Production of renewable 1,3-pentadiene from xylitol via formic acid-mediated deoxydehydration and palladium-catalyzed deoxygenation reactions

Ruiyan Sun; Mingyuan Zheng; Xinsheng Li; Jifeng Pang; Aiqin Wang; Xiaodong Wang; Tao Zhang

doi:10.1039/c6gc02868c

Production of renewable 1,3-pentadiene from xylitol via formic acid-mediated deoxydehydration and palladium-catalyzed deoxygenation reactions

Ruiyan Sun, Mingyuan Zheng, Xinsheng Li, Jifeng Pang, Aiqin Wang, Xiaodong Wang, Tao Zhang

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

A two-step synthetic approach for the production of renewable 1,3-pentadiene was reported: xylitol deoxydehydration (DODH) by formic acid to 2,4-pentadien-1-ol, 1-formate (2E), followed by deoxygenation to 1,3-pentadiene over Pd/C. The overall carbon yield of 1,3-pentadiene reached 51.8% under the optimized conditions.

Original language	English
Pages (from-to)	638-642
Number of pages	5
Journal	Green Chemistry
Volume	19
Issue number	3
DOIs	https://doi.org/10.1039/c6gc02868c
State	Published - 2017
Externally published	Yes

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title = "Production of renewable 1,3-pentadiene from xylitol via formic acid-mediated deoxydehydration and palladium-catalyzed deoxygenation reactions",

abstract = "A two-step synthetic approach for the production of renewable 1,3-pentadiene was reported: xylitol deoxydehydration (DODH) by formic acid to 2,4-pentadien-1-ol, 1-formate (2E), followed by deoxygenation to 1,3-pentadiene over Pd/C. The overall carbon yield of 1,3-pentadiene reached 51.8% under the optimized conditions.",

author = "Ruiyan Sun and Mingyuan Zheng and Xinsheng Li and Jifeng Pang and Aiqin Wang and Xiaodong Wang and Tao Zhang",

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T1 - Production of renewable 1,3-pentadiene from xylitol via formic acid-mediated deoxydehydration and palladium-catalyzed deoxygenation reactions

AU - Sun, Ruiyan

AU - Zheng, Mingyuan

AU - Li, Xinsheng

AU - Pang, Jifeng

AU - Wang, Aiqin

AU - Wang, Xiaodong

AU - Zhang, Tao

PY - 2017

Y1 - 2017

N2 - A two-step synthetic approach for the production of renewable 1,3-pentadiene was reported: xylitol deoxydehydration (DODH) by formic acid to 2,4-pentadien-1-ol, 1-formate (2E), followed by deoxygenation to 1,3-pentadiene over Pd/C. The overall carbon yield of 1,3-pentadiene reached 51.8% under the optimized conditions.

AB - A two-step synthetic approach for the production of renewable 1,3-pentadiene was reported: xylitol deoxydehydration (DODH) by formic acid to 2,4-pentadien-1-ol, 1-formate (2E), followed by deoxygenation to 1,3-pentadiene over Pd/C. The overall carbon yield of 1,3-pentadiene reached 51.8% under the optimized conditions.

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U2 - 10.1039/c6gc02868c

DO - 10.1039/c6gc02868c

M3 - 文章

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SN - 1463-9262

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SP - 638

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JO - Green Chemistry

JF - Green Chemistry

IS - 3

ER -

Production of renewable 1,3-pentadiene from xylitol via formic acid-mediated deoxydehydration and palladium-catalyzed deoxygenation reactions

Abstract

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