TY - JOUR
T1 - Recent Advances and Challenges in Perovskite-Based Protonic Ceramic Electrolytes
T2 - Design Strategies and Fabrication Innovations
AU - Nie, Haoyu
AU - Liu, Zuoqing
AU - Xiao, Ming
AU - Yang, Guangming
AU - Li, Tao
AU - Starostina, Inna A.
AU - Medvedev, Dmitry A.
AU - Wang, Wei
AU - Zhou, Wei
AU - Ran, Ran
N1 - Publisher Copyright:
© 2024 Wiley-VCH GmbH.
PY - 2025/3/4
Y1 - 2025/3/4
N2 - Protonic ceramic electrochemical cells (PCECs) have received extensive research attention as full solid-state, electrochemical devices that can interconvert electrical and chemical energies via rapid proton conduction at reduced temperatures. Nonetheless, the practical application of PCECs still faces numerous challenges. In addition to the development of electrode materials, the protonic ceramic electrolytes (PCEs), which are crucial for the performance and stability of PCECs, encounter issues such as poor sinterability, low ionic conductivity, and inadequate thermochemical matching. To address these obstacles, the design and optimization of protonic ceramic electrolytes have recently become essential research focuses in the field of PCECs. To achieve effective customization of the elemental composition, crystal structure, defect structure, ionic conductivity, and chemical stability, many candidates for electrolyte materials with various compositions have been proposed. This review also covers state-of-the-art developments in PCE fabrication technologies, including powder synthesis, thin-film deposition, more controllable sintering processes and interface treatments for structural integrity and ionic conductivity. This review comprehensively summarizes the most recent design approaches and optimization strategies for perovskite-based protonic ceramic electrolyte materials and is crucial for advancing the commercialization of PCECs.
AB - Protonic ceramic electrochemical cells (PCECs) have received extensive research attention as full solid-state, electrochemical devices that can interconvert electrical and chemical energies via rapid proton conduction at reduced temperatures. Nonetheless, the practical application of PCECs still faces numerous challenges. In addition to the development of electrode materials, the protonic ceramic electrolytes (PCEs), which are crucial for the performance and stability of PCECs, encounter issues such as poor sinterability, low ionic conductivity, and inadequate thermochemical matching. To address these obstacles, the design and optimization of protonic ceramic electrolytes have recently become essential research focuses in the field of PCECs. To achieve effective customization of the elemental composition, crystal structure, defect structure, ionic conductivity, and chemical stability, many candidates for electrolyte materials with various compositions have been proposed. This review also covers state-of-the-art developments in PCE fabrication technologies, including powder synthesis, thin-film deposition, more controllable sintering processes and interface treatments for structural integrity and ionic conductivity. This review comprehensively summarizes the most recent design approaches and optimization strategies for perovskite-based protonic ceramic electrolyte materials and is crucial for advancing the commercialization of PCECs.
KW - electrolytes
KW - proton-conducting oxides
KW - protonic ceramic fuel cells
KW - triple conductors
UR - http://www.scopus.com/inward/record.url?scp=86000431866&partnerID=8YFLogxK
U2 - 10.1002/adfm.202416651
DO - 10.1002/adfm.202416651
M3 - 文献综述
AN - SCOPUS:86000431866
SN - 1616-301X
VL - 35
JO - Advanced Functional Materials
JF - Advanced Functional Materials
IS - 10
M1 - 2416651
ER -