	Yes

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title = "Preparation of organic/inorganic hybrid nanoballs using aggregates of PTMSPMA-b-PSMA-Fc-PSMA-b-PTMSPMA block copolymers as precursors",

abstract = "Brush-type amphiphilic block copolymers of 3-(trimethoxysilyl)propyl methacrylate (TMSPMA) and stearyl methacrylate (SMA) were prepared through the initiation of chloroacetylferrocene using atom transfer radical polymerization (ATRP) in anisole solution. The resultant copolymers were characterized by 1H NMR and GPC. We investigated the morphologies and sizes of organic/inorganic hybrid nanoballs using aggregates of these multi-block copolymers as precursors after a sol-gel process. The effect of the copolymer-solvent interaction on these aggregations was discussed.",

author = "Junfeng Zhou and Li Wang and Xiaochen Dong and Tao Chen and Qiang Yang and Chang Chen and Xu Chen",

year = "2006",

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T1 - Preparation of organic/inorganic hybrid nanoballs using aggregates of PTMSPMA-b-PSMA-Fc-PSMA-b-PTMSPMA block copolymers as precursors

AU - Zhou, Junfeng

AU - Wang, Li

AU - Dong, Xiaochen

AU - Chen, Tao

AU - Yang, Qiang

AU - Chen, Chang

AU - Chen, Xu

PY - 2006/5/19

Y1 - 2006/5/19

N2 - Brush-type amphiphilic block copolymers of 3-(trimethoxysilyl)propyl methacrylate (TMSPMA) and stearyl methacrylate (SMA) were prepared through the initiation of chloroacetylferrocene using atom transfer radical polymerization (ATRP) in anisole solution. The resultant copolymers were characterized by 1H NMR and GPC. We investigated the morphologies and sizes of organic/inorganic hybrid nanoballs using aggregates of these multi-block copolymers as precursors after a sol-gel process. The effect of the copolymer-solvent interaction on these aggregations was discussed.

AB - Brush-type amphiphilic block copolymers of 3-(trimethoxysilyl)propyl methacrylate (TMSPMA) and stearyl methacrylate (SMA) were prepared through the initiation of chloroacetylferrocene using atom transfer radical polymerization (ATRP) in anisole solution. The resultant copolymers were characterized by 1H NMR and GPC. We investigated the morphologies and sizes of organic/inorganic hybrid nanoballs using aggregates of these multi-block copolymers as precursors after a sol-gel process. The effect of the copolymer-solvent interaction on these aggregations was discussed.

UR - http://www.scopus.com/inward/record.url?scp=33744549333&partnerID=8YFLogxK

U2 - 10.1088/0957-4484/17/11/006

DO - 10.1088/0957-4484/17/11/006

M3 - 文章

AN - SCOPUS:33744549333

SN - 0957-4484

VL - 17

SP - 2745

EP - 2751

JO - Nanotechnology

JF - Nanotechnology

IS - 11

ER -

Preparation of organic/inorganic hybrid nanoballs using aggregates of PTMSPMA-b-PSMA-Fc-PSMA-b-PTMSPMA block copolymers as precursors

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