TY - JOUR
T1 - Selective removal and utilization of copper from electroplating wastewater by modified MXene-based capacitive deionization
AU - Jiang, Kaixiang
AU - Zhang, Jianwei
AU - Xu, Bin
AU - Han, Zilong
AU - Wang, Zheng
AU - Li, Zhe
AU - Luo, Jun
AU - Zhang, Jie
AU - Ji, Changhai
AU - Chen, Zhihao
AU - Yang, Wenzhong
N1 - Publisher Copyright:
© 2025 Elsevier B.V.
PY - 2025/8/14
Y1 - 2025/8/14
N2 - Capacitive deionization (CDI) technology has promising potential for the removal of copper ions from electroplating wastewater. In this study, a new kind of FeS2 modified MXene electrode material with three-dimensional mutual support structure was synthesized, which has excellent hydrophilicity, electrical conductivity, and specific redox activity for copper ions. Therefore, this material was applied for the selective removal of copper ions from electroplating wastewater through the use of CDI. The FeS2/MXene electrode demonstrated excellent electrosorption performance, with an electrosorption capacity (EC) of 80.02 mg g−1 and a removal efficiency of 96.02 %. The electrosorption mechanism involves three synergistic pathways: (1) Faradaic redox reactions between Fe2+/Fe3+ and Cu2+/Cu+, (2) ion intercalation, and (3) capacitive adsorption. Notably, the material exhibited remarkable selectivity for Cu2+ even in mixed ion systems, with distribution coefficients exceeding 104 mL g−1. Additionally, Cu2+ in the actual electroplating wastewater was efficiently removed (99.97 %), meeting the water quality standard for metal plating and chemical coating process. Furthermore, the electrosorption-saturated electrodes with copper ions were reused as raw materials to prepare Cu@FeS2/MXene electrocatalysts for nitrate (NO3–-N) reduction. The electrocatalytic efficiency of NO3–-N was 86.9 %, and the selectivity for nitrogen (N2) reached 98.3 %. This study opens up a promising approach not only for selectively removing copper from wastewater but also for utilizing copper-saturated electrodes, demonstrating a sustainable and efficient strategy for water treatment and resource recovery.
AB - Capacitive deionization (CDI) technology has promising potential for the removal of copper ions from electroplating wastewater. In this study, a new kind of FeS2 modified MXene electrode material with three-dimensional mutual support structure was synthesized, which has excellent hydrophilicity, electrical conductivity, and specific redox activity for copper ions. Therefore, this material was applied for the selective removal of copper ions from electroplating wastewater through the use of CDI. The FeS2/MXene electrode demonstrated excellent electrosorption performance, with an electrosorption capacity (EC) of 80.02 mg g−1 and a removal efficiency of 96.02 %. The electrosorption mechanism involves three synergistic pathways: (1) Faradaic redox reactions between Fe2+/Fe3+ and Cu2+/Cu+, (2) ion intercalation, and (3) capacitive adsorption. Notably, the material exhibited remarkable selectivity for Cu2+ even in mixed ion systems, with distribution coefficients exceeding 104 mL g−1. Additionally, Cu2+ in the actual electroplating wastewater was efficiently removed (99.97 %), meeting the water quality standard for metal plating and chemical coating process. Furthermore, the electrosorption-saturated electrodes with copper ions were reused as raw materials to prepare Cu@FeS2/MXene electrocatalysts for nitrate (NO3–-N) reduction. The electrocatalytic efficiency of NO3–-N was 86.9 %, and the selectivity for nitrogen (N2) reached 98.3 %. This study opens up a promising approach not only for selectively removing copper from wastewater but also for utilizing copper-saturated electrodes, demonstrating a sustainable and efficient strategy for water treatment and resource recovery.
KW - Capacitive deionization
KW - Copper removal
KW - Electrocatalytic reduction
KW - MXene
UR - http://www.scopus.com/inward/record.url?scp=85219108406&partnerID=8YFLogxK
U2 - 10.1016/j.seppur.2025.132303
DO - 10.1016/j.seppur.2025.132303
M3 - 文章
AN - SCOPUS:85219108406
SN - 1383-5866
VL - 363
JO - Separation and Purification Technology
JF - Separation and Purification Technology
M1 - 132303
ER -