Radical fluoroalkylthiolation of aldehydes with PhSO2SRf (Rf = CF3, C2F5, CF2H or CH2F): A general protocol for the preparation of fluoroalkylthioesters

Bin Xu; Dezhi Li; Long Lu; Decai Wang; Yonghong Hu; Qilong Shen

doi:10.1039/c8qo00327k

Radical fluoroalkylthiolation of aldehydes with PhSO₂SR_f (R_f = CF₃, C₂F₅, CF₂H or CH₂F): A general protocol for the preparation of fluoroalkylthioesters

Bin Xu, Dezhi Li, Long Lu, Decai Wang, Yonghong Hu, Qilong Shen

COLLEGE OF FOOD SCIENCE AND LIGHT INDUSTRY

Research output: Contribution to journal › Article › peer-review

62 Scopus citations

Abstract

A general method for the preparation of fluoroalkylthioesters including trifluoromethylthio/pentafluoroethylthio/difluoromethylthio/monofluoromethylthio-esters from aldehydes and a corresponding fluoroalkylthiolating reagent was reported. The reactions were conducted under mild conditions and various common functional groups such as fluorine, chloride, bromide, iodide, and ester groups were compatible.

Original language	English
Pages (from-to)	2163-2166
Number of pages	4
Journal	Organic Chemistry Frontiers
Volume	5
Issue number	14
DOIs	https://doi.org/10.1039/c8qo00327k
State	Published - 21 Jul 2018

Access to Document

10.1039/c8qo00327k

Cite this

@article{0db7ce76bb7c443a90a0f8f7d4f53873,

title = "Radical fluoroalkylthiolation of aldehydes with PhSO2SRf (Rf = CF3, C2F5, CF2H or CH2F): A general protocol for the preparation of fluoroalkylthioesters",

abstract = "A general method for the preparation of fluoroalkylthioesters including trifluoromethylthio/pentafluoroethylthio/difluoromethylthio/monofluoromethylthio-esters from aldehydes and a corresponding fluoroalkylthiolating reagent was reported. The reactions were conducted under mild conditions and various common functional groups such as fluorine, chloride, bromide, iodide, and ester groups were compatible.",

author = "Bin Xu and Dezhi Li and Long Lu and Decai Wang and Yonghong Hu and Qilong Shen",

note = "Publisher Copyright: {\textcopyright} the Partner Organisations 2018.",

year = "2018",

month = jul,

day = "21",

doi = "10.1039/c8qo00327k",

language = "英语",

volume = "5",

pages = "2163--2166",

journal = "Organic Chemistry Frontiers",

issn = "2052-4110",

publisher = "Royal Society of Chemistry",

number = "14",

}

TY - JOUR

T1 - Radical fluoroalkylthiolation of aldehydes with PhSO2SRf (Rf = CF3, C2F5, CF2H or CH2F)

T2 - A general protocol for the preparation of fluoroalkylthioesters

AU - Xu, Bin

AU - Li, Dezhi

AU - Lu, Long

AU - Wang, Decai

AU - Hu, Yonghong

AU - Shen, Qilong

PY - 2018/7/21

Y1 - 2018/7/21

N2 - A general method for the preparation of fluoroalkylthioesters including trifluoromethylthio/pentafluoroethylthio/difluoromethylthio/monofluoromethylthio-esters from aldehydes and a corresponding fluoroalkylthiolating reagent was reported. The reactions were conducted under mild conditions and various common functional groups such as fluorine, chloride, bromide, iodide, and ester groups were compatible.

AB - A general method for the preparation of fluoroalkylthioesters including trifluoromethylthio/pentafluoroethylthio/difluoromethylthio/monofluoromethylthio-esters from aldehydes and a corresponding fluoroalkylthiolating reagent was reported. The reactions were conducted under mild conditions and various common functional groups such as fluorine, chloride, bromide, iodide, and ester groups were compatible.

UR - http://www.scopus.com/inward/record.url?scp=85049504625&partnerID=8YFLogxK

U2 - 10.1039/c8qo00327k

DO - 10.1039/c8qo00327k

M3 - 文章

AN - SCOPUS:85049504625

SN - 2052-4110

VL - 5

SP - 2163

EP - 2166

JO - Organic Chemistry Frontiers

JF - Organic Chemistry Frontiers

IS - 14

ER -

Radical fluoroalkylthiolation of aldehydes with PhSO₂SR_f (R_f = CF₃, C₂F₅, CF₂H or CH₂F): A general protocol for the preparation of fluoroalkylthioesters

Abstract

Access to Document

Other files and links

Fingerprint

Cite this