Solubility and solution thermodynamics of 2,5-thiophenedicarboxylic acid in (water + ethanol) binary solvent mixtures

Yang Yang; Qi Zhang; Cuicui Cao; Limin Cheng; Ying Shi; Wenge Yang; Yonghong Hu

doi:10.1016/j.tca.2014.08.002

Solubility and solution thermodynamics of 2,5-thiophenedicarboxylic acid in (water + ethanol) binary solvent mixtures

Yang Yang, Qi Zhang, Cuicui Cao, Limin Cheng, Ying Shi, Wenge Yang, Yonghong Hu

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

In this paper, we focused on solubility and solution thermodynamics of 2,5-thiophenedicarboxylic acid. By gravimetric method, the solubility of 2,5-thiophenedicarboxylic acid was measured in (water + ethanol) binary solvent mixtures from 278.15 K to 333.15 K under atmosphere pressure. The solubility data were fitted using modified Apelblat equation, a variant of the combined nearly ideal binary solvent/Redlich-Kister (CNIBS/R-K) model and Jouyban-Acree model. Computational results showed that the modified Apelblat equation has the lowest MD (mean deviation). In addition, the thermodynamic properties of the solution process, including the Gibbs energy, enthalpy, and entropy were calculated by the van't Hoff analysis.

Original language	English
Pages (from-to)	52-57
Number of pages	6
Journal	Thermochimica Acta
Volume	592
DOIs	https://doi.org/10.1016/j.tca.2014.08.002
State	Published - 20 Sep 2014

Keywords

2,5-thiophenedicarboxylic acid
Apelblat equation
CNIBS/R-K
Jouyban-Acree model
van't Hoff analysis

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10.1016/j.tca.2014.08.002

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title = "Solubility and solution thermodynamics of 2,5-thiophenedicarboxylic acid in (water + ethanol) binary solvent mixtures",

abstract = "In this paper, we focused on solubility and solution thermodynamics of 2,5-thiophenedicarboxylic acid. By gravimetric method, the solubility of 2,5-thiophenedicarboxylic acid was measured in (water + ethanol) binary solvent mixtures from 278.15 K to 333.15 K under atmosphere pressure. The solubility data were fitted using modified Apelblat equation, a variant of the combined nearly ideal binary solvent/Redlich-Kister (CNIBS/R-K) model and Jouyban-Acree model. Computational results showed that the modified Apelblat equation has the lowest MD (mean deviation). In addition, the thermodynamic properties of the solution process, including the Gibbs energy, enthalpy, and entropy were calculated by the van't Hoff analysis.",

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author = "Yang Yang and Qi Zhang and Cuicui Cao and Limin Cheng and Ying Shi and Wenge Yang and Yonghong Hu",

year = "2014",

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doi = "10.1016/j.tca.2014.08.002",

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T1 - Solubility and solution thermodynamics of 2,5-thiophenedicarboxylic acid in (water + ethanol) binary solvent mixtures

AU - Yang, Yang

AU - Zhang, Qi

AU - Cao, Cuicui

AU - Cheng, Limin

AU - Shi, Ying

AU - Yang, Wenge

AU - Hu, Yonghong

PY - 2014/9/20

Y1 - 2014/9/20

N2 - In this paper, we focused on solubility and solution thermodynamics of 2,5-thiophenedicarboxylic acid. By gravimetric method, the solubility of 2,5-thiophenedicarboxylic acid was measured in (water + ethanol) binary solvent mixtures from 278.15 K to 333.15 K under atmosphere pressure. The solubility data were fitted using modified Apelblat equation, a variant of the combined nearly ideal binary solvent/Redlich-Kister (CNIBS/R-K) model and Jouyban-Acree model. Computational results showed that the modified Apelblat equation has the lowest MD (mean deviation). In addition, the thermodynamic properties of the solution process, including the Gibbs energy, enthalpy, and entropy were calculated by the van't Hoff analysis.

AB - In this paper, we focused on solubility and solution thermodynamics of 2,5-thiophenedicarboxylic acid. By gravimetric method, the solubility of 2,5-thiophenedicarboxylic acid was measured in (water + ethanol) binary solvent mixtures from 278.15 K to 333.15 K under atmosphere pressure. The solubility data were fitted using modified Apelblat equation, a variant of the combined nearly ideal binary solvent/Redlich-Kister (CNIBS/R-K) model and Jouyban-Acree model. Computational results showed that the modified Apelblat equation has the lowest MD (mean deviation). In addition, the thermodynamic properties of the solution process, including the Gibbs energy, enthalpy, and entropy were calculated by the van't Hoff analysis.

KW - 2,5-thiophenedicarboxylic acid

KW - Apelblat equation

KW - CNIBS/R-K

KW - Jouyban-Acree model

KW - van't Hoff analysis

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U2 - 10.1016/j.tca.2014.08.002

DO - 10.1016/j.tca.2014.08.002

M3 - 文章

AN - SCOPUS:84906282268

SN - 0040-6031

VL - 592

SP - 52

EP - 57

JO - Thermochimica Acta

JF - Thermochimica Acta

ER -

Solubility and solution thermodynamics of 2,5-thiophenedicarboxylic acid in (water + ethanol) binary solvent mixtures

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Keywords

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