Rhodium(iii)-catalyzed olefinic C–H alkynylation of enamides at room temperature

Chao Feng; Daming Feng; Teck Peng Loh

doi:10.1039/c4cc04072d

Rhodium(iii)-catalyzed olefinic C–H alkynylation of enamides at room temperature

Chao Feng, Daming Feng, Teck Peng Loh

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130 Scopus citations

Abstract

Rh(iii)-catalyzed C–H olefinic alkynylation of enamides for the stereospecific construction of synthetically useful Z -type enynamides is reported. This protocol displays good functionality tolerance and operational simplicity thus providing an alternative synthetic opportunity for the ease of access to specific 1,3-enyne derivatives.

Original language	English
Pages (from-to)	9865-9868
Number of pages	4
Journal	Chemical Communications
Volume	50
Issue number	69
DOIs	https://doi.org/10.1039/c4cc04072d
State	Published - 31 Jul 2014
Externally published	Yes

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title = "Rhodium(iii)-catalyzed olefinic C–H alkynylation of enamides at room temperature",

abstract = "Rh(iii)-catalyzed C–H olefinic alkynylation of enamides for the stereospecific construction of synthetically useful Z -type enynamides is reported. This protocol displays good functionality tolerance and operational simplicity thus providing an alternative synthetic opportunity for the ease of access to specific 1,3-enyne derivatives.",

author = "Chao Feng and Daming Feng and Loh, {Teck Peng}",

year = "2014",

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AU - Feng, Chao

AU - Feng, Daming

AU - Loh, Teck Peng

PY - 2014/7/31

Y1 - 2014/7/31

N2 - Rh(iii)-catalyzed C–H olefinic alkynylation of enamides for the stereospecific construction of synthetically useful Z -type enynamides is reported. This protocol displays good functionality tolerance and operational simplicity thus providing an alternative synthetic opportunity for the ease of access to specific 1,3-enyne derivatives.

AB - Rh(iii)-catalyzed C–H olefinic alkynylation of enamides for the stereospecific construction of synthetically useful Z -type enynamides is reported. This protocol displays good functionality tolerance and operational simplicity thus providing an alternative synthetic opportunity for the ease of access to specific 1,3-enyne derivatives.

UR - http://www.scopus.com/inward/record.url?scp=84905499395&partnerID=8YFLogxK

U2 - 10.1039/c4cc04072d

DO - 10.1039/c4cc04072d

M3 - 文章

AN - SCOPUS:84905499395

SN - 1359-7345

VL - 50

SP - 9865

EP - 9868

JO - Chemical Communications

JF - Chemical Communications

IS - 69

ER -

Rhodium(iii)-catalyzed olefinic C–H alkynylation of enamides at room temperature

Abstract

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