Second structural directing agent induces the formation of 1D organic templated terbium sulfate

Lei Zheng; Xinmin Qiu; Yan Xu; Jie Fu; Yan Yuan; Dunru Zhu; Su Chen

doi:10.1039/c0ce00895h

Second structural directing agent induces the formation of 1D organic templated terbium sulfate

Lei Zheng, Xinmin Qiu, Yan Xu, Jie Fu, Yan Yuan, Dunru Zhu, Su Chen

College of Chemical Engineering

Nanjing Tech University

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

Two organic amine templated 1D terbium sulfates (H₃O) ₂(C₂H₈N)[Tb(SO₄)₃] 1 and 3D (C₂H₈N)₉[Tb₅(SO₄) ₁₂]·2H₂O 2 have been solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction. Compound 1 exhibits a 1D anionic chain structure compensated by protonated dimethylamine and water cations occluded in the helical [Tb-O-S]_n chains, while the 3D inorganic framework of 2 contains extra-large 20-membered ring channels. The synthesis of both compounds demonstrates that a large organic amine (1,3,5-triazine-2,4,6-triamine) may be used as the second structural directing agent (SDA) to prevent the formation of a high dimensional inorganic framework as well as inducing crystal growth of 1D structural terbium sulfate chain of 1. Because of the excellent luminescent properties of Tb³⁺, compounds 1 and 2 were investigated. The very strong luminescence in the green light region indicates 1D compound 1 is an excellent candidate for green fluorescent materials.

Original language	English
Pages (from-to)	2714-2720
Number of pages	7
Journal	CrystEngComm
Volume	13
Issue number	7
DOIs	https://doi.org/10.1039/c0ce00895h
State	Published - 7 Apr 2011

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title = "Second structural directing agent induces the formation of 1D organic templated terbium sulfate",

abstract = "Two organic amine templated 1D terbium sulfates (H3O) 2(C2H8N)[Tb(SO4)3] 1 and 3D (C2H8N)9[Tb5(SO4) 12]·2H2O 2 have been solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction. Compound 1 exhibits a 1D anionic chain structure compensated by protonated dimethylamine and water cations occluded in the helical [Tb-O-S]n chains, while the 3D inorganic framework of 2 contains extra-large 20-membered ring channels. The synthesis of both compounds demonstrates that a large organic amine (1,3,5-triazine-2,4,6-triamine) may be used as the second structural directing agent (SDA) to prevent the formation of a high dimensional inorganic framework as well as inducing crystal growth of 1D structural terbium sulfate chain of 1. Because of the excellent luminescent properties of Tb3+, compounds 1 and 2 were investigated. The very strong luminescence in the green light region indicates 1D compound 1 is an excellent candidate for green fluorescent materials.",

author = "Lei Zheng and Xinmin Qiu and Yan Xu and Jie Fu and Yan Yuan and Dunru Zhu and Su Chen",

year = "2011",

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doi = "10.1039/c0ce00895h",

language = "英语",

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T1 - Second structural directing agent induces the formation of 1D organic templated terbium sulfate

AU - Zheng, Lei

AU - Qiu, Xinmin

AU - Xu, Yan

AU - Fu, Jie

AU - Yuan, Yan

AU - Zhu, Dunru

AU - Chen, Su

PY - 2011/4/7

Y1 - 2011/4/7

N2 - Two organic amine templated 1D terbium sulfates (H3O) 2(C2H8N)[Tb(SO4)3] 1 and 3D (C2H8N)9[Tb5(SO4) 12]·2H2O 2 have been solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction. Compound 1 exhibits a 1D anionic chain structure compensated by protonated dimethylamine and water cations occluded in the helical [Tb-O-S]n chains, while the 3D inorganic framework of 2 contains extra-large 20-membered ring channels. The synthesis of both compounds demonstrates that a large organic amine (1,3,5-triazine-2,4,6-triamine) may be used as the second structural directing agent (SDA) to prevent the formation of a high dimensional inorganic framework as well as inducing crystal growth of 1D structural terbium sulfate chain of 1. Because of the excellent luminescent properties of Tb3+, compounds 1 and 2 were investigated. The very strong luminescence in the green light region indicates 1D compound 1 is an excellent candidate for green fluorescent materials.

AB - Two organic amine templated 1D terbium sulfates (H3O) 2(C2H8N)[Tb(SO4)3] 1 and 3D (C2H8N)9[Tb5(SO4) 12]·2H2O 2 have been solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction. Compound 1 exhibits a 1D anionic chain structure compensated by protonated dimethylamine and water cations occluded in the helical [Tb-O-S]n chains, while the 3D inorganic framework of 2 contains extra-large 20-membered ring channels. The synthesis of both compounds demonstrates that a large organic amine (1,3,5-triazine-2,4,6-triamine) may be used as the second structural directing agent (SDA) to prevent the formation of a high dimensional inorganic framework as well as inducing crystal growth of 1D structural terbium sulfate chain of 1. Because of the excellent luminescent properties of Tb3+, compounds 1 and 2 were investigated. The very strong luminescence in the green light region indicates 1D compound 1 is an excellent candidate for green fluorescent materials.

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U2 - 10.1039/c0ce00895h

DO - 10.1039/c0ce00895h

M3 - 文章

AN - SCOPUS:79952830355

SN - 1466-8033

VL - 13

SP - 2714

EP - 2720

JO - CrystEngComm

JF - CrystEngComm

IS - 7

ER -

Second structural directing agent induces the formation of 1D organic templated terbium sulfate

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