Recent Advances in Barium Cobaltite-Based Perovskite Oxides as Cathodes for Intermediate-Temperature Solid Oxide Fuel Cells

Solid oxide fuel cells (SOFCs) are considered as advanced energy conversion technologies due to the high efficiency, fuel flexibility, and all-solid structure. Nevertheless, their widespread applications are strongly hindered by the high operational temperatures, limited material selection choices, inferior long-term stability, and relatively high costs. Therefore, reducing operational temperatures of SOFCs to intermediate-temperature (IT, 500–800 °C) range can remarkably promote the practical applications by enabling the use of low-cost materials and enhancing the cell stability. Nevertheless, the conventional cathodes for high-temperature SOFCs display inferior electrocatalytic activity for oxygen reduction reaction (ORR) at reduced temperatures. Barium cobaltite (BaCoO_3-δ)-based perovskite oxides are regarded as promising cathodes for IT-SOFCs because of the high free lattice volume and large oxygen vacancy content. However, BaCoO_3-δ-based perovskite oxides suffer from poor structural stability, inferior thermal compatibility, and insufficient ionic conductivity. Herein, an in-time review about the recent advances in BaCoO_3-δ-based cathodes for IT-SOFCs is presented by emphasizing the material design strategies including functional/selectively doping, deficiency control, and (nano)composite construction to enhance the ORR activity/durability and thermal compatibility. Finally, the currently existed challenges and future research trends are presented. This review will provide valuable insights for the development of BaCoO_3-δ-based electrocatalysts for various energy conversion/storage technologies.