Preparing natural clay-based catalysts for HCl catalytic oxidation to recycle chlorine

Yong Dai; Hong Bin Ye; Zhao Yang Fei; Xian Chen; Ji Hai Tang; Mi Fen Cui; Xu Qiao

Preparing natural clay-based catalysts for HCl catalytic oxidation to recycle chlorine

Yong Dai, Hong Bin Ye, Zhao Yang Fei, Xian Chen, Ji Hai Tang, Mi Fen Cui, Xu Qiao

College of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

Using cheap and available natural clays (activated clay, bentonite and colin) as supports, CeCuK/activated clay, CeCuK/bentonite and CeCuK/colin catalysts for HCl oxidation were prepared, respectively, and cha- [JP2]racterized by technologies of BET, XRD, Raman, H₂-TPR, ICP and ESEM. Their corresponding catalytic oxidation performances were studied. The experimental results showed that CeCuK/activated clay catalyst had the maximum values of surface area, pore volume and pore diameter, and active component CuO was most dispersed on the support of activated clay. The reducing sequence of catalysts was as follows: CeCuK/activated clay>CeCuK/bentonite>CeCuK/colin. Under conditions of bed temperature 430°C and HCl weight space-time speed 1.53 h^-1, V(HCl):V(O₂)=1:1, the reaction capability of HCl on catalyst CeCuK/activated clay reached 749 L·kg^-1·h^-1.

Original language	English
Pages (from-to)	54-59
Number of pages	6
Journal	Journal of Molecular Catalysis
Volume	28
Issue number	1
State	Published - Feb 2014

Keywords

Activated clay
Catalytic oxidation
Clay-based catalyst
Hydrogen chloride

Cite this

@article{718da89944034f248ead92e34907fb5e,

title = "Preparing natural clay-based catalysts for HCl catalytic oxidation to recycle chlorine",

abstract = "Using cheap and available natural clays (activated clay, bentonite and colin) as supports, CeCuK/activated clay, CeCuK/bentonite and CeCuK/colin catalysts for HCl oxidation were prepared, respectively, and cha- [JP2]racterized by technologies of BET, XRD, Raman, H2-TPR, ICP and ESEM. Their corresponding catalytic oxidation performances were studied. The experimental results showed that CeCuK/activated clay catalyst had the maximum values of surface area, pore volume and pore diameter, and active component CuO was most dispersed on the support of activated clay. The reducing sequence of catalysts was as follows: CeCuK/activated clay>CeCuK/bentonite>CeCuK/colin. Under conditions of bed temperature 430°C and HCl weight space-time speed 1.53 h-1, V(HCl):V(O2)=1:1, the reaction capability of HCl on catalyst CeCuK/activated clay reached 749 L·kg-1·h-1.",

keywords = "Activated clay, Catalytic oxidation, Clay-based catalyst, Hydrogen chloride",

author = "Yong Dai and Ye, {Hong Bin} and Fei, {Zhao Yang} and Xian Chen and Tang, {Ji Hai} and Cui, {Mi Fen} and Xu Qiao",

year = "2014",

month = feb,

language = "英语",

volume = "28",

pages = "54--59",

journal = "Journal of Molecular Catalysis",

issn = "1001-3555",

publisher = "Science China Press",

number = "1",

}

TY - JOUR

T1 - Preparing natural clay-based catalysts for HCl catalytic oxidation to recycle chlorine

AU - Dai, Yong

AU - Ye, Hong Bin

AU - Fei, Zhao Yang

AU - Chen, Xian

AU - Tang, Ji Hai

AU - Cui, Mi Fen

AU - Qiao, Xu

PY - 2014/2

Y1 - 2014/2

N2 - Using cheap and available natural clays (activated clay, bentonite and colin) as supports, CeCuK/activated clay, CeCuK/bentonite and CeCuK/colin catalysts for HCl oxidation were prepared, respectively, and cha- [JP2]racterized by technologies of BET, XRD, Raman, H2-TPR, ICP and ESEM. Their corresponding catalytic oxidation performances were studied. The experimental results showed that CeCuK/activated clay catalyst had the maximum values of surface area, pore volume and pore diameter, and active component CuO was most dispersed on the support of activated clay. The reducing sequence of catalysts was as follows: CeCuK/activated clay>CeCuK/bentonite>CeCuK/colin. Under conditions of bed temperature 430°C and HCl weight space-time speed 1.53 h-1, V(HCl):V(O2)=1:1, the reaction capability of HCl on catalyst CeCuK/activated clay reached 749 L·kg-1·h-1.

AB - Using cheap and available natural clays (activated clay, bentonite and colin) as supports, CeCuK/activated clay, CeCuK/bentonite and CeCuK/colin catalysts for HCl oxidation were prepared, respectively, and cha- [JP2]racterized by technologies of BET, XRD, Raman, H2-TPR, ICP and ESEM. Their corresponding catalytic oxidation performances were studied. The experimental results showed that CeCuK/activated clay catalyst had the maximum values of surface area, pore volume and pore diameter, and active component CuO was most dispersed on the support of activated clay. The reducing sequence of catalysts was as follows: CeCuK/activated clay>CeCuK/bentonite>CeCuK/colin. Under conditions of bed temperature 430°C and HCl weight space-time speed 1.53 h-1, V(HCl):V(O2)=1:1, the reaction capability of HCl on catalyst CeCuK/activated clay reached 749 L·kg-1·h-1.

KW - Activated clay

KW - Catalytic oxidation

KW - Clay-based catalyst

KW - Hydrogen chloride

UR - http://www.scopus.com/inward/record.url?scp=84897564839&partnerID=8YFLogxK

M3 - 文章

AN - SCOPUS:84897564839

SN - 1001-3555

VL - 28

SP - 54

EP - 59

JO - Journal of Molecular Catalysis

JF - Journal of Molecular Catalysis

IS - 1

ER -

Preparing natural clay-based catalysts for HCl catalytic oxidation to recycle chlorine

Abstract

Keywords

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