Rhodium(iii)-catalyzed C-H allylation of electron-deficient alkenes with allyl acetates

Chao Feng; Daming Feng; Teck Peng Loh

doi:10.1039/c4cc07597h

Rhodium(iii)-catalyzed C-H allylation of electron-deficient alkenes with allyl acetates

Chao Feng, Daming Feng, Teck Peng Loh

Research output: Contribution to journal › Article › peer-review

80 Scopus citations

Abstract

Rhodium-catalyzed C-H allylation of acrylamides with allyl acetates is reported. The use of weakly coordinating directing group resulted in high reaction efficiency, broad functionality tolerance and excellent γ-selectivity, which opens a new synthetic pathway for the access of 1,4-diene skeletons.

Original language	English
Pages (from-to)	342-345
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	2
DOIs	https://doi.org/10.1039/c4cc07597h
State	Published - 7 Jan 2015
Externally published	Yes

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title = "Rhodium(iii)-catalyzed C-H allylation of electron-deficient alkenes with allyl acetates",

abstract = "Rhodium-catalyzed C-H allylation of acrylamides with allyl acetates is reported. The use of weakly coordinating directing group resulted in high reaction efficiency, broad functionality tolerance and excellent γ-selectivity, which opens a new synthetic pathway for the access of 1,4-diene skeletons.",

author = "Chao Feng and Daming Feng and Loh, {Teck Peng}",

note = "Publisher Copyright: {\textcopyright} 2015 The Royal Society of Chemistry.",

year = "2015",

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AU - Feng, Chao

AU - Feng, Daming

AU - Loh, Teck Peng

PY - 2015/1/7

Y1 - 2015/1/7

N2 - Rhodium-catalyzed C-H allylation of acrylamides with allyl acetates is reported. The use of weakly coordinating directing group resulted in high reaction efficiency, broad functionality tolerance and excellent γ-selectivity, which opens a new synthetic pathway for the access of 1,4-diene skeletons.

AB - Rhodium-catalyzed C-H allylation of acrylamides with allyl acetates is reported. The use of weakly coordinating directing group resulted in high reaction efficiency, broad functionality tolerance and excellent γ-selectivity, which opens a new synthetic pathway for the access of 1,4-diene skeletons.

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U2 - 10.1039/c4cc07597h

DO - 10.1039/c4cc07597h

M3 - 文章

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AN - SCOPUS:84916198276

SN - 1359-7345

VL - 51

SP - 342

EP - 345

JO - Chemical Communications

JF - Chemical Communications

IS - 2

ER -

Rhodium(iii)-catalyzed C-H allylation of electron-deficient alkenes with allyl acetates

Abstract

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