RhIII-Catalyzed Hydroarylation of Internal Alkynes through C−H Bond Activation

Cheng Qiang Wang; Chao Feng; Teck Peng Loh

doi:10.1002/ajoc.201600144

Rh^III-Catalyzed Hydroarylation of Internal Alkynes through C−H Bond Activation

Cheng Qiang Wang, Chao Feng, Teck Peng Loh

School of Chemistry and Moleculai Engineering

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

Rh^III-catalyzed hydroarylation of internal alkynes through C−H bond activation is described herein by using N,N-dimethylaminocarbonyl as a directing group without the need of an external oxidant. This protocol exhibits exceptional functionality compatibility owing to its extremely mild reaction conditions, which provides a facile and highly efficient synthetic method for olefin moiety introduction.

Original language	English
Pages (from-to)	1002-1007
Number of pages	6
Journal	Asian Journal of Organic Chemistry
Volume	5
Issue number	8
DOIs	https://doi.org/10.1002/ajoc.201600144
State	Published - 1 Aug 2016

Keywords

C−H activation
alkynes
cross-coupling
hydroarylation
rhodium

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abstract = "RhIII-catalyzed hydroarylation of internal alkynes through C−H bond activation is described herein by using N,N-dimethylaminocarbonyl as a directing group without the need of an external oxidant. This protocol exhibits exceptional functionality compatibility owing to its extremely mild reaction conditions, which provides a facile and highly efficient synthetic method for olefin moiety introduction.",

keywords = "C−H activation, alkynes, cross-coupling, hydroarylation, rhodium",

author = "Wang, {Cheng Qiang} and Chao Feng and Loh, {Teck Peng}",

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AU - Feng, Chao

AU - Loh, Teck Peng

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N2 - RhIII-catalyzed hydroarylation of internal alkynes through C−H bond activation is described herein by using N,N-dimethylaminocarbonyl as a directing group without the need of an external oxidant. This protocol exhibits exceptional functionality compatibility owing to its extremely mild reaction conditions, which provides a facile and highly efficient synthetic method for olefin moiety introduction.

AB - RhIII-catalyzed hydroarylation of internal alkynes through C−H bond activation is described herein by using N,N-dimethylaminocarbonyl as a directing group without the need of an external oxidant. This protocol exhibits exceptional functionality compatibility owing to its extremely mild reaction conditions, which provides a facile and highly efficient synthetic method for olefin moiety introduction.

KW - C−H activation

KW - alkynes

KW - cross-coupling

KW - hydroarylation

KW - rhodium

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M3 - 文章

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JO - Asian Journal of Organic Chemistry

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ER -

Rh^III-Catalyzed Hydroarylation of Internal Alkynes through C−H Bond Activation

Abstract

Keywords

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