Solubility of 3,3′-(Oxidi-2,1-ethanediyl)bis[1-methyl-imidazolium] Dihexafluorophosphate in Water, Methanol, Ethanol, Acetone, and Acetonitrile and Binary Mixtures (Water + DMF) from (283.00 to 323.00) K

Jia Rong Guo; Bin Xu; Yan Wang; Ling Hua Zhuang; Guo Wei Wang

doi:10.1021/je501026m

Solubility of 3,3′-(Oxidi-2,1-ethanediyl)bis[1-methyl-imidazolium] Dihexafluorophosphate in Water, Methanol, Ethanol, Acetone, and Acetonitrile and Binary Mixtures (Water + DMF) from (283.00 to 323.00) K

Jia Rong Guo, Bin Xu, Yan Wang, Ling Hua Zhuang, Guo Wei Wang

School of Chemistry and Moleculai Engineering

Nanjing Tech University

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

3,3′-(Oxidi-2,1-ethanediyl)bis[1-methyl-imidazolium] dihexafluorophosphate ([C₄O(mim)₂][PF₆]₂) was synthesized and confirmed with ¹H NMR and FT-IR. The thermal stability of [C₄O(mim)₂][PF₆]₂ was studied with differential scanning calorimetry and thermogravimetric analyses. Using the dynamic method, the solubility of [C₄O(mim)₂][PF₆]₂ in five different pure solvents (water, methanol, ethanol, acetone, and acetonitrile) and binary mixtures (water + DMF) was measured at the temperature range from (283.00 to 323.00 K) at atmospheric pressure. The solubility of [C₄O(mim)₂][PF₆]₂ in those selected solvents increased with increasing temperature and DMF contents, but the rate of solubility is different. The experimental data were correlated with the modified Apelblat equation. Also, the solubility of [C₄O(mim)₂][PF₆]₂ and [C₆O₂(mim)₂][PF₆]₂ was been compared in the same solvent. (Graphical Presented).

Original language	English
Pages (from-to)	1091-1097
Number of pages	7
Journal	Journal of Chemical and Engineering Data
Volume	60
Issue number	4
DOIs	https://doi.org/10.1021/je501026m
State	Published - 9 Apr 2015

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@article{a21afc38ca2e41d5a41b7f1eef8c7082,

title = "Solubility of 3,3′-(Oxidi-2,1-ethanediyl)bis[1-methyl-imidazolium] Dihexafluorophosphate in Water, Methanol, Ethanol, Acetone, and Acetonitrile and Binary Mixtures (Water + DMF) from (283.00 to 323.00) K",

abstract = "3,3′-(Oxidi-2,1-ethanediyl)bis[1-methyl-imidazolium] dihexafluorophosphate ([C4O(mim)2][PF6]2) was synthesized and confirmed with 1H NMR and FT-IR. The thermal stability of [C4O(mim)2][PF6]2 was studied with differential scanning calorimetry and thermogravimetric analyses. Using the dynamic method, the solubility of [C4O(mim)2][PF6]2 in five different pure solvents (water, methanol, ethanol, acetone, and acetonitrile) and binary mixtures (water + DMF) was measured at the temperature range from (283.00 to 323.00 K) at atmospheric pressure. The solubility of [C4O(mim)2][PF6]2 in those selected solvents increased with increasing temperature and DMF contents, but the rate of solubility is different. The experimental data were correlated with the modified Apelblat equation. Also, the solubility of [C4O(mim)2][PF6]2 and [C6O2(mim)2][PF6]2 was been compared in the same solvent. (Graphical Presented).",

author = "Guo, {Jia Rong} and Bin Xu and Yan Wang and Zhuang, {Ling Hua} and Wang, {Guo Wei}",

note = "Publisher Copyright: {\textcopyright} 2015 American Chemical Society.",

year = "2015",

month = apr,

day = "9",

doi = "10.1021/je501026m",

language = "英语",

volume = "60",

pages = "1091--1097",

journal = "Journal of Chemical and Engineering Data",

issn = "0021-9568",

publisher = "American Chemical Society",

number = "4",

}

Solubility of 3,3′-(Oxidi-2,1-ethanediyl)bis[1-methyl-imidazolium] Dihexafluorophosphate in Water, Methanol, Ethanol, Acetone, and Acetonitrile and Binary Mixtures (Water + DMF) from (283.00 to 323.00) K. / Guo, Jia Rong; Xu, Bin; Wang, Yan et al.
In: Journal of Chemical and Engineering Data, Vol. 60, No. 4, 09.04.2015, p. 1091-1097.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Solubility of 3,3′-(Oxidi-2,1-ethanediyl)bis[1-methyl-imidazolium] Dihexafluorophosphate in Water, Methanol, Ethanol, Acetone, and Acetonitrile and Binary Mixtures (Water + DMF) from (283.00 to 323.00) K

AU - Guo, Jia Rong

AU - Xu, Bin

AU - Wang, Yan

AU - Zhuang, Ling Hua

AU - Wang, Guo Wei

PY - 2015/4/9

Y1 - 2015/4/9

N2 - 3,3′-(Oxidi-2,1-ethanediyl)bis[1-methyl-imidazolium] dihexafluorophosphate ([C4O(mim)2][PF6]2) was synthesized and confirmed with 1H NMR and FT-IR. The thermal stability of [C4O(mim)2][PF6]2 was studied with differential scanning calorimetry and thermogravimetric analyses. Using the dynamic method, the solubility of [C4O(mim)2][PF6]2 in five different pure solvents (water, methanol, ethanol, acetone, and acetonitrile) and binary mixtures (water + DMF) was measured at the temperature range from (283.00 to 323.00 K) at atmospheric pressure. The solubility of [C4O(mim)2][PF6]2 in those selected solvents increased with increasing temperature and DMF contents, but the rate of solubility is different. The experimental data were correlated with the modified Apelblat equation. Also, the solubility of [C4O(mim)2][PF6]2 and [C6O2(mim)2][PF6]2 was been compared in the same solvent. (Graphical Presented).

AB - 3,3′-(Oxidi-2,1-ethanediyl)bis[1-methyl-imidazolium] dihexafluorophosphate ([C4O(mim)2][PF6]2) was synthesized and confirmed with 1H NMR and FT-IR. The thermal stability of [C4O(mim)2][PF6]2 was studied with differential scanning calorimetry and thermogravimetric analyses. Using the dynamic method, the solubility of [C4O(mim)2][PF6]2 in five different pure solvents (water, methanol, ethanol, acetone, and acetonitrile) and binary mixtures (water + DMF) was measured at the temperature range from (283.00 to 323.00 K) at atmospheric pressure. The solubility of [C4O(mim)2][PF6]2 in those selected solvents increased with increasing temperature and DMF contents, but the rate of solubility is different. The experimental data were correlated with the modified Apelblat equation. Also, the solubility of [C4O(mim)2][PF6]2 and [C6O2(mim)2][PF6]2 was been compared in the same solvent. (Graphical Presented).

UR - http://www.scopus.com/inward/record.url?scp=84927604539&partnerID=8YFLogxK

U2 - 10.1021/je501026m

DO - 10.1021/je501026m

M3 - 文章

AN - SCOPUS:84927604539

SN - 0021-9568

VL - 60

SP - 1091

EP - 1097

JO - Journal of Chemical and Engineering Data

JF - Journal of Chemical and Engineering Data

IS - 4

ER -

Solubility of 3,3′-(Oxidi-2,1-ethanediyl)bis[1-methyl-imidazolium] Dihexafluorophosphate in Water, Methanol, Ethanol, Acetone, and Acetonitrile and Binary Mixtures (Water + DMF) from (283.00 to 323.00) K

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