Recent progress in C(aryl)-C(alkyl) bond cleavage of alkylarenes

Peng Fei Dai; Hua Wang; Xian Chao Cui; Jian Ping Qu; Yan Biao Kang

doi:10.1039/c9qo01438a

Recent progress in C(aryl)-C(alkyl) bond cleavage of alkylarenes

Peng Fei Dai, Hua Wang, Xian Chao Cui, Jian Ping Qu, Yan Biao Kang

School of Chemistry and Moleculai Engineering

Research output: Contribution to journal › Review article › peer-review

17 Scopus citations

Abstract

Cleavage of the C(aryl)-C(alkyl) σ-bond is important both in academy and industry as it holds the potential to provide straightforward access to a variety of targets from readily available chemical feedstocks such like alkylarenes. However, C(aryl)-C(alkyl) bonds of alkylarenes remain intact under most conventional reaction conditions. In this review, we highlight the results of recent C(aryl)-C(alkyl) bond cleavages that have been induced by homogeneous transition metal reagents, by oxidative cleavages, and by rearrangement.

Original language	English
Pages (from-to)	896-904
Number of pages	9
Journal	Organic Chemistry Frontiers
Volume	7
Issue number	6
DOIs	https://doi.org/10.1039/c9qo01438a
State	Published - 21 Mar 2020

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abstract = "Cleavage of the C(aryl)-C(alkyl) σ-bond is important both in academy and industry as it holds the potential to provide straightforward access to a variety of targets from readily available chemical feedstocks such like alkylarenes. However, C(aryl)-C(alkyl) bonds of alkylarenes remain intact under most conventional reaction conditions. In this review, we highlight the results of recent C(aryl)-C(alkyl) bond cleavages that have been induced by homogeneous transition metal reagents, by oxidative cleavages, and by rearrangement.",

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AU - Dai, Peng Fei

AU - Wang, Hua

AU - Cui, Xian Chao

AU - Qu, Jian Ping

AU - Kang, Yan Biao

PY - 2020/3/21

Y1 - 2020/3/21

N2 - Cleavage of the C(aryl)-C(alkyl) σ-bond is important both in academy and industry as it holds the potential to provide straightforward access to a variety of targets from readily available chemical feedstocks such like alkylarenes. However, C(aryl)-C(alkyl) bonds of alkylarenes remain intact under most conventional reaction conditions. In this review, we highlight the results of recent C(aryl)-C(alkyl) bond cleavages that have been induced by homogeneous transition metal reagents, by oxidative cleavages, and by rearrangement.

AB - Cleavage of the C(aryl)-C(alkyl) σ-bond is important both in academy and industry as it holds the potential to provide straightforward access to a variety of targets from readily available chemical feedstocks such like alkylarenes. However, C(aryl)-C(alkyl) bonds of alkylarenes remain intact under most conventional reaction conditions. In this review, we highlight the results of recent C(aryl)-C(alkyl) bond cleavages that have been induced by homogeneous transition metal reagents, by oxidative cleavages, and by rearrangement.

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U2 - 10.1039/c9qo01438a

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M3 - 文献综述

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VL - 7

SP - 896

EP - 904

JO - Organic Chemistry Frontiers

JF - Organic Chemistry Frontiers

IS - 6

ER -

Recent progress in C(aryl)-C(alkyl) bond cleavage of alkylarenes

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