TY - JOUR
T1 - Reinforcement of EPDM/SmBO3 and EPDM/ATO composites by four polyolefins
T2 - Assessment of branch content and crystallinity
AU - Su, Jun
AU - Chen, Shuangjun
AU - Zhang, Jun
PY - 2010/9
Y1 - 2010/9
N2 - From Van Gurp plot, it was found that low-density polyethylene possesses long branches. The larger number of short branches would consume more peroxide and lower the maximum toque (MH) in cure curves. Rheological studies show the complex viscosity of polypropylene (PP) is the highest among four polyolefins. But PP would undergo beta-scission, which would consume peroxide and also lower the MH. Moreover, the acidic Sb-doped SnO2 (ATO) would retard the cure and descend the chemical crosslink points, which would facilitate the motion of ethylene chain and enhance the crystallinity of polyolefin in ethylene-propylene-diene monomer composites.
AB - From Van Gurp plot, it was found that low-density polyethylene possesses long branches. The larger number of short branches would consume more peroxide and lower the maximum toque (MH) in cure curves. Rheological studies show the complex viscosity of polypropylene (PP) is the highest among four polyolefins. But PP would undergo beta-scission, which would consume peroxide and also lower the MH. Moreover, the acidic Sb-doped SnO2 (ATO) would retard the cure and descend the chemical crosslink points, which would facilitate the motion of ethylene chain and enhance the crystallinity of polyolefin in ethylene-propylene-diene monomer composites.
KW - Mooney viscosity
KW - ethylene-propylene-diene rubber
KW - mechanical and electrical properties
KW - polyolefin
KW - rheological measurement
KW - swelling ratio
UR - http://www.scopus.com/inward/record.url?scp=78650282309&partnerID=8YFLogxK
U2 - 10.1177/0095244310379980
DO - 10.1177/0095244310379980
M3 - 文章
AN - SCOPUS:78650282309
SN - 0095-2443
VL - 42
SP - 471
EP - 492
JO - Journal of Elastomers and Plastics
JF - Journal of Elastomers and Plastics
IS - 5
ER -